Alkali feldspar series

Orthoclase, or orthoclase feldspar (endmember formula KAlSi3O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture", because its two cleavage planes are at right angles to each other. It is a type of alkali feldspar, also known as potassium feldspar or K-spar. The gem known as moonstone (see below) is largely composed of orthoclase.

orthoclase variety moonstone also known as white labradorite from feldspar with schiller

Amazonite, also known as amazonstone, is a green tectosilicate mineral, a variety of the potassium feldspar called microcline. Its chemical formula is KAlSi3O8, which is polymorphic to orthoclase.

Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. It is common in granite and pegmatites. Microcline forms during slow cooling of orthoclase. Sanidine is a polymorph of alkali feldspar stable at yet higher temperature. Microcline has cross-hatch twinning that forms as a result of the transformation of monoclinic orthoclase into triclinic microcline.

Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal system. Orthoclase is a monoclinic polymorph stable at lower temperatures. At yet lower temperatures, microcline, a triclinic polymorph of potassium feldspar, is stable.

Sunstone is a microcline or oligoclase feldspar, which when viewed from certain directions exhibits a spangled appearance. It has been found in Southern Norway, Sweden, various localities in the United States, and on some beaches along the midcoast of South Australia.

The mineral anorthoclase ((Na,K)AlSi3O8) is a crystalline solid solution in the alkali feldspar series, in which the proportion of the sodium-aluminium silicate member exceeds the potassium-aluminium silicate member. It typically consists of between 64 and 90 percent of NaAlSi3O8 and between 10 and 36 percent of KAlSi3O8. thumb|left|upright|An anorthoclase crystal from Mount Erebus, Antarctica

feldspar, orthoclase - albite solid solution series

Rubicline, also referred to as Rb-microcline, is the rubidium analogue of microcline, an important tectosilicate mineral. Its chemical formula is (Rb, K)[AlSi3O8] with an ideal composition of RbAlSi3O8. Chemical analysis by electron microprobe indicated the average weight of the crystal is 56.66% SiO2, 16.95% Al2O3, and 23.77% Rb2O, along with trace amounts of caesium oxide (Cs2O) and iron(III) oxide (Fe2O3).