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Cluster chemistry

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tetrahedrane
Tetrahedrane is a hypothetical platonic hydrocarbon with chemical formula and a tetrahedral structure. The molecule would be subject to considerable angle strain and has not been synthesized . However, a number of derivatives have been prepared. In a more general sense, the term tetrahedranes is used to describe a class of molecules and ions with related structure, e.g. white phosphorus.
carborane
thumb|right|Ball-and-stick model of o-carborane <!-- thumb|right|Ball-and-stick model of the [[carborane acid anion (acidic proton not displayed)
cluster
ensemble of bound atoms or molecules that is intermediate in size between a molecule and a bulk solid
polyoxometalate
Polyoxometalates (POMs) are a group of inorganic, anionic molecular metal oxides.
carborane acid
chemical compound
iron-sulfur cluster
synthetic analogue of active redox-center in enzymes and Fe–S proteins
superatom
In chemistry, a superatom is any cluster of atoms that seem to exhibit some of the properties of elemental atoms. One example of a superatom is the cluster .
iron-sulfur protein
class of proteins in which iron is coordinated with cysteine sulfur and also with inorganic sulfur
Zintl phase
product of certain chemical reactions
water cluster
discrete hydrogen bonded assembly or cluster of molecules of water
polyhedral skeletal electron pair theory
electron counting rules useful for predicting the structures of clusters
Metal aromaticity
Concept of aromaticity extended to metals
Keggin structure
best known structural form for heteropoly acids
molybdenum blue
pigment
water dimer
two water molecules held together by a hydrogen bond; the simplest water cluster
dodecaborate
The dodecaborate(12) anion, [B12H12]2−, is a boron hydride cluster anion. It forms a variety of colorless salts with alkali metal and quaternary ammonium cations. The cluster has a distinctive icosahedral structure with 12 boron atoms at the vertices, each boron atom is attached to a hydrogen atom. Its symmetry is classified by the molecular point group Ih.