Category
page 1Hydrido complexes
cobalt tetracarbonyl hydride
chemical compound
sodium bis(2-methoxyethoxy)aluminum hydride
chemical compound
Schwartz's reagent
chemical compound
potassium nonahydridorhenate
chemical compound
pentacarbonylhydridorhenium
Pentacarbonylhydridorhenium is a chemical compound with the formula ReH(CO)5. This colorless liquid is a weak acid and represents one of the most important derivatives of dirhenium decacarbonyl (Re2(CO)10). It is synthesized by treating a methanolic solution of bromopentacarbonylrhenium(I) (Re(CO)5Br) with zinc and acetic acid (HOAc).
Re(CO)5Br + Zn + HOAc → ReH(CO)5 + ZnBrOAc
iron tetracarbonyl hydride
chemical compound
Pentacarbonylhydridomanganese
Pentacarbonylhydridomanganese is an organometallic compound with formula HMn(CO). This compound is one of the most stable "first-row" transition metal hydrides.
decacarbonyldihydridotriosmium
Decacarbonyldihydridotriosmium is an organoosmium compound with the formula H2Os3(CO)10. This purple-violet crystalline air-stable cluster is noteworthy because it is electron-deficient and hence adds a variety of substrates.
tris(triphenylphosphine)rhodium carbonyl hydride
chemical compound