Isotopes of plutonium

Plutonium-238 (' or Pu-238') is a radioactive isotope of plutonium that has a half-life of 87.7 years.

Plutonium-240 (' or Pu-240') is an isotope of plutonium formed when plutonium-239 captures a neutron without undergoing fission. The detection of its spontaneous fission led to its discovery in 1944 at Los Alamos and had important consequences for the Manhattan Project.

Plutonium-241 (', Pu-241') is an isotope of plutonium formed when plutonium-240 captures a neutron. Like some other plutonium isotopes (especially 239Pu), 241Pu is fissile, with a neutron absorption cross section about one-third greater than that of 239Pu, and a similar probability of fissioning on neutron absorption, around 73%. In the non-fission case, neutron capture produces plutonium-242. In general, isotopes with an odd number of neutrons are both more likely to absorb a neutron and more likely to undergo fission on neutron absorption than isotopes with an even number of neutrons.

Plutonium-244 (Pu) is an isotope of plutonium that has a half-life of 81.3 million years. This is longer than any other isotope of plutonium and longer than any other known isotope of an element beyond bismuth, except for the three naturally abundant ones: uranium-235 (704 million years), uranium-238 (4.463 billion years), and thorium-232 (14.0 billion years). Given the half-life of Pu, an exceedingly small amount should still be present on Earth, making plutonium a likely but unproven candidate as the shortest-lived primordial element.

Plutonium-242 (Pu or Pu-242) is the second longest-lived isotope of plutonium, with a half-life of 375,000 years. The half-life of Pu is about 15 times that of Pu; so it is one-fifteenth as radioactive, and not one of the larger contributors to nuclear waste radioactivity. Pu's gamma ray emissions are also weaker than those of the other isotopes. As the direct parent of uranium-238 it is part of the uranium series decay chain.