Lithium minerals

thumb|upright=1.3|Main tourmaline producing countries

Spodumene is a pyroxene mineral consisting of lithium aluminium inosilicate, LiAl(SiO3)2, and is a commercially important source of lithium. It occurs as colorless to yellowish, purplish, or lilac kunzite (see below), or alternatively yellowish-green or emerald-green hiddenite; it takes the form of prismatic crystals, often of great size. Single crystals of in size are reported from the Black Hills of South Dakota, United States.

Lepidolite is the common name for a lilac-gray or rose-colored series of minerals in the mica group. The mineralogical name for this series is the polylithionite-trilithionite series. Lepidolite has a chemical formula of . It is the most abundant lithium-bearing mineral and is a secondary source of this metal. It is also the major source of the alkali metal rubidium, which substitutes (as in all minerals) for potassium.

Petalite, also known as castorite, is a lithium aluminum phyllosilicate mineral LiAlSi4O10, crystallizing in the monoclinic system. Petalite occurs as colorless, pink, grey, yellow, yellow grey, to white tabular crystals and columnar masses. It occurs in lithium-bearing pegmatites with spodumene, lepidolite, and tourmaline. Petalite is an important ore of lithium, and is converted to spodumene and quartz by heating to ~500 °C and under 3 kbar of pressure in the presence of a dense hydrous alkali borosilicate fluid with a minor carbonate component. Petalite (and secondary spodumene fo

Amblygonite () is a fluorophosphate mineral, , composed of lithium, sodium, aluminium, phosphate, fluoride and hydroxide. The mineral occurs in pegmatite deposits and is easily mistaken for albite and other feldspars. Its density, cleavage and flame test for lithium are diagnostic. Amblygonite forms a series with montebrasite, the low fluorine endmember. Geologic occurrence is in granite pegmatites, high-temperature tin veins, and greisens. Amblygonite occurs with spodumene, apatite, lepidolite, tourmaline, and other lithium-bearing minerals in pegmatite veins. It contains about 10% lithium, a

Zinnwaldite, KLiFeAl(AlSi3)O10(OH,F)2, potassium lithium iron aluminium silicate hydroxide fluoride, is a silicate mineral in the mica group. The IMA status is as a series between siderophyllite (KFe2Al(Al2Si2)O10(F,OH)2) and polylithionite (KLi2AlSi4O10(F,OH)2) and not considered a valid mineral species.

Elbaite, a sodium, lithium, aluminium boro-silicate, with the chemical composition Na(Li1.5Al1.5)Al6Si6O18(BO3)3(OH)4, is a mineral species belonging to the six-member ring cyclosilicate tourmaline group.

Jadarite is a white, earthy monoclinic silicate mineral, sodium lithium boron silicate hydroxide with the chemical formula LiNaSiB3O7(OH). == Discovery and classification ==

Sugilite ( ) is a relatively rare pink to purple cyclosilicate mineral with the complex chemical formula KNa2(Fe, Mn, Al)2Li3Si12O30. Sugilite crystallizes in the hexagonal system with prismatic crystals. The crystals are rarely found and the form is usually massive. It has a Mohs hardness of 5.5–6.5 and a specific gravity of 2.75–2.80. It is mostly translucent. Sugilite was first described in 1944 by the Japanese petrologist Ken-ichi Sugi (1901–1948) for an occurrence on Iwagi Islet, Japan, where it is found in an aegirine syenite intrusive stock. It is found in a similar environment at

Neptunite is a silicate mineral with the formula KNa2Li(Fe2+, Mn2+)2Ti2Si8O24. With increasing manganese it forms a series with mangan-neptunite. is the variety with vanadium replacing the titanium in the formula.

Pezzottaite, marketed under the name raspberyl or raspberry beryl, is a mineral species first recognized by the International Mineralogical Association in September 2003. Pezzottaite is a caesium analogue of beryl, a silicate of caesium, beryllium, lithium and aluminium, with the chemical formula Cs(Be2Li)Al2Si6O18. Named after Italian geologist and mineralogist Federico Pezzotta, pezzottaite was first thought to be either red beryl or a new variety of beryl ("caesium beryl"); unlike actual beryl, however, pezzottaite contains lithium and crystallizes in the trigonal crystal system rather than

Lithiophilite is a mineral containing the element lithium. It is lithium manganese(II) phosphate with chemical formula . It occurs in pegmatites often associated with triphylite, the iron end member in a solid solution series. The mineral with intermediate composition is known as sicklerite and has the chemical formula ). The name lithiophilite is derived from the Greek philos () "friend", as lithiophilite is usually found with lithium.

Triphylite is a lithium iron(II) phosphate mineral with the chemical formula LiFePO4. It is a member of the triphylite group and forms a complete solid solution series with the lithium manganese(II) phosphate, lithiophilite. Triphylite crystallizes in the orthorhombic crystal system. It rarely forms prismatic crystals and is more frequently found in hypidiomorphic rock. It is bluish- to greenish-gray in color, but upon alteration becomes brown to black.

Eucryptite is a lithium-bearing aluminium silicate mineral with formula LiAlSiO4. It crystallizes in the trigonal - rhombohedral crystal system. It typically occurs as granular to massive in form and may pseudomorphically replace spodumene. It has a brittle to conchoidal fracture and indistinct cleavage. It is transparent to translucent and varies from colorless to white to brown. It has a Mohs hardness of 6.5 and a specific gravity of 2.67. Optically it is uniaxial positive with refractive index values of nω = 1.570 – 1.573 and nε = 1.583 – 1.587.

Hectorite is a rare soft, greasy, white, lithium-rich clay mineral with a chemical formula of .

The mineral zektzerite is a member of the tuhualite group and was first found in 1966 by Seattle mineralogist Benjamin Bartlett "Bart" Cannon. It was discovered in the Willow creek basin below Silver Star mountain in miarolitic cavities within the alkaline arfvedsonite granite phase of the Golden Horn batholith, Okanogan County, Washington. It is named for Jack Zektzer (born 1936), mathematician and mineral collector of Seattle, Washington.

Zabuyelite is the natural mineral form of lithium carbonate, with a formula Li2CO3. It was discovered in 1987 at Lake Zabuye, Tibet, after which it is named. It forms colorless vitreous monoclinic crystals.

Nambulite is a lithium bearing manganese silicate mineral with the chemical formula . It is named after the mineralogist Matsuo Nambu (born 1917) of Tohoko University, Japan, who studies manganese minerals. It was first discovered in the Funakozawa Mine of northeastern Japan in a metasedimentary manganese ore.

Cookeite is a mineral species of the silicate group and the phyllosilicate subgroup, part of the chlorite family, with the formula LiAl4(Si3Al)O10(OH)8. This soft, low-density mineral of variable color has a crystalline structure made up of alternating layers LiAl2(OH)6 and Al2O4(OH)2Si8O12 having several polytypes. Cookeite is often found as a product of hydrothermal alteration of silicates in pegmatites. It forms at relatively low temperatures (below 200°C) and variable pressures.

Saliotite is a rare colorless to pearl white phyllosilicate mineral in the smectite group with formula . It is an ordered 1:1 interstratification of cookeite and paragonite. It has perfect cleavage, a pearly luster and leaves a white streak. Its crystal structure is monoclinic, and it is a soft mineral with a hardness rated 2-3 on the Mohs scale.

Fluor-liddicoatite is a rare member of the tourmaline group of minerals, elbaite subgroup, and the theoretical calcium endmember of the elbaite-fluor-liddicoatite series; the pure end-member has not yet been found in nature. Fluor-liddicoatite is indistinguishable from elbaite by X-ray diffraction techniques. It forms a series with elbaite and probably also with olenite. Liddiocoatite is currently a non-approved mineral name, but Aurisicchio et al. (1999) and Breaks et al. (2008) found OH-dominant species. Formulae are Fluor-liddicoatite Ca(Li2Al)Al6(BO3)3Si6O18(OH)3F Elbaite Na(Al1.5Li1.5)A

Lithiophosphate is a natural form of (pure) lithium orthophosphate. It is an exceedingly rare mineral, occurring in some special types of pegmatites.