Rubidium compounds

Lepidolite is the common name for a lilac-gray or rose-colored series of minerals in the mica group. The mineralogical name for this series is the polylithionite-trilithionite series. Lepidolite has a chemical formula of . It is the most abundant lithium-bearing mineral and is a secondary source of this metal. It is also the major source of the alkali metal rubidium, which substitutes (as in all minerals) for potassium.

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An alkalide is a chemical compound in which alkali metal atoms are anions (negative ions) with a charge or oxidation state of −1. Until the first discovery of alkalides in the 1970s, alkali metals were known to appear in salts only as cations (positive ions) with a charge or oxidation state of +1. These types of compounds are of theoretical interest due to their unusual stoichiometry and low ionization potentials. Alkalide compounds are chemically related to the electrides, salts in which trapped electrons are effectively the anions.

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Rubicline, also referred to as Rb-microcline, is the rubidium analogue of microcline, an important tectosilicate mineral. Its chemical formula is (Rb, K)[AlSi3O8] with an ideal composition of RbAlSi3O8. Chemical analysis by electron microprobe indicated the average weight of the crystal is 56.66% SiO2, 16.95% Al2O3, and 23.77% Rb2O, along with trace amounts of caesium oxide (Cs2O) and iron(III) oxide (Fe2O3).

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