Uranium(IV) minerals

Uraninite, also known as pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium causes the mineral to contain oxides of lead and trace amounts of helium. It may also contain thorium and rare-earth elements.

Thorite, (Th,U)SiO4, is a rare nesosilicate of thorium that crystallizes in the tetragonal system and is isomorphous with zircon and hafnon. It is the most common mineral of thorium and is nearly always strongly radioactive. Thorite was discovered in 1828 on the island of Løvøya, Norway, by the vicar and mineralogist, Hans Morten Thrane Esmark. First specimens of Thorite were sent to his father, Jens Esmark, who was a professor of mineralogy and geology. It was named in 1829 to reflect its thorium content.

Coffinite is a uranium-bearing silicate mineral with formula: U(SiO4)1−x(OH)4x.

thumb|The cleveite sample from which Ramsay first purified helium, in the collection of University College London Cleveite is an impure radioactive variety of uraninite containing uranium, found in Norway. It has the composition UO2 with about 10% of the uranium substituted by rare-earth elements. It was named after Swedish chemist Per Teodor Cleve.