Aluminosilicates

Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the plagioclase (sodium-calcium) feldspars and the alkali (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust and 41% of the Earth's continental crust by weight.

Kaolinite ( ; also called kaolin) is a clay mineral, with the chemical composition Al2Si2O5(OH)4. It is a layered silicate mineral, with one "tetrahedral" sheet of silicate tetrahedra () linked to one "octahedral" sheet of aluminate octahedrons () through oxygen atoms on one side, and another such sheet through hydrogen bonds on the other side.

Orthoclase, or orthoclase feldspar (endmember formula KAlSi3O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture", because its two cleavage planes are at right angles to each other. It is a type of alkali feldspar, also known as potassium feldspar or K-spar. The gem known as moonstone (see below) is largely composed of orthoclase.

Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicate. Its color is usually pure white, hence its name from Latin, . It is a common constituent in felsic rocks.

Labradorite ((Ca, Na)(Al, Si)4O8) is a calcium-enriched feldspar mineral first identified in Labrador, Canada, which can display an iridescent effect (schiller).

Ultramarine is a deep blue pigment which was originally made by grinding lapis lazuli into a powder. Its lengthy grinding and washing process makes the natural pigment quite valuable—roughly ten times more expensive than the stone it comes from. Between the 14th and 15th centuries, it was as expensive as gold in Europe.

Anorthite (2Si2O8. Anorthite is found in igneous rocks.

thumb|Plagioclase displaying cleavage (crystal)|cleavage (unknown scale) thumb|In volcanic rocks, [[fine-grained plagioclase can display a "microlitic" texture of many small crystals.]]

Amazonite, also known as amazonstone, is a green tectosilicate mineral, a variety of the potassium feldspar called microcline. Its chemical formula is KAlSi3O8, which is polymorphic to orthoclase.

Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. It is common in granite and pegmatites. Microcline forms during slow cooling of orthoclase. Sanidine is a polymorph of alkali feldspar stable at yet higher temperature. Microcline has cross-hatch twinning that forms as a result of the transformation of monoclinic orthoclase into triclinic microcline.

Andesine is a silicate mineral, a member of the plagioclase feldspar solid solution series. Its chemical formula is (Ca, Na)(Al, Si)4O8, where the ratio of albite to anorthite (Na:Ca) is 50:50 to 70:30. The formula may be written as Na0.5-0.7Ca0.3-0.5Al1.3-1.5Si2.5-2.7O8.

Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal system. Orthoclase is a monoclinic polymorph stable at lower temperatures. At yet lower temperatures, microcline, a triclinic polymorph of potassium feldspar, is stable.

Aluminosilicate refers to materials containing anionic Si-O-Al linkages. Commonly, the associate cations are sodium (Na+), potassium (K+) and protons (H+). Such materials occur as minerals, coal combustion products and as synthetic materials, often in the form of zeolites. Both synthetic and natural aluminosilicates are of technical significance as structural materials, catalysts, and reagents.

thumb|Structure of illite mica – USGS

Oligoclase is a rock-forming mineral belonging to the plagioclase feldspars. In chemical composition and in its crystallographic and physical characters it is intermediate between albite (NaAlSi3O8) and anorthite (CaAl2Si2O8). The albite:anorthite molar ratio of oligoclase ranges from 90:10 to 70:30.

Bytownite is a calcium rich member of the plagioclase solid solution series of feldspar minerals with composition between anorthite and labradorite. It is usually defined as having between 70 and 90%An (formula: ). Like others of the series, bytownite forms grey to white triclinic crystals commonly exhibiting the typical plagioclase twinning and associated fine striations.

Sunstone is a microcline or oligoclase feldspar, which when viewed from certain directions exhibits a spangled appearance. It has been found in Southern Norway, Sweden, various localities in the United States, and on some beaches along the midcoast of South Australia.

thumb|SEM image of a geopolymer granule prepared from metakaolin by alkaline activation to be further used as a sorbent. A geopolymer is an inorganic, often ceramic-like material, that forms a stable, covalently bonded, non-crystalline to semi-crystalline network through the reaction of aluminosilicate materials with an alkaline or acidic solution. Many geopolymers may also be classified as alkali-activated cements or acid-activated binders. They are mainly produced by a chemical reaction between a chemically reactive aluminosilicate powder e.g. metakaolin or other clay-derived powders, natura

The mineral anorthoclase ((Na,K)AlSi3O8) is a crystalline solid solution in the alkali feldspar series, in which the proportion of the sodium-aluminium silicate member exceeds the potassium-aluminium silicate member. It typically consists of between 64 and 90 percent of NaAlSi3O8 and between 10 and 36 percent of KAlSi3O8. thumb|left|upright|An anorthoclase crystal from Mount Erebus, Antarctica

Celsian is an uncommon feldspar mineral, barium aluminosilicate, BaAl2Si2O8. The mineral occurs in contact metamorphic rocks with significant barium content. Its crystal system is monoclinic, and it is white, yellow, or transparent in appearance. In pure form, it is transparent. Synthetic barium aluminosilicate is used as a ceramic in dental fillings and other applications.

Hyalophane or jaloallofane is a crystalline mineral, part of the feldspar group of tectosilicates. It is considered a barium-rich potassium feldspar. Its chemical formula is , and it has a hardness of 6 to . The name hyalophane comes from the Greek , meaning "glass", and meaning "to appear".

Buddingtonite is an ammonium feldspar with formula: NH4AlSi3O8 (note: some sources add 0.5H2O to the formula). It forms by hydrothermal alteration of primary feldspar minerals. It is an indicator of possible gold and silver deposits, as they can become concentrated by hydrothermal processes. It crystallizes in the monoclinic crystal system and is colorless to white with a vitreous luster. Its structure is analogous to that of high sanidine (KAlSi3O8). Buddingtonite has a hardness of 5.5 and a specific gravity of 2.32.

chemical compound

Banalsite is a rare barium, sodium aluminium silicate mineral with formula: BaNa2Al4Si4O16. Banalsite is a tectosilicate of the feldspar group.

Bicchulite has an ideal chemical formula of , which was formularized from the hydrothermal synthesis of synthetic gehlenite (). Also, bicchulite was sighted in the mines of Japan with related minerals. This sodalite-type structured bicchulite has an uncommon ratio of aluminium to silicon, causing difficulties deciphering the structure. Because of bicchulite's structure it has a powdery texture, which leads to complications in obtaining information on the mineral's physical properties. Despite this problem, the color, specific gravity, and crystal size of bicchulite are known. Although bicchuli

Rubicline, also referred to as Rb-microcline, is the rubidium analogue of microcline, an important tectosilicate mineral. Its chemical formula is (Rb, K)[AlSi3O8] with an ideal composition of RbAlSi3O8. Chemical analysis by electron microprobe indicated the average weight of the crystal is 56.66% SiO2, 16.95% Al2O3, and 23.77% Rb2O, along with trace amounts of caesium oxide (Cs2O) and iron(III) oxide (Fe2O3).

chemical compound

Saussurite is a mineral aggregate which is formed as a hydrothermal alteration product of plagioclase feldspar. It appears very similar to zoisite with a green or grayish-green color, it has been used as a substitute or simulant for jade.