Carbonate minerals

Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scratch hardness comparison. Large calcite crystals are used in optical equipment, and limestone composed mostly of calcite has numerous uses.

carbonate mineral – CaMg(CO₃)₂

Malachite () is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures and deep, underground spaces, where the water table and hydrothermal fluids provide the means for chemical precipitation. Individual crystals are rare, but occur as slender to acicular prisms. Pseudomorphs after more tabular or blocky azurite crystals also occur.

thumb|Calcite alabaster: The tomb of Tutankhamun (d. 1323 BC) contained a practical objet d’art, a cosmetics jar made of Egyptian alabaster, which features a lid surmounted by a lioness (goddess Bast).

Azurite or Azure spar is a soft, deep-blue copper mineral produced by weathering of copper ore deposits. During the early 19th century, it was also known as chessylite, after the type locality at Chessy near Lyon, France. The mineral, a basic carbonate with the chemical formula Cu3(CO3)2(OH)2, has been known since ancient times, and was mentioned in Pliny the Elder's Natural History under the Greek name (κυανός: "deep blue," root of English cyan) and the Latin name caeruleum. Copper (Cu2+) gives it its deep blue color.

Aragonite is a carbonate mineral and one of the three most common naturally occurring crystal forms of calcium carbonate (), the others being calcite and vaterite. It is formed by biological and physical processes, including precipitation from marine and freshwater environments.

Magnesite is a mineral with the chemical formula (magnesium carbonate). Iron, manganese, cobalt, and nickel may occur as admixtures, but only in small amounts. Magnesite occurs naturally in both cryptocrystalline and crystalline forms depending on the conditions of formation.

Siderite is a mineral composed of iron(II) carbonate (FeCO3). Its name comes from the Ancient Greek word (), meaning "iron". A valuable iron ore, it consists of 48% iron and lacks sulfur and phosphorus. Zinc, magnesium, and manganese commonly substitute for the iron, resulting in the siderite-smithsonite, siderite-magnesite, and siderite-rhodochrosite solid solution series.

Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its pure form (rare), it is typically a rose-red colour, but it can also be shades of pink to pale brown. It streaks white, and its Mohs hardness varies between 3.5 and 4.5. Its specific gravity is between 3.45 and 3.6. The crystal system of rhodochrosite is trigonal, with a structure and cleavage in the carbonate rhombohedral system. The carbonate ions () are arranged in a triangular planar configuration, and the manganese ions (Mn2+) are surrounded by six oxygen ions in an octahedral arrangement. The MnO6 octa

Smithsonite, also known as zinc spar, is the mineral form of zinc carbonate (ZnCO3). Historically, smithsonite was identified with hemimorphite before it was realized that they were two different minerals. The two minerals are very similar in appearance and the term calamine has been used for both, leading to some confusion. The distinct mineral smithsonite was named in 1832 by François Sulpice Beudant in honor of English scientist James Smithson (c. 1765–1829), who first identified the mineral in 1802.

Cerussite (also known as lead carbonate or white lead ore) is a mineral consisting of lead carbonate with the chemical formula PbCO3, and is an important ore of lead. The name is from the Latin cerussa, white lead. Cerussa nativa was mentioned by Conrad Gessner in 1565, and in 1832 F. S. Beudant applied the name céruse to the mineral, whilst the present form, cerussite, is due to W. Haidinger (1845). Miners' names in early use were lead-spar and white-lead-ore.

Natron is a naturally occurring mixture of sodium carbonate decahydrate (Na2CO3·10H2O, a kind of soda ash) and around 17% sodium bicarbonate (also called baking soda, NaHCO3) along with small quantities of sodium chloride and sodium sulfate. Natron is white to colourless when pure, varying to gray or yellow with impurities. Natron deposits are sometimes found in saline lake beds which arose in arid environments. Throughout history natron has had many practical applications that continue today in the wide range of modern uses of its constituent mineral components.

Strontianite (SrCO3) is an important raw material for the extraction of strontium. It is a rare carbonate mineral and one of only a few strontium minerals. It is a member of the aragonite group.

Witherite is a barium carbonate mineral, BaCO3, in the aragonite group. Witherite crystallizes in the orthorhombic system and virtually always is twinned. The mineral is colorless, milky-white, grey, pale-yellow, green, to pale-brown. The specific gravity is 4.3, which is high for a translucent mineral. It fluoresces light blue under both long- and short-wave UV light, and is phosphorescent under short-wave UV light.

Ankerite, also known as brown spar () is a calcium, iron, magnesium, manganese carbonate mineral of the group of rhombohedral carbonates with the chemical formula . In composition it is closely related to dolomite, but differs from this in having magnesium replaced by varying amounts of iron(II) and manganese. It forms a series with dolomite and kutnohorite.

transparent variety of calcite

Aurichalcite is a carbonate mineral, usually found as a secondary mineral in copper and zinc deposits. Its chemical formula is . The zinc to copper ratio is about 5:4. Copper (Cu2+) gives aurichalcite its green-blue colors.

minerals in which CO3 and NO3 are the main anion

Trona (trisodium hydrogendicarbonate dihydrate, also sodium sesquicarbonate dihydrate, Na2CO3·NaHCO3·2H2O) is a non-marine evaporite mineral. It is mined as the primary source of sodium carbonate in the United States, where it has replaced the Solvay process used in most of the rest of the world for sodium carbonate production. Turkey is also a major producer.

Hydrozincite, also known as zinc bloom or marionite, is a white carbonate mineral consisting of Zn5(CO3)2(OH)6. It is usually found in massive rather than crystalline form.

The mineral bastnäsite (or bastnaesite) is one of a family of three fluorocarbonate minerals, which includes bastnäsite-(Ce) with a formula of (Ce, La)CO3F, bastnäsite-(La) with a formula of (La, Ce)CO3F, and bastnäsite-(Y) with a formula of (Y, Ce)CO3F. Some of the bastnäsites contain OH− instead of F− and receive the name of hydroxylbastnasite. Most bastnäsite is bastnäsite-(Ce), and cerium is by far the most common of the rare earths in this class of minerals. Bastnäsite and the phosphate mineral monazite are the two largest sources of cerium and other rare-earth elements.

Rosasite is a carbonate mineral with minor potential for use as a zinc and copper ore. Chemically, it is a copper zinc carbonate hydroxide with a copper to zinc ratio of 3:2, occurring in the secondary oxidation zone of copper-zinc deposits. It was originally discovered in 1908 in the Rosas mine in Sardinia, Italy, and is named after the location. Fibrous blue-green rosasite crystals are usually found in globular aggregates, often associated with red limonite and other colorful minerals. It is very similar to aurichalcite, but can be distinguished by its superior hardness.

Dundasite is a rare lead aluminium carbonate mineral. The mineral is named after the type locality, Dundas, Tasmania, Australia. The mineral was first discovered in the Adelaide Proprietary Mine. Dundasite was first described by William Frederick Petterd in 1893.

Cancrinite is a complex carbonate and silicate of sodium, calcium and aluminium with the formula Na6Ca2[(CO3)2|Al6Si6O24]·2H2O. It is classed as a member of the feldspathoid group of minerals; the alkali feldspars that are poor in silica. Yellow, orange, pink, white or even blue, it has a vitreous or pearly luster; a hardness of 5–6 and an uneven conchoidal fracture. It is unusual among the silicate minerals in that it will effervesce with hydrochloric acid due to the associated carbonate ions.

Bismutite or bismuthite is a bismuth carbonate mineral with formula Bi2(CO3)O2 (bismuth subcarbonate). Bismutite occurs as an oxidation product of other bismuth minerals such as bismuthinite and native bismuth in hydrothermal veins and pegmatites. It crystallizes in the orthorhombic system and typically occurs as earthy to fibrous masses.

Hydromagnesite is a hydrated magnesium carbonate mineral with the formula .

Otavite is a rare cadmium carbonate mineral with the formula CdCO3. Otavite crystallizes in the trigonal system and forms encrustations and small scalenohedral crystals that have a pearly to adamantine luster. The color is white to reddish to yellow brown. Its Mohs hardness is 3.5 to 4 and the specific gravity is 5.04. Associated minerals include azurite, calcite, malachite, and smithsonite.

Abenakiite-(Ce) is a mineral of sodium, cerium, neodymium, lanthanum, praseodymium, thorium, samarium, oxygen, sulfur, carbon, phosphorus, and silicon with a chemical formula Na26Ce6(SiO3)6(PO4)6(CO3)6(S4+O2)O. The silicate groups may be given as the cyclic Si6O18 grouping. The mineral is named after the Abenaki, an Algonquian Indian tribe of New England. Its Mohs scale rating is 4 to 5.

class of sedimentary rock

Spherocobaltite or sphaerocobaltite is the mineral form of Cobalt(II) carbonate (). It is a cobalt bearing member of the calcite group of carbonate minerals, crystallizing in the trigonal crystal system. Rare specimens of pure spherocobaltite typically show a rose-red color, but the color range of impure specimens extends to shades of pink and pale brown.

Artinite is a hydrated basic magnesium carbonate mineral with formula: . It forms white silky monoclinic prismatic crystals that are often in radial arrays or encrustations. It has a Mohs hardness of 2.5 and a specific gravity of 2.

Hydrotalcite, or formerly also völknerite, is a layered double hydroxide (LDH) of general formula , whose name is derived from its resemblance with talc and its high water content. Multiple structures containing loosely bound carbonate () ions exist. The easily exchangeable carbonates enable applications of the mineral in wastewater treatment and the immobilisation of radioactive waste after nuclear fuel reprocessing.

Phosgenite is a rare mineral consisting of lead carbonate chloride, (PbCl)2CO3. The tetragonal crystals are prismatic or tabular in habit: they are usually colorless and transparent, and have a brilliant adamantine lustre. Sometimes the crystals have a curious helical twist about the tetrad or principal axis. The hardness is 3 and the specific gravity 6.3. The mineral is rather sectile, and consequently was earlier known as corneous lead ().

right|upright=1.35|300px|thumb|Caliche Petrified wood|fossil forest on [[San Miguel Island, California]]

Leadhillite is a lead sulfate carbonate hydroxide mineral, often associated with anglesite. It has the formula Pb4SO4(CO3)2(OH)2. Leadhillite crystallises in the monoclinic system, but develops pseudo-hexagonal forms due to crystal twinning. It forms transparent to translucent variably coloured crystals with an adamantine lustre. It is quite soft with a Mohs hardness of 2.5 and a relatively high specific gravity of 6.26 to 6.55.

Dawsonite is a mineral composed of sodium aluminium carbonate hydroxide, chemical formula NaAlCO3(OH)2. It crystallizes in the orthorhombic crystal system. It is not mined for ore. It was discovered in 1874 during the construction of the Redpath Museum in a feldspathic dike on the campus of McGill University on the Island of Montreal, Canada. It is named after geologist Sir John William Dawson (1820–1899).

thumb|Putnisite (animation) Putnisite is a mineral composed of strontium, calcium, chromium, sulfur, carbon, oxygen and hydrogen. It was discovered on the Polar Bear Peninsula in Shire of Dundas, Western Australia in 2007 during mining activity. Following identification and recognition by the IMA in 2012 the mineral was named after mineralogists Andrew and Christine Putnis. The formal description was published in 2014.

Gaylussite is a carbonate mineral, a hydrated sodium calcium carbonate, formula Na2Ca(CO3)2·5H2O. It occurs as translucent, vitreous white to grey to yellow monoclinic prismatic crystals. It is an unstable mineral which dehydrates in dry air and decomposes in water.

Aerinite () is a bluish-purple inosilicate mineral. It crystallizes in the monoclinic system and occurs as fibrous or compact masses and coatings. It has a dark, vitreous luster, a specific gravity of 2.48 and a Mohs hardness of 3.

Kutnohorite is a rare calcium manganese carbonate mineral with the formula in the dolomite group of minerals. It forms a solid solution with the other group members dolomite and ankerite. The mineral was originally spelt "kutnahorite" but "kutnohorite" is the current IMA-approved spelling.

Rutherfordine is a mineral containing almost pure uranyl carbonate (UO2CO3). It crystallizes in the orthorhombic system in translucent lathlike, elongated, commonly radiating in fibrous, and in pulverulent, earthy to very fine-grained dense masses. It has a specific gravity of 5.7 and exhibits two directions of cleavage. It appears as brownish, brownish yellow, white, light brown orange, or light yellow fluorescent encrustations. It is also known as diderichite.

Vaterite is a mineral, a polymorph of calcium carbonate (CaCO3). It was named after the German mineralogist Heinrich Vater. It is also known as mu-calcium carbonate (μ-CaCO3). Vaterite belongs to the hexagonal crystal system, whereas calcite is trigonal and aragonite is orthorhombic.

Thaumasite is a calcium silicate mineral, containing Si atoms in unusual octahedral configuration, with chemical formula Ca3Si(OH)6(CO3)(SO4)·12H2O, also sometimes more simply written as CaSiO3·CaCO3·CaSO4·15H2O.

Huntite is a carbonate mineral with the chemical formula Mg3Ca(CO3)4. Huntite crystallizes in the trigonal system and typically occurs as platy crystals and powdery masses. For most of recorded history its main use was as a white pigment. Today the most common industrial use of huntite is as a natural mixture with hydromagnesite as a flame retardant or fire retardant additive for polymers.

Thermonatrite is a naturally occurring evaporite mineral form of sodium carbonate, Na2CO3·H2O.

Zaratite is a bright emerald green nickel carbonate mineral with formula Ni3CO3(OH)4·4H2O. Zaratite crystallizes in the isometric crystal system as massive to mammillary encrustations and vein fillings. It has a specific gravity of 2.6 and a Mohs hardness of 3 to 3.5. It has no cleavage and is brittle to conchoidal fracture. The luster is vitreous to greasy.

Abellaite is a hydrous carbonate mineral discovered in the abandoned Eureka uranium mine in the village of La Torre de Capdella (Lleida province), Catalonia, Spain. The ideal chemical formula of abellaite is NaPb2(CO3)2(OH). It is named in honor of Joan Abella i Creus, a Catalan gemmologist who has long studied minerals from the Eureka mine and first found abellaite in the mine. A team composed, among others, by Jordi Ibáñez-Insa from the Institute of Earth Sciences Jaume Almera (CSIC) and by Joan Viñals and Xavier Llovet from the University of Barcelona, identified and characterized the miner

Spurrite is a white, yellow or light blue mineral with monoclinic crystals. Its chemical formula is Ca5(SiO4)2CO3.

Nahcolite is a soft, colourless or white carbonate mineral with the composition of sodium bicarbonate (NaHCO3) also called thermokalite. It crystallizes in the monoclinic system.

Adamsite-(Y) (previously IMA 1999-020), chemical formula NaY(CO3)2·6H2O is a mineral of sodium, yttrium, carbon, oxygen, and hydrogen. It is named after Frank Dawson Adams (1859–1942), professor of geology, McGill University. Its Mohs scale rating is 3.

Minrecordite, CaZn(CO3)2, is a very rare mineral belonging to the dolomite group, the member with Ca and Zn. It was discovered, associated with dioptase, in a specimen from the Tsumeb mine (Namibia), which is consequently its type locality. Its name is a tribute to The Mineralogical Record magazine, representing the collaboration between professional and amateur mineralogists. In this locality it is associated primarily with dioptase, and less frequently with duftite, calcite and malachite. It is a rare mineral, which has been found only in a few deposits in the world. In addition to the type

Liebigite is a uranium carbonate mineral with the chemical formula: Ca2(UO2)(CO3)3·11H2O. It is a secondary mineral occurring in the oxidizing zone of uranium-bearing ores. It is green to yellow green in colour. It has a Mohs hardness of about 3. Liebigite, like some other uranium minerals, is fluorescent under UV light and is also translucent. It crystallizes in the orthorhombic system, but only rarely forms distinct crystals. It typically forms encrustations or granular aggregates.

Hanksite is a sulfate mineral, distinguished as one of only a handful that contain both carbonate and sulfate ions (a sulfate carbonate). It has the chemical formula Na22K(SO4)9(CO3)2Cl.

Gaspéite, a very rare nickel carbonate mineral, with the formula , is named for the place it was first described, in the Gaspé Peninsula, Québec, Canada.

Weloganite is a rare carbonate mineral with the formula: It was discovered by Canadian government mineralogist Ann P. Sabina in 1967 and named for Canadian geologist Sir William Edmond Logan (1798–1875). It was first discovered in Francon Quarry, Montreal, Quebec, Canada and has only been reported from a few localities worldwide.

Alstonite, also known as bromlite, is a low temperature hydrothermal mineral that is a rare double carbonate of calcium and barium with the formula , sometimes with some strontium. Barytocalcite and paralstonite have the same formula but different structures, so these three minerals are said to be trimorphous. Alstonite is triclinic but barytocalcite is monoclinic and paralstonite is trigonal. The species was named Bromlite by Thomas Thomson in 1837 after the Bromley-Hill mine, and alstonite by August Breithaupt of the Freiberg Mining Academy in 1841, after Alston, Cumbria, the base of operati

Barytocalcite is an anhydrous barium calcium carbonate mineral with the chemical formula BaCa(CO3)2. It is trimorphous with alstonite and paralstonite, that is to say the three minerals have the same formula but different structures. Baryte and quartz pseudomorphs after barytocalcite have been observed.

Benstonite is a mineral with formula Ba6Ca6Mg(CO3)13. Discovered in 1954, the mineral was described in 1961 and named after Orlando J. Benston (1901–1966).

Barstowite, formula Pb4[Cl6|CO3]•H2O, is a transparent to white mineral in the monoclinic system. It has a Mohs hardness of 3, a white streak and an adamantine lustre.

Ikaite is the mineral name for the hexahydrate of calcium carbonate, . Ikaite tends to form very steep or spiky pyramidal crystals, often radially arranged, of varied sizes from thumbnail size aggregates to gigantic salient spurs. It is only found in a metastable state and decomposes rapidly by losing most of its water content once removed from near-freezing water. This "melting mineral" is more commonly known through its pseudomorphs.