Cyanometallates

Ferricyanide is the name of the anion . It is also called hexacyanoferrate(III) and in rare, but systematic nomenclature, hexacyanidoferrate(III). The most common salt of this anion is potassium ferricyanide, a red crystalline material that is used as an oxidant in organic chemistry.

chemical compound

chemical compound

chemical compound

Ferrocyanide is the anion [Fe(CN)6]4−. Salts of this coordination complex give yellow solutions. It is usually available as the salt potassium ferrocyanide, which has the formula K4Fe(CN)6. [Fe(CN)6]4− is a diamagnetic species, featuring low-spin iron(II) center in an octahedral ligand environment. Although many salts of cyanide are highly toxic, ferro- and ferricyanides are less toxic because they tend not to release free cyanide. It is of commercial interest as a precursor to the pigment Prussian blue and, as its potassium salt, an anticaking agent.

Platinocyanide, also known as tetracyanoplatinate (IUPAC), cyanoplatinate, or platinocyanate, is a polyatomic ion with the molecular formula [Pt(CN)4]2−. The name also applies to compounds containing this ion, which are salts of the hypothetical platinocyanic acid (sometimes platinocyanhydric acid).