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ferricyanide(3-)

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ferricyanide(3-)

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Also known as hexacyanoferrate(III)

Ferricyanide is the name of the anion . It is also called hexacyanoferrate(III) and in rare, but systematic nomenclature, hexacyanidoferrate(III). The most common salt of this anion is potassium ferricyanide, a red crystalline material that is used as an oxidant in organic chemistry.

Chemical data

Formula
C6FeN6-3
Molecular weight
211.95 g/mol
IUPAC name
iron(3+) hexacyanide
SMILES
[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[Fe+3]
InChIKey
YAGKRVSRTSUGEY-UHFFFAOYSA-N
Polar surface area
143 Ų
H-bond donors
0
H-bond acceptors
12
Formal charge
-3

via PubChem

Wikidata facts

Mass
211.95502723973
Show 3 more facts
canonical SMILES
[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[Fe+3]
chemical formula
C₆FeN₆³⁻
Sources (3)

via Wikidata · CC0

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Encyclopedic overview

4 sections
Contents
  • Properties
  • Uses
  • See also
  • References

Ferricyanide is the name of the anion . It is also called hexacyanoferrate(III) and in rare, but systematic nomenclature, hexacyanidoferrate(III). The most common salt of this anion is potassium ferricyanide, a red crystalline material that is used as an oxidant in organic chemistry.

== Properties == consists of a center bound in octahedral geometry to six cyanide ligands. The complex has Oh symmetry. The iron is low-spin and easily reduced to the related ferrocyanide ion , which is a ferrous () derivative. This redox couple is reversible and entails no making or breaking of Fe–C bonds:

Excerpted from Wikipedia’s “ferricyanide(3-)” article, available under the CC BY-SA 4.0 licence.