Category
page 1Electrides

Electride
thumb|right|Cavities and channels in an electride
An electride is an ionic compound in which an electron serves the role of the anion.
==Solutions==
Solutions of alkali metals in ammonia are electride salts. In the case of sodium, these blue solutions consist of [Na(NH3)6]+ and solvated electrons:
Na + 6 NH3 → [Na(NH3)6]+ + e−
The cation [Na(NH3)6]+ is an octahedral coordination complex. Despite the name, the electron does not leave the sodium-ammonia complex, but it is transferred from Na to the vacant orbitals of the coordinated ammonia molecules.
Solvated electron
Free electron in a solution, often liquid ammonia
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