Electride
Sign in to savethumb|right|Cavities and channels in an electride An electride is an ionic compound in which an electron serves the role of the anion. ==Solutions== Solutions of alkali metals in ammonia are electride salts. In the case of sodium, these blue solutions consist of [Na(NH3)6]+ and solvated electrons: Na + 6 NH3 → [Na(NH3)6]+ + e− The cation [Na(NH3)6]+ is an octahedral coordination complex. Despite the name, the electron does not leave the sodium-ammonia complex, but it is transferred from Na to the vacant orbitals of the coordinated ammonia molecules.
Article
10 sectionsContents
- Solutions
- Solid salts
- Organometallic electrides
- Reactions
- High-pressure elements
- Layered electrides (Electrenes)
- See also
- References
- Further reading
- External links
thumb|right|Cavities and channels in an electride An electride is an ionic compound in which an electron serves the role of the anion. ==Solutions== Solutions of alkali metals in ammonia are electride salts. In the case of sodium, these blue solutions consist of [Na(NH3)6]+ and solvated electrons: Na + 6 NH3 → [Na(NH3)6]+ + e− The cation [Na(NH3)6]+ is an octahedral coordination complex. Despite the name, the electron does not leave the sodium-ammonia complex, but it is transferred from Na to the vacant orbitals of the coordinated ammonia molecules.
Similar solutions exist in hexamethylphosphoramide.