Nucleophilic substitution reactions

Saponification is a process of cleaving esters into carboxylate salts and alcohols by the action of aqueous alkali. Typically aqueous sodium hydroxide solutions are used. It is an important type of alkaline hydrolysis. When the carboxylate is a long chain, its salt is called a soap. The saponification of ethyl acetate gives sodium acetate and ethanol:

class of chemical reactions in which a leaving group (electrophile) is replaced by an electron rich compound (nucleophile)

A nucleophilic substitution reaction with a carbocation intermediate

substitution reaction with a tetrahedral intermediate

substitution reaction in organic chemistry

In chemistry, Si (substitution nucleophilic internal) refers to a specific, regio-selective but not often encountered reaction mechanism for nucleophilic aliphatic substitution. The name was introduced by Cowdrey et al. in 1937 to label nucleophilic reactions which occur with retention of configuration, but later was employed to describe various reactions that proceed with a similar mechanism.