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Organic reactions

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pyrolysis
thumb|Burning pieces of wood, showing various stages of pyrolysis, followed by oxidative combustion
cracking
thermal or catalytic decomposition of a compound such as a hydrocarbon into chemical species of smaller molecular weight
halogenation
In chemistry, halogenation is a chemical reaction which introduces one or more halogens into a chemical compound. Halide-containing compounds are pervasive, making this type of transformation important, e.g. in the production of polymers, drugs. This kind of conversion is in fact so common that a comprehensive overview is challenging. This article mainly deals with halogenation using elemental halogens (). Halides are also commonly introduced using halide salts and hydrogen halide acids. Many specialized reagents exist for introducing halogens into diverse substrates, e.g. thionyl chloride.
disproportionation
In chemistry, disproportionation, sometimes called dismutation (the French word), is a redox reaction in which one compound of intermediate oxidation state converts to two compounds, one of higher and one of lower oxidation state. The reverse of disproportionation, such as when a compound in an intermediate oxidation state is formed from precursors of lower and higher oxidation states, is called comproportionation, also known as symproportionation.
enol
alkylation
thumb|upright=1.5|Typical route for alkylation of benzene with ethylene and ZSM-5 as a heterogeneous catalystAlkylation is a chemical reaction that entails transfer of an alkyl group. The alkyl group may be transferred as an alkyl carbocation, a free radical, a carbanion, or a carbene (or their equivalents). Alkylating agents are reagents for effecting alkylation. Alkyl groups can also be removed in a process known as dealkylation. Alkylating agents are often classified according to their nucleophilic or electrophilic character. In oil refining contexts, alkylation refers to a particular alkyl
methylation
Methylation, in the chemical sciences, is the addition of a methyl group on a substrate, or the substitution of an atom (or group) by a methyl group. Methylation is a form of alkylation, with a methyl group replacing a hydrogen atom. These terms are commonly used in chemistry, biochemistry, soil science, and biology.
acetylation
class=skin-invert-image|thumb|400px|Salicylic acid is acetylated with acetic anhydride to form [[aspirin and acetic acid as a byproduct]]
glycosylation
Glycosylation is the reaction in which a carbohydrate (or 'glycan'), i.e. a glycosyl donor, is attached to a hydroxyl or other functional group of another molecule (a glycosyl acceptor) in order to form a glycoconjugate. In biology (but not always in chemistry), glycosylation usually refers to an enzyme-catalysed reaction, whereas glycation (also 'non-enzymatic glycation' and 'non-enzymatic glycosylation') may refer to a non-enzymatic reaction.
acylation
In chemistry, acylation is a broad class of chemical reactions in which an acyl group () is added to a substrate. The compound providing the acyl group is called the acylating agent. The substrate to be acylated and the product include the following: alcohols, esters amines, amides arenes or alkenes, ketones A particularly common type of acylation is acetylation, the addition of the acetyl group. Closely related to acylation is formylation, which employ sources of "HCO+ in place of "RCO+".
Transamination
thumb|right|300px|Aminotransfer reaction between an amino acid and an alpha-keto acid
organic reaction
chemical reaction involving organic compounds
carboxylation
Carboxylation is a chemical reaction in which a carboxylic acid is produced by treating a substrate with carbon dioxide. The opposite reaction is decarboxylation. In chemistry, the term carbonation is sometimes used synonymously with carboxylation, especially when applied to the reaction of carbanionic reagents with CO2. More generally, carbonation usually describes the production of carbonates.
leaving group
molecular fragment that departs with a pair of electrons in heterolytic bond cleavage
demethylation
Demethylation is the chemical process resulting in the removal of a methyl group (CH3) from a molecule. A common way of demethylation is the replacement of a methyl group by a hydrogen atom, resulting in a net loss of one carbon and two hydrogen atoms.
Edman degradation
degradation
Wöhler synthesis
chemical reaction
concerted reaction
chemical reaction
hydroboration
right|400px In organic chemistry, hydroboration refers to the addition of a hydrogen-boron bond to certain double and triple bonds involving carbon (, , , and ). This chemical reaction is useful in the organic synthesis of organic compounds.
amination
Amination is the process by which an amine group is introduced into an organic molecule. This type of reaction is important because organonitrogen compounds are pervasive.
Sommelet reaction
chemical reaction
Paternò–Büchi reaction
photochemical reaction
Achmatowicz reaction
organic synthesis
Baeyer–Drewson indigo synthesis
organic reaction in which indigo is prepared from 2-nitrobenzaldehyde and acetone
Formose reaction
chemical reaction involving the formation of sugars from formaldehyde
Elbs reaction
chemical reaction
Tishchenko reaction
chemical reaction (disproportionation of an aldehyde in the presence of an alkoxide)
enolate ion
thumb|right|300px|Resonance structures of an enolate anion.
nitrosation
process of converting organic compounds into nitroso derivatives
cellular glucuronidation
Glucuronidation is often involved in drug metabolism of substances such as drugs, pollutants, bilirubin, androgens, estrogens, mineralocorticoids, glucocorticoids, fatty acid derivatives, retinoids, and bile acids. These linkages involve glycosidic bonds.
Tsuji–Trost reaction
palladium-catalysed substitution reaction
Hooker reaction
chemical reaction
DeMayo reaction
Name reactions
Oxychlorination
In chemistry, oxychlorination is a process for generating the equivalent of chlorine gas (Cl2) from hydrogen chloride and oxygen. This process is attractive industrially because hydrogen chloride is less expensive than chlorine.
von Braun reaction
chemical reaction
Ester pyrolysis
vacuum pyrolysis reaction
Meyers synthesis
Kostanecki acylation
Carbylamine reaction
Method of synthesizing an isocyanide
Barton decarboxylation
Reaction
Danheiser annulation
organic chemical reaction
methanation
Methanation is the conversion of carbon monoxide and carbon dioxide (COx) to methane (CH4) through hydrogenation. The methanation reactions of COx were first discovered by Sabatier and Senderens in 1902.
Riemschneider thiocarbamate synthesis
chemical reaction
transmethylation
thumb|400px|The recovery of methionine from [[homocysteine by transmethylation is depicted in reaction 4. The transmethylation cycle is depicted in reactions 1–4.]]
Reichstein process
chemical process
free-radical reaction
chemical reaction involving free radicals. This reaction type is abundant in organic reactions
Baeyer–Emmerling indole synthesis
Carbometalation
right|frameless|550x550px A carbometallation is any reaction where a carbon-metal bond reacts with a carbon-carbon π-bond to produce a new carbon-carbon σ-bond and a carbon-metal σ-bond. The resulting carbon-metal bond can undergo further carbometallation reactions (oligomerization or polymerization see Ziegler-Natta polymerization) or it can be reacted with a variety of electrophiles including halogenating reagents, carbonyls, oxygen, and inorganic salts to produce different organometallic reagents. Carbometallations can be performed on alkynes and alkenes to form products with high geometric
Boord olefin synthesis
reaction in organic chemistry
Kochi reaction
organic reaction for the decarboxylation of carboxylic acids to alkyl halides
Murai reaction
reaction in organic chemistry
Adams decarboxylation
inorganic chemical reaction
Boekelheide reaction
a rearrangement reaction
Barbier–Wieland degradation
Fischer glycosidation
chemical reaction
Histone acetylation and deacetylation
Biological processes used in gene regulation
Büchner–Curtius–Schlotterbeck reaction
organic reaction
Pinner triazine synthesis
Chemical reaction
Dehalogenation
thumb|Scheme for dehalogenation reaction (R = alkyl or [[aryl group, X = I, Cl, Br, F)]]
Payne rearrangement
isomerization reaction