Titanium minerals

Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite.

Ilmenite is a titanium-iron(II) oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used as white pigment in paints, printing inks, fabrics, plastics, paper, sunscreen, food and cosmetics.

thumb|150px|Titanite crystal model

Perovskite (pronunciation: ) is an orthorhombic calcium titanium oxide mineral composed of calcium titanate (chemical formula ). Its name is also applied to the class of compounds which have the same type of crystal structure as , known as the perovskite structure, which has a general chemical formula for chalcogen (group 16) perovskites, or for the halogen (group 17) perovskites (the kind typically found in modern photovoltaics like photodiodes and solar panels). Many different cations can be embedded in this structure, allowing the development of diverse engineered materials.

Anatase is a metastable mineral form of titanium dioxide (TiO2) with a tetragonal crystal structure. Although colorless or white when pure, anatase in nature is usually a black solid due to impurities. Three other polymorphs (or mineral forms) of titanium dioxide are known to occur naturally: brookite, akaogiite, and rutile, with rutile being the most common and most stable of the bunch. Anatase is formed at relatively low temperatures and found in minor concentrations in igneous and metamorphic rocks. Glass coated with a thin film of TiO2 shows antifogging and self-cleaning properties under u

thumb|Andradite garnet – Jiangxi, Nantan, China. Andradite is a mineral species of the garnet group. It is a nesosilicate, with chemical formula Ca3Fe2Si3O12.

Brookite is the orthorhombic variant of titanium dioxide (TiO2), which occurs in four known natural polymorphic forms (minerals with the same composition but different structure). The other three of these forms are akaogiite (monoclinic), anatase (tetragonal) and rutile (tetragonal). Brookite is rare compared to anatase and rutile and, like these forms, it exhibits photocatalytic activity. Brookite also has a larger cell volume than either anatase or rutile, with 8 TiO2 groups per unit cell, compared with 4 for anatase and 2 for rutile. Iron (Fe), tantalum (Ta) and niobium (Nb) are common impu

Euxenite, or euxenite-(Y) (the official mineralogical name), is a brownish black mineral with a metallic luster.

Benitoite () is a rare, blue, barium titanium cyclosilicate mineral, found in hydrothermally altered serpentinite. It forms in low-temperature, high-pressure environments typical of subduction zones at convergent plate boundaries. Benitoite fluoresces under short-wave ultraviolet light, appearing bright blue to bluish white in color. The more rarely seen clear to white benitoite crystals fluoresce red under long-wave UV light.

Armalcolite () is a titanium-rich mineral with the chemical formula (Mg,Fe2+)Ti2O5. It was first found at Tranquility Base on the Moon in 1969 during the Apollo 11 mission, and is named for Armstrong, Aldrin and Collins, the three Apollo 11 astronauts. Together with tranquillityite and pyroxferroite, it is one of three new minerals that were discovered on the Moon. Armalcolite was later identified at various locations on Earth and has been synthesized in the laboratory. (Tranquillityite and pyroxferroite were also later found at various locations on Earth). The synthesis requires low pressures

Neptunite is a silicate mineral with the formula KNa2Li(Fe2+, Mn2+)2Ti2Si8O24. With increasing manganese it forms a series with mangan-neptunite. is the variety with vanadium replacing the titanium in the formula.

thumb|Betafite, Gunnison, Colorado

Aenigmatite, also known as cossyrite after Cossyra, the ancient name of Pantelleria, is a sodium, iron, titanium inosilicate mineral. The chemical formula is Na2Fe2+5TiSi6O20 and its structure consists of single tetrahedral chains with a repeat unit of four and complex side branches. It forms brown to black triclinic lamellar crystals. It has Mohs hardness of 5.5 to 6 and specific gravity of 3.74 to 3.85. Aenigmatite forms a solid-solution series with wilkinsonite, Na2Fe2+4Fe3+2Si6O20.

Aeschynite-(Y) (or Aeschinite-(Y), Aeschynite-(Yt), Blomstrandine, Priorite) is a rare earth mineral of yttrium, calcium, iron, thorium, titanium, niobium, oxygen, and hydrogen with the chemical formula . Its name comes from the Greek word for "shame". Its Mohs scale rating is 5 to 6.

Lorenzenite is a rare sodium titanium silicate mineral with the formula Na2Ti2Si2O9 It is an orthorhombic mineral, variously found as colorless, grey, pinkish, or brown crystals.

Zirconolite is a mineral, calcium zirconium titanate; formula CaZrTi2O7. Some examples of the mineral may also contain thorium, uranium, cerium, niobium and iron; the presence of thorium or uranium would make the mineral radioactive. It is black or brown in color.

Polycrase or polycrase-(Y) is a black or brown metallic complex uranium yttrium oxide mineral with the chemical formula . It is amorphous. It has a Mohs hardness of 5 to 6 and a specific gravity of 5. It is radioactive due to its uranium content (around 6%). It occurs in granitic pegmatites.

Pyrophanite is a manganese titanium oxide mineral with formula: MnTiO3. It is a member of the ilmenite group. It is a deep red to greenish black mineral which crystallizes in the trigonal system.

Tausonite is the rare naturally occurring mineral form of strontium titanate: chemical formula: SrTiO3. It occurs as red to orange brown cubic crystals and crystal masses.

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Zirkelite is an oxide mineral with the chemical formula . It occurs as well-formed fine sized isometric crystals. It is a black, brown or yellow mineral with a hardness of 5.5 and a specific gravity of 4.7.

Sabinaite (Na4Zr2TiO4(CO3)4) is a rare carbonate mineral. It crystallizes in the monoclinic crystal system as colorless to white prisms within cavities. It is more typically found as powdery coatings and masses. It has a specific gravity of 3.36.

Macedonite is a mineral named by Radusinović and Markov in 1971. It has the elemental formula PbTiO3 and exhibits tetragonal crystal system. The type locality is near Crni Kamen, Selecka Planina, Prilep Municipality, North Macedonia. It can be confused with perovskite. It is found in an amazonite-rich area.

Panguite is a type of titanium oxide mineral first discovered as an inclusion within the Allende meteorite, and first described in 2012.

Nenadkevichite is a rare silicate mineral containing niobium with the chemical formula . It forms brown to yellow to rose colored orthorhombic dipyramidal crystals with a dull to earthy luster. It has a Mohs hardness of 5 and a specific gravity of 2.86.

Wassonite is a scarce titanium sulfide mineral with the chemical formula TiS. Its discovery was announced in a 2011 NASA press release as a single small grain within an enstatite chondrite meteorite called "Yamato 691", which was found during a 1969 Japanese expedition to Antarctica. This grain represents the first observation in nature of the synthetic compound titanium(II) sulfide.

Cafetite is a rare titanium oxide mineral with formula ·. It is named for its composition, Ca-Fe-Ti.

Warwickite is an iron magnesium titanium borate mineral with the chemical formula or . It occurs as brown to black prismatic orthorhombic crystals which are vitreous and transparent. It has a Mohs hardness of 3 to 4 and a specific gravity of 3.36.

Geikielite is a magnesium titanium oxide mineral with formula: MgTiO3. It is a member of the ilmenite group. It crystallizes in the trigonal system forming typically opaque, black to reddish black crystals.

Akaogiite (IMA symbol Aka) is an exceedingly rare mineral, one of the natural forms of titanium dioxide (TiO2). It is a high-pressure polymorph of TiO2, along with anatase, brookite and another high-pressure phase called "TiO2 II". Rutile is the stable polymorph of TiO2, most commonly found at standard temperatures and pressures.

Cleusonite is a member of the crichtonite group of minerals with the chemical formula . This group of minerals contains approximately thirteen complex metal titanates. The structures of minerals of this group is complicated by frequent fine-scale twinning and metamictization due to radioactive elements. The crichtonite group consists of members of related mineral species of the type A{BC2D6E12}O38 which are characterized by their predominant cations (as seen in crichtonite (Sr), senaite (Pb), davidite (REE + U), landauite (Na), loveringite (Ca), lindsleyite (Ba), and mathiasite (K).

Azoproite is a rare manganese iron borate mineral with the chemical formula (Mg,Fe)(Fe,Ti,Mg)(BO)O. It was first identified near Lake Baikal, Russia. It was named after the Association pour l'Etude Géologique des Zones Profondes de l'Ecorce Terrestre, whose acronym is AZOPRO in French.

thumb|Asbecasite found at its type locality Asbecasite is a calcium titanium beryllium arsenite silicate mineral with the chemical formula . Its type locality is the Binn valley in Switzerland.

Nezhilovite is a magnetoplumbite mineral discovered in 1996 by Bermanec et al., who gave it the ideal elemental formula PbZn2(Mn4+, Ti4+)2Fe8O19. It forms black magnetic crystals up to 1mm with a tabular, hexagonal outline. The mineral is optically anisotropic, bireflectant and is paramagnetic. The minerals occurs in a matrix of "pink dolomitic marble from a Precambrian metamorphic complex of gneisses, schists and marbles in the Nezhilovo area" of the Pelagonian massif.

Zimbabweite is a yellow brown mineral with orthorhombic crystal habit and a hardness of 5, with formula . It is generally classed as an arsenite but is notable for also containing niobium and tantalum. It was discovered in 1986 in kaolinized pegmatite, i.e. weathered to clay, in Zimbabwe.

Haggertyite is a rare barium, iron, magnesium, titanate mineral: Ba(Fe2+6Ti5Mg)O19 first described in 1996 from the Crater of Diamonds State Park near Murfreesboro in Pike County, Arkansas. The microscopic metallic mineral crystallizes in the hexagonal system and forms tiny hexagonal plates associated with richterite and serpentinitized olivine of mafic xenoliths in the lamproite host rock. It is an iron(II) rich member of the magnetoplumbite group. It is a light grey opaque mineral with calculated Mohs hardness of 5.

Joaquinite-(Ce) is a rare silicate mineral with the chemical formula NaBa2Ce2Fe2+Ti2Si8O26(OH)·2H2O. It crystallizes in the monoclinic system with orthorhombic pseudomorphism and exhibits tabular crystals.

Titanowodginite is a mineral with the chemical formula MnTiTa2O8. Titanowodginite has a Mohs hardness of 5.5 and a vitreous luster. It is an iridescent dark brown to black crystal that commonly forms in a matrix of smoky quartz or white beryl in a complex zoned pegmatite.

Loveringite is a rare metallic oxide mineral of the crichtonite group with the chemical formula . It is a late-stage magmatic mineral, formed in the residual melt of mafic layered intrusions in either the olivine-chromite, pyroxene, or plagioclase-rich layers.

Ferri-obertiite is an amphibole group mineral that was formally approved by the International Mineralogical Association in 2015. It has the chemical formula Na(Na2)(Mg3Fe3+Ti)(Si8O22)O2.

Delindeite is a very rare titanium sorosilicate mineral in the lamprophyllite group and seidozerite supergroup. It was named in honor of Henry Samuel de Linde, an amateur mineralogist who was the former owner of the Diamond Jo quarry, Arkansas, where the mineral was first discovered in 1987. It is a secondary mineral formed under oxidizing conditions from a titanium-bearing nepheline and syenite.

Jinshajiangite is a rare silicate mineral named after the Jinshajiang river in China. Its currently accepted formula is BaNaFe4Ti2(Si2O7)2O2(OH)2F. It gives a name of the jinshajiangite group. The mineral is associated with alkaline rocks. In jinshajiangite, there is a potassium-to-barium, calcium-to-sodium, manganese-to-iron and iron-to-titanium diadochy substitution. Jinshajiangite is the iron-analogue of surkhobite and perraultite. It is chemically related to bafertisite, cámaraite and emmerichite. Its structure is related to that of bafertisite. Jinshajiangite is a titanosilicate with hete

Zorite is a silicate mineral with the chemical formula of . It is named because of its pink color, after the Russian word "zoria" which refers to the rosy hue of the sky at dawn. It is primarily found in Mount Karnasurta, Lovozero Massif, Kola Peninsula, Russia. The Lovozero Massif is an area with an igneous mountain range, home to various types of minerals such as eudialyte, loparite, and natrosilitite.

thumb | 220x124px | right | alt= SEM BSE images showing kaitianite (Ktn) with tistarite (Tta), Ti,Al,Zr-oxide (TAZ), MgTi3+2Al4SiO12 phase (MTAS), spinel (Spl), sapphirine (Spr), and Ti-sulfide (Ti-S) in corundum Grain 1125C2. The upper rectangular area in (b) are enlarged in (c) | SEM BSE images showing kaitianite (Ktn) with tistarite (Tta), Ti,Al,Zr-oxide (TAZ), MgTi3+2Al4SiO12 phase (MTAS), spinel (Spl), sapphirine (Spr), and Ti-sulfide (Ti-S) in corundum Grain 1125C2. The upper rectangular area in (b) are enlarged in (c) Tistarite is an exceedingly rare mineral with the formula Ti2O3, thus

Alluaivite is a rare mineral of the eudialyte group, with complex formula written as . It is unique among the eudialyte group as the only titanosilicate (other representatives of the group are usually zirconosilicates). The two dual-nature minerals of the group, being both titano- and zirconosilicates, are labyrinthite and dualite. They both contain alluaivite module in their structures. Alluaivite is named after Mt. Alluaiv in Lovozero Tundry massif, Kola Peninsula, Russia, where it is found in ultra-agpaitic, hyperalkaline pegmatites.

Grossmanite is a very rare mineral of the pyroxene group, with formula CaTi3+AlSiO6. It is the titanium-dominant member. Grossmanite is unique in being a mineral with trivalent titanium, a feature shared with tistarite, Ti2O3. Titanium in minerals is almost exclusively tetravalent. Grossmanite stands for titanium-analogue of davisite, esseneite and kushiroite – other members of the pyroxene group. Both grossmanite and tistarite come from the famous Allende meteorite.

Schreyerite (V2Ti3O9), is a vanadium, titanium oxide mineral found in the Lasamba Hill, Kwale district in Coast Province, Kenya. It is polymorphous with kyzylkumite.

Altisite (IMA symbol: Ati) is an exceedingly rare alkaline titanium aluminosilicate chloride mineral with formula Na3K6Ti2Al2Si8O26Cl3, from alkaline pegmatites. It is named after its composition (ALuminium, TItanium, and SIlicon).

Nabalamprophyllite has a general formula of . The name is given for its composition (Naba, meaning sodium, Na and barium, Ba) and relation to other lamprophyllite-group minerals. Lamprophyllite is a rare Ti-bearing silicate mineral usually found in intrusive igneous rocks.

Achyrophanite ((K,Na)3(Fe3+,Ti,Al,Mg)5O2(AsO4)5) is a yellow mineral, discovered in 2018 and described in 2025.

Zircophyllite is a complex mineral, formula . It crystallizes in the triclinic – pinacoidal crystal class as dark brown to black micaceous plates. It has perfect 001 cleavage, a Mohs hardness of 4 to 4.5 and a specific gravity of 3.34. Its indices of refraction are nα=1.708 nβ=1.738 nγ=1.747 and it has a 2V optical angle of 62°.

Dualite is a very rare and complex mineral of the eudialyte group, its complexity being expressed in its formula . The formula is simplified as it does not show the presence of cyclic silicate groups. The name of the mineral comes from its dual nature: zircono- and titanosilicate at once. Dualite has two modules in its structure: alluaivite one and eudialyte one. After alluaivite and labyrinthite it stands for third representative of the eudialyte group with essential titanium.

Achalaite ((Fe2+, Mn)(Ti, Fe3+, Ta)(Nb, Ta)2O8) is a black mineral of the wodginite group, first discovered in 2013.

Alsakharovite-Zn (IMA symbol: Ask-Zn) is an extremely rare alkaline strontium zinc titanium silicate mineral from the cyclosilicates class, with the chemical formula , from alkaline pegmatites. It belongs to the labuntsovite group.

Pabstite is a barium tin titanium silicate mineral that is found in contact metamorphosed limestone. It belongs to the benitoite group of minerals. The chemical formula of pabstite is . It is found in Santa Cruz, California. The crystal system of the mineral is hexagonal.