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perovskite

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perovskite

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Perovskite (pronunciation: ) is an orthorhombic calcium titanium oxide mineral composed of calcium titanate (chemical formula ). Its name is also applied to the class of compounds which have the same type of crystal structure as , known as the perovskite structure, which has a general chemical formula for chalcogen (group 16) perovskites, or for the halogen (group 17) perovskites (the kind typically found in modern photovoltaics like photodiodes and solar panels). Many different cations can be embedded in this structure, allowing the development of diverse engineered materials.

Key facts

Mineral.name
Perovskite
Mineral.category
Oxide minerals
Mineral.image
Perovskite-155026.jpg
Mineral.caption
Crystals of perovskite on matrixSize:
Mineral.IMAsymbol
Prv
Mineral.molweight
135.96 g/mol
Mineral.strunz
4.CC.30
Mineral.system
Orthorhombic
Mineral.class
Dipyramidal (mmm) H-M symbol: (2/m 2/m 2/m)
Mineral.symmetry
Pbnm
Mineral.color
Black, reddish brown, pale yellow, yellowish orange
Mineral.habit
Pseudo cubic – crystals show a cubic outline
Mineral.cleavage
[100] good, [010] good, [001] good
Mineral.twinning
complex penetration twins
Mineral.fracture
Conchoidal
Mineral.mohs
5.0–5.5
Mineral.luster
Adamantine to metallic; may be dull
Mineral.refractive
nα = 2.3, nβ = 2.34, nγ = 2.38

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Wikidata facts

Image
Perovskite - Perovskite Hill, Magnet Cove, Hot Spring Co, Arkansas, USA.jpg
Show 8 more facts
Nickel-Strunz '10th ed', review of (9th ed/ 2009 update)
4.CC.30
Commons category
Perovskite
chemical formula
CaTiO₃
Nickel-Strunz 9th edition (updated 2009)
4.CC.30
Mohs' hardness
5.5
density
4
IMA Mineral Symbol
Prv
Strunz 8th edition (series ID, updated)
IV/C.07
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Article

17 sections
Contents
  • History
  • Occurrence
  • In stars and brown dwarfs
  • Physical properties
  • Perovskite derivatives
  • Double perovskites
  • Crystallographic principles and ordering mechanisms
  • Common distortion modes and Glazer tilt patterns
  • Electronic and magnetic structure trends
  • Defect chemistry and antisite disorder
  • Representative functional materials
  • Lower dimensional perovskites
  • Lead-free halide perovskites
  • Chiral perovskites
  • See also
  • References
  • External links

Perovskite (pronunciation: ) is an orthorhombic calcium titanium oxide mineral composed of calcium titanate (chemical formula ). Its name is also applied to the class of compounds which have the same type of crystal structure as , known as the perovskite structure, which has a general chemical formula for chalcogen (group 16) perovskites, or for the halogen (group 17) perovskites (the kind typically found in modern photovoltaics like photodiodes and solar panels). Many different cations can be embedded in this structure, allowing the development of diverse engineered materials.

== History == The mineral was discovered in the Ural Mountains of Russia by Gustav Rose in 1839 and is named after Russian mineralogist Lev Perovski (1792–1856). Perovskite's notable crystal structure was first described by Victor Goldschmidt in 1926 in his work on tolerance factors. The crystal structure was later published in 1945 from X-ray diffraction data on barium titanate by Helen Dick Megaw.

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