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1,4,7-trithionane

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EntityQ4545688· pop 8· linked from 8 articles

1,4,7-trithionane

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Also known as [9]aneS3, 1,4,7-trithiacyclononane

1,4,7-Trithiacyclononane, also called 9-ane-S3, is the thia-crown ether with the formula (CH2CH2S)3. This cyclic thioether is most often encountered as a tridentate ligand in coordination chemistry, where it forms transition metal thioether complexes.

Chemical data

Formula
C6H12S3
Molecular weight
180.4 g/mol
IUPAC name
1,4,7-trithionane

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Drug data · ChEMBL

Molecule type
Small molecule

via ChEMBL · EBI

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Encyclopedic overview

2 sections
Contents
  • Synthesis
  • References

1,4,7-Trithiacyclononane, also called 9-ane-S3, is the thia-crown ether with the formula (CH2CH2S)3. This cyclic thioether is most often encountered as a tridentate ligand in coordination chemistry, where it forms transition metal thioether complexes.

9-ane-S3 forms complexes with many metal ions, including those considered hard, such as copper(II) and iron(II). Most of its complexes have the formula [M(9-ane-S3)2]2+ and are octahedral. The point group of [M(9-ane-S3)2]2+ is S6.

Excerpted from Wikipedia’s “1,4,7-trithionane” article, available under the CC BY-SA 4.0 licence.

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