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DIOP
Sign in to saveAlso known as {[(4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl]bis(methylene)}bis(diphenylphosphane)
DIOP (2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane) is an organophosphorus compound that is used as a chiral ligand in asymmetric catalysis. It is a white solid that is soluble in organic solvents.
Chemical data
- Formula
- C31H32O2P2
- Molecular weight
- 498.5 g/mol
- IUPAC name
- [5-(diphenylphosphanylmethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl-diphenylphosphane
- SMILES
- CC1(OC(C(O1)CP(C2=CC=CC=C2)C3=CC=CC=C3)CP(C4=CC=CC=C4)C5=CC=CC=C5)C
- InChIKey
- VCHDBLPQYJAQSQ-UHFFFAOYSA-N
- XLogP
- 6.2
- Polar surface area
- 18.5 Ų
- H-bond donors
- 0
- H-bond acceptors
- 2
- Formal charge
- 0
via PubChem
Wikidata facts
- Subclass of
- organic compound, having C-P covalent bound
- Mass
- 498.18775352399996
Show 3 more facts
- Commons category
- DIOP
- canonical SMILES
- CC1(C)OC(CP(c2ccccc2)c2ccccc2)C(CP(c2ccccc2)c2ccccc2)O1
- chemical formula
- C₃₁H₃₂O₂P₂
Sources (1)
via Wikidata · CC0
~2 min read
Encyclopedic overview
2 sectionsContents
- Use
- References
{{Chembox | ImageFile = (S,S)-DIOP.svg | ImageSize = | ImageAlt = | IUPACName = O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane | PIN = {[(4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl]bis(methylene)}bis(diphenylphosphane) | OtherNames = (−)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane (−)-1,4-Bis(diphenylphosphino)-1,4-dideoxy-2,3-O-isopropylidene-L-threitol (+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane (+)-1,4-Bis(diphenylphosphino)-1,4-dideoxy-2,3-O-isopropylidene-L-threitol |Section1= |Section2= |Section3= }}
DIOP (2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane) is an organophosphorus compound that is used as a chiral ligand in asymmetric catalysis. It is a white solid that is soluble in organic solvents.
Excerpted from Wikipedia’s “DIOP” article, available under the CC BY-SA 4.0 licence.