Hexagonal minerals

thumbGraphite () is a crystalline allotrope (form) of the element carbon. It consists of many stacked layers of graphene, typically in excess of hundreds of layers. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on a large scale (1.3million metric tons per year in 2022) for uses in many critical industries including refractories (50%), lithium-ion batteries (18%), foundries (10%), and lubricants (5%), among others (17%). Graphite converts to diamond under extremely high pressure and temperature. Graphite's

Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of OH−, F− and Cl− ion, respectively, in the crystal. The formula of the admixture of the three most common endmembers is written as Ca10(PO4)6(OH,F,Cl)2, and the crystal unit cell formulae of the individual minerals are written as Ca10(PO4)6(OH)2, Ca10(PO4)6F2 and Ca10(PO4)6Cl2.

Vanadinite is a mineral belonging to the apatite group of phosphates, with the chemical formula Pb5(VO4)3Cl. It is one of the main industrial ores of the metal vanadium and a minor source of lead. A dense, brittle mineral, it is usually found in the form of red hexagonal crystals. It is an uncommon mineral, formed by the oxidation of lead ore deposits such as galena. First discovered in 1801 in Mexico, vanadinite deposits have since been unearthed in South America, Europe, Africa, and North America.

Molybdenite is a mineral of molybdenum disulfide, MoS2. Similar in appearance and feel to graphite, molybdenite has a lubricating effect that is a consequence of its layered structure. The atomic structure consists of a sheet of molybdenum atoms sandwiched between sheets of sulfur atoms. The Mo-S bonds are strong, but the interaction between the sulfur atoms at the top and bottom of separate sandwich-like tri-layers is weak, resulting in easy slippage as well as cleavage planes. Molybdenite crystallizes in the hexagonal crystal system as the common polytype 2H and also in the trigonal system a

Nepheline (), also called nephelite, is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate (Na3KAl4Si4O16) that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites. It is used in glass and ceramic manufacturing and other industries, and has been investigated as an ore of aluminium.

thumb|Covellite (gray) replacing and embaying chalcopyrite (light), polished section from Horn Silver Mine, San Francisco Mining District, Utah. Enlarged to 210 diameters. |alt= Covellite (also known as covelline) is a rare copper sulfide mineral with the formula CuS. This indigo blue mineral is commonly a secondary mineral in limited abundance and although it is not an important ore of copper itself, it is well known to mineral collectors.

thumb|Hydroxyapatite thumb|Needle-like hydroxyapatite crystals on stainless steel. Scanning electron microscope picture from [[University of Tartu.]] thumb|Nanoscale coating of Ca-HAp, image taken with Scanning probe microscopy|scanning probe microscope thumbnail|right|A 3D visualization of half of a hydroxyapatite unit cell, from x-ray crystallography Hydroxyapatite (IMA name: hydroxylapatite) (Hap, HAp, or HA) is a naturally occurring mineral form of apatite with the formula , often written to denote that the crystal unit cell comprises two entities. It is the hydroxyl endmember of the compl

Nickeline or niccolite is the mineral form of nickel arsenide. The naturally occurring mineral contains roughly 43.9% nickel and 56.1% arsenic by mass, but composition of the mineral may vary slightly.

Wurtzite is a zinc and iron sulfide mineral with the chemical formula , a less frequently encountered structural polymorph form of sphalerite. The iron content is variable up to eight percent. It is trimorphous with matraite and sphalerite.

Pyromorphite is a mineral species composed of lead chlorophosphate: Pb5(PO4)3Cl, sometimes occurring in sufficient abundance to be mined as an ore of lead. Crystals are common, and have the form of a hexagonal prism terminated by the basal planes, sometimes combined with narrow faces of a hexagonal pyramid. Crystals with a barrel-like curvature are not uncommon. Globular and reniform masses are also found.

Benitoite () is a rare, blue, barium titanium cyclosilicate mineral, found in hydrothermally altered serpentinite. It forms in low-temperature, high-pressure environments typical of subduction zones at convergent plate boundaries. Benitoite fluoresces under short-wave ultraviolet light, appearing bright blue to bluish white in color. The more rarely seen clear to white benitoite crystals fluoresce red under long-wave UV light.

Moissanite () is naturally occurring silicon carbide and its various crystalline polymorphs. It has the chemical formula SiC and is a rare mineral, discovered by the French chemist Henri Moissan in 1893. Silicon carbide or moissanite is useful for commercial and industrial applications due to its hardness, optical properties, and thermal conductivity.

Zincite is the mineral form of zinc oxide (ZnO). Its crystal form is rare in nature; a notable exception to this is at the Franklin and Sterling Hill Mines in New Jersey, an area also famed for its many fluorescent minerals. It has a hexagonal crystal structure and a color that depends on the presence of impurities. The zincite found at the Franklin Furnace is red-colored, mostly due to iron and manganese dopants, and associated with willemite and franklinite.

Greenockite, also cadmium blende or cadmium ochre (obsolete) is a rare cadmium bearing metal sulfide mineral consisting of cadmium sulfide (CdS) in crystalline form. Greenockite crystallizes in the hexagonal system. It occurs as massive encrustations and as hemimorphic six-sided pyramidal crystals which vary in color from a honey yellow through shades of red to brown. The Mohs hardness is 3 to 3.5 and the specific gravity is 4.8 to 4.9.

Painite is a rare borate mineral. It was first found in Myanmar by British mineralogist and gem dealer Arthur C.D. Pain who misidentified it as ruby, until it was discovered as a new gemstone in the 1950s. When it was confirmed as a new mineral species, the mineral was named after him.

Mimetite is a lead arsenate chloride mineral () which forms as a secondary mineral in lead deposits, usually by the oxidation of galena and arsenopyrite. The name derives from the Greek mimetes, meaning "imitator" and refers to mimetite's resemblance to the mineral pyromorphite. This resemblance is not coincidental, as mimetite forms a mineral series with pyromorphite () and with vanadinite (). Notable occurrences are Mapimi, Durango, Mexico, and Tsumeb, Namibia.

The mineral bastnäsite (or bastnaesite) is one of a family of three fluorocarbonate minerals, which includes bastnäsite-(Ce) with a formula of (Ce, La)CO3F, bastnäsite-(La) with a formula of (La, Ce)CO3F, and bastnäsite-(Y) with a formula of (Y, Ce)CO3F. Some of the bastnäsites contain OH− instead of F− and receive the name of hydroxylbastnasite. Most bastnäsite is bastnäsite-(Ce), and cerium is by far the most common of the rare earths in this class of minerals. Bastnäsite and the phosphate mineral monazite are the two largest sources of cerium and other rare-earth elements.

Troilite () is a rare iron sulfide mineral with the simple formula of FeS. It is the iron-rich endmember of the pyrrhotite group. Pyrrhotite has the formula Fe(1−x)S (x = 0 to 0.2) which is iron deficient. As troilite lacks the iron deficiency which gives pyrrhotite its characteristic magnetism, troilite is non-magnetic.

Cancrinite is a complex carbonate and silicate of sodium, calcium and aluminium with the formula Na6Ca2[(CO3)2|Al6Si6O24]·2H2O. It is classed as a member of the feldspathoid group of minerals; the alkali feldspars that are poor in silica. Yellow, orange, pink, white or even blue, it has a vitreous or pearly luster; a hardness of 5–6 and an uneven conchoidal fracture. It is unusual among the silicate minerals in that it will effervesce with hydrochloric acid due to the associated carbonate ions.

Sugilite ( ) is a relatively rare pink to purple cyclosilicate mineral with the complex chemical formula KNa2(Fe, Mn, Al)2Li3Si12O30. Sugilite crystallizes in the hexagonal system with prismatic crystals. The crystals are rarely found and the form is usually massive. It has a Mohs hardness of 5.5–6.5 and a specific gravity of 2.75–2.80. It is mostly translucent. Sugilite was first described in 1944 by the Japanese petrologist Ken-ichi Sugi (1901–1948) for an occurrence on Iwagi Islet, Japan, where it is found in an aegirine syenite intrusive stock. It is found in a similar environment at

Taaffeite (; BeMgAl4O8) is a mineral, named after its discoverer Richard Taaffe (1898–1967) who found the first sample, a cut and polished gem, in October 1945 in a jeweler's shop in Dublin, Ireland. As such, it is the only gemstone to have been initially identified from a faceted stone. Taaffeite is a million times rarer than diamonds and comes in shades of purple, pink, red. Most pieces of the gem, prior to Taaffe, had been misidentified as spinel. For many years afterwards, it was known only in a few samples, and it is still one of the rarest gemstone minerals in the world.

Algodonite is a copper arsenide mineral with formula: Cu6As. It is a gray white metallic mineral crystallizing in the hexagonal system. It has a Mohs hardness of 4 and a specific gravity of 8.38 – 8.72.

beryl var.

Jeremejevite is an aluminium borate mineral with variable fluoride and hydroxide ions. Its chemical formula is . It is considered as one of the rarest, thus one of the most expensive stones. For nearly a century, it was considered as one of the rarest gemstones in the world.

Tranquillityite is a silicate mineral with formula (Fe2+)8Ti3Zr2 Si3O24. It is mostly composed of iron, oxygen, silicon, zirconium and titanium with smaller fractions of yttrium and calcium. It is named after the Mare Tranquillitatis (Sea of Tranquility), the place on the Moon where the rock samples were found during the 1969 Apollo 11 mission. It was the last mineral brought from the Moon which was thought to be unique, with no counterpart on Earth, until it was discovered in Australia in 2011.

Iodyrite or iodargyrite is a natural mineral form of silver iodide.

Vaterite is a mineral, a polymorph of calcium carbonate (CaCO3). It was named after the German mineralogist Heinrich Vater. It is also known as mu-calcium carbonate (μ-CaCO3). Vaterite belongs to the hexagonal crystal system, whereas calcite is trigonal and aragonite is orthorhombic.

Allargentum is a mineral from the class of antimonides, superclass of sulfides and sulfosalts (sometimes ascribed to the natural elements and alloys class), with formula written as Ag1−xSbx, where x = 0.09–0.16. This moderately rare mineral is found in silver ores and is therefore named from the Greek ἄλλος (allos, "another") and the Latin argentum ("silver"). Its Vickers hardness is 172–203.

Bentorite is a mineral with the chemical formula . It is colored violet to light violet. Its crystals are hexagonal to dihexagonal dipyramidal. It is transparent and has vitreous luster. It has perfect cleavage. It is not radioactive. Bentorite is rated 2 on the Mohs scale.

Gmelinite is a series of rare zeolite minerals. The most common member is gmelinite-Na; others are gmelinite-Ca and gmelinite-K. It is closely related to the very similar mineral chabazite. Gmelinite was named as a single species in 1825 after Christian Gottlob Gmelin (1792–1860) professor of chemistry and mineralogist from Tübingen, Germany, and in 1997 it was raised to the status of a series.Gmelinite-Na has been synthesised from Na-bearing aluminosilicate gels. The naturally occurring mineral forms striking crystals, shallow, six sided double pyramids, which can be colorless, white, pale ye

Osumilite is a very rare potassium-sodium-iron-magnesium-aluminium silicate mineral. Osumilite is part of the milarite group (also known as the milarite-osumilite group) of cyclosilicates.

Thaumasite is a calcium silicate mineral, containing Si atoms in unusual octahedral configuration, with chemical formula Ca3Si(OH)6(CO3)(SO4)·12H2O, also sometimes more simply written as CaSiO3·CaCO3·CaSO4·15H2O.

Chaoite, or white carbon, is a mineral described as an allotrope of carbon, whose existence is disputed. It was discovered in shock-fused graphite gneiss from the Ries crater in Bavaria. It has been described as slightly harder than graphite, with a reflection colour of grey to white. From its electron diffraction pattern, the mineral has been considered to have a carbyne structure, the linear acetylenic carbon allotrope of carbon. A later report has called this identification, and the very existence of carbyne phases, into question, arguing that the new reflections in the diffraction pattern

Breithauptite is a nickel antimonide mineral with the simple formula NiSb. Breithauptite is a metallic opaque copper-red mineral crystallizing in the hexagonal - dihexagonal dipyramidal crystal system. It is typically massive to reniform in habit, but is observed as tabular crystals. It has a Mohs hardness of 3.5 to 4 and a specific gravity of 8.23.

Cacoxenite is an iron aluminium phosphate mineral with formula: Fe3+24Al(PO4)17O6(OH)12·17(H2O). Cacoxenite is associated with iron ores. The name comes from the Greek κăκός for "bad" or "evil" and ξένος for "guest" because the phosphorus content of cacoxenite lessens the quality of iron smelted from ore containing it.

Connellite is a rare mineral species, a hydrous copper chloro-sulfate, Cu19(OH)32(SO4)Cl4·3H2O, crystallizing in the hexagonal system. It occurs as tufts of very delicate acicular crystals of a fine blue color, and is associated with other copper minerals of secondary origin, such as cuprite and malachite. Its occurrence in Cornwall, England was noted by Philip Rashleigh in 1802, and it was first examined chemically by Prof Arthur Connell FRSE in 1847, after whom it is named.

Bromellite, whose name derives from the Swedish chemist Magnus von Bromell (1670–1731), is a white oxide mineral. The mineral form of beryllium oxide, it is found in complex pegmatitic manganese-iron deposits, but is more frequently made synthetically. This is a rare mineral to encounter in its natural state, but it has been made synthetically for over 40 years.

Mixite is a rare copper bismuth arsenate mineral with formula: BiCu6(AsO4)3(OH)6·3(H2O). It crystallizes in the hexagonal crystal system typically occurring as radiating acicular prisms and massive encrustations. The color varies from white to various shades of green and blue. It has a Mohs hardness of 3.5 to 4 and a specific gravity of 3.8. It has an uneven fracture and a brilliant to adamantine luster.

Zinkenite is a steel-gray metallic sulfosalt mineral composed of lead antimony sulfide Pb9Sb22S42. Zinkenite occurs as acicular needle-like crystals.

Hanksite is a sulfate mineral, distinguished as one of only a handful that contain both carbonate and sulfate ions (a sulfate carbonate). It has the chemical formula Na22K(SO4)9(CO3)2Cl.

Hibonite is a mineral with the chemical formula , occurring in various colours, with a hardness of 7.5–8.0 and a hexagonal crystal structure. It is rare, but is found in high-grade metamorphic rocks on Madagascar. Some presolar grains in primitive meteorites consist of hibonite. Hibonite also is a common mineral in the Ca-Al-rich inclusions found in some chondritic meteorites. Hibonite is closely related to hibonite-Fe (IMA 2009-027, ) an alteration mineral from the Allende meteorite. Hibonites were among the first minerals to form as the disk of gas and dust swirling around the young sun cool

Fluorapatite, often with the alternate spelling of fluoroapatite, is a phosphate mineral with the formula Ca5(PO4)3F (calcium fluorophosphate). Fluorapatite is a hard crystalline solid. Although samples can have various colors (green, brown, blue, yellow, violet, or colorless), the pure mineral is colorless, as expected for a material lacking transition metals. Along with hydroxylapatite, it can be a component of tooth enamel, especially in individuals who use fluoridated toothpaste, but for industrial use both minerals are mined in the form of phosphate rock, whose usual mineral composition i

Erionite is a naturally occurring asbestiform mineral that belongs to a group of minerals called zeolites. It usually is found in volcanic ash that has been altered by weathering and ground water. Erionite forms brittle, wool-like fibrous masses in the hollows of rock formations and has an internal molecular structure similar to chabazite. This mineral is likely as toxic as asbestos; however, erionite is not currently regulated by the U.S. Environmental Protection Agency and there are no occupational exposure limits for erionite fibers. Erionite was first described by A.S. Eakle in 1898, as wh

Alforsite is a barium phosphate chloride mineral with formula: Ba5(PO4)3Cl. It was discovered in 1981, and named to honor geologist John T. Alfors (1930–2005) of the California Geological Survey for his work in the area where it was discovered.

Vishnevite, or sulfatic cancrinite, is a mineral of the cancrinite group with the chemical formula (Na, Ca, K)6(Si, Al)12O24[(SO4),(CO3), Cl2]2-4·nH2O. It has hexagonal crystals.

Kalsilite (KAlSiO4) is a vitreous white to grey feldspathoidal mineral that is found in some potassium-rich lavas, such as from Chamengo Crater in Uganda. It has a relative hardness of 5.5.

Oregonite, Ni2FeAs2 is a nickel iron arsenide mineral first described from Josephine Creek, Oregon, United States.

Berborite is a beryllium borate mineral with the chemical formula Be2(BO3)(OH,F)·(H2O). It is colorless and leaves a white streak. Its crystals are hexagonal to pyramidal. It is transparent and has vitreous luster. It is not radioactive. Berborite is rated 3 on the Mohs Scale.

thumb|alt=X-ray diffraction patterns for six-line and two-line ferrihydrite.|X-ray diffraction patterns for six-line (top) and two-line (bottom) ferrihydrite. Cu Kα radiation.

Stützite or stuetzite is a silver telluride mineral with formula: Ag5−xTe3 (with x = 0.24 to 0.36) or Ag7Te4.

Stibiopalladinite is a mineral containing the chemical elements palladium and antimony. Its chemical formula is Pd5Sb2. It is a silvery white to steel grey opaque mineral crystallizing in the hexagonal crystal system.

Zemannite is a very rare oxide mineral with the chemical formula Mg0.5ZnFe3+[TeO3]3·4.5H2O. It crystallizes in the hexagonal crystal system and forms small prismatic brown crystals. Because of the rarity and small crystal size, zemannite has no applications and serves as a collector's item.

Poudretteite is an extremely rare mineral and gemstone that was first discovered as minute crystals in Mont St. Hilaire, Quebec, Canada, during the 1960s. The mineral was named for the Poudrette family because they operated a quarry in the Mont St. Hilaire area where poudretteite was originally found, and the quarry is currently owned by the United Kingdom based Salmon Mining Industries Inc. Poudretteite has a barely detectable radioactivity.

Feroxyhyte is an oxide/hydroxide of iron, δ-Fe3+O(OH). Feroxyhyte crystallizes in the hexagonal system. Feroxyhyte forms as brown, rounded to concretionary masses. Feroxyhyte is an opaque, magnetic mineral with a yellow streak and a relative density of 4.2.

Achávalite is a selenide mineral that is a member of the nickeline group. It has only been found in a single Argentinian mine system, being first discovered in 1939 in a selenide deposit. The type locality is Cacheuta mine, Sierra de Cacheuta, Mendoza, Argentina.

Nsutite is a manganese oxide mineral with formula: (Mn4+1−xMn2+xO2-2x(OH)2x where x = 0.06–0.07). It is found in most large manganese deposits and was first discovered in Nsuta, Ghana. Since then, it has been found worldwide. Nsutite is a dull mineral with a hardness of 6.5–8.5 and an average specific gravity of 4.45. Nsutite has been used as a cathode in zinc–carbon batteries, but synthetic manganese oxide is gradually replacing it.

Quintinite is a carbonate mineral with the chemical formula Mg4Al2(OH)12CO3⋅3H2O.

Britholite-(Ce) is a rare radioactive mineral with the chemical formula . It comes in a variety of different colors. Its type locality is Naujakasik (Naajakasik), Tunulliarfik Fjord, Ilímaussaq complex, Narsaq, Kujalleq, Greenland.

Almarudite (IMA symbol: Alr) is an extremely rare alkaline manganese beryllium silicate mineral of the cyclosilicates (ring silicates) class, with the chemical formula , from the volcanic environment of the Eifel Mountains in Germany.