Nesosilicates

Topaz is a silicate mineral made of aluminum and fluorine with the chemical formula AlSiO(F, OH). It is used as a gemstone in jewelry and other adornments. Common topaz in its natural state is colorless, though trace element impurities can make it pale blue or golden-brown to yellow-orange. Topaz is often treated with heat or radiation to make it a deep blue, reddish-orange, pale green, pink, or purple.

Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is ZrSiO4. An empirical formula showing some of the range of substitution in zircon is (Zr1–y, REEy)(SiO4)1–x(OH)4x–y. Zircon precipitates from silicate melts and has relatively high concentrations of high field strength incompatible elements. For example, hafnium is almost always present in quantities ranging from 1 to 4%. The crystal structure of zircon is tetragonal crystal system. The natural color of zirc

The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickly on the surface. Olivine has many uses, such as the gemstone peridot (or chrysolite), as well as industrial applications like metalworking processes.

Andalusite is an aluminium nesosilicate mineral with the chemical formula Al2SiO5. This mineral was called andalousite by Delamétherie, who thought it came from Andalusia, Spain. It soon became clear that it was a locality error, and that the specimens studied were actually from El Cardoso de la Sierra, in the Spanish province of Guadalajara, not Andalusia.

Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks generally indicates metamorphism deep in the Earth's crust. Kyanite is also known as disthene or cyanite.

thumb|150px|Titanite crystal model

Sillimanite or fibrolite is an aluminosilicate mineral with the chemical formula Al2SiO5. Sillimanite is named after the American chemist Benjamin Silliman (1779–1864). It was first described in 1824 for an occurrence in Chester, Connecticut.

Braunite is a silicate mineral containing both di- and tri-valent manganese with the chemical formula: Mn2+Mn3+6[O8|SiO4]. Common impurities include iron, calcium, boron, barium, titanium, aluminium, and magnesium.

Staurolite is a reddish brown to black, mostly opaque, nesosilicate mineral with a white streak. It crystallizes in the monoclinic crystal system, has a Mohs hardness of 7 to 7.5 and the chemical formula: Fe2+2Al9O6(SiO4)4(O,OH)2. Magnesium, zinc and manganese substitute in the iron site and trivalent iron can substitute for aluminium.

Gadolinite, sometimes known as ytterbite, is a silicate mineral consisting principally of the silicates of cerium, lanthanum, neodymium, yttrium, beryllium, and iron with the formula . It is called gadolinite-(Ce) or gadolinite-(Y), depending on the prominent composing element (Y if yttrium predominates, and Ce if cerium). It may contain 35.5% yttria sub-group rare earths, 2.2% ceria earths, as much as to 11.6% BeO, and traces of thorium. It is found in Sweden, Norway, and the US (Texas and Colorado).

Phenakite or phenacite is a fairly rare nesosilicate mineral consisting of beryllium orthosilicate, Be2SiO4. Occasionally used as a gemstone, phenakite occurs as isolated crystals, which are rhombohedral with parallel-faced hemihedrism, and are either lenticular or prismatic in habit: the lenticular habit is determined by the development of faces of several obtuse rhombohedra and the absence of prism faces. There is no cleavage, and the fracture is conchoidal. The Mohs hardness is high, being 7.5–8; the specific gravity is 2.96. The crystals are sometimes perfectly colorless and transparent, b

Thorite, (Th,U)SiO4, is a rare nesosilicate of thorium that crystallizes in the tetragonal system and is isomorphous with zircon and hafnon. It is the most common mineral of thorium and is nearly always strongly radioactive. Thorite was discovered in 1828 on the island of Løvøya, Norway, by the vicar and mineralogist, Hans Morten Thrane Esmark. First specimens of Thorite were sent to his father, Jens Esmark, who was a professor of mineralogy and geology. It was named in 1829 to reflect its thorium content.

Willemite is a zinc silicate mineral () and a minor ore of zinc. It is highly fluorescent (green) under shortwave ultraviolet light. It occurs in a variety of colors in daylight, in fibrous masses and apple-green gemmy masses. Troostite is a variant in which part of the zinc is partly replaced by manganese, it occurs in solid brown masses.

Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthorhombic system (space group Pbnm) with cell parameters a 4.75 Å (0.475 nm), b 10.20 Å (1.020 nm) and c 5.98 Å (0.598 nm).

Fayalite (, commonly abbreviated to Fa) is the iron-rich end-member of the olivine solid-solution series. In common with all minerals in the olivine group, fayalite crystallizes in the orthorhombic system (space group Pbnm) with cell parameters a = 4.82 Å, b = 10.48 Å and c = 6.09 Å.

Aluminosilicate refers to materials containing anionic Si-O-Al linkages. Commonly, the associate cations are sodium (Na+), potassium (K+) and protons (H+). Such materials occur as minerals, coal combustion products and as synthetic materials, often in the form of zeolites. Both synthetic and natural aluminosilicates are of technical significance as structural materials, catalysts, and reagents.

Euclase is a beryllium aluminium hydroxide silicate mineral (BeAlSiO4(OH)). It crystallizes in the monoclinic crystal system and is typically massive to fibrous as well as in slender prismatic crystals. It is related to beryl (Be3Al2Si6O18) and other beryllium minerals. It is a product of the decomposition of beryl in pegmatites. Euclase occurs mostly in association with minerals like: quartz, muscovite, fluorite, albite, rutile, schorl and calcite. thumb|left|Euclase, 3.0 x 1.6 x 1.6 cm. Lost Hope Mine, Mwami, Zimbabwe|Mwami, [[Mashonaland West Province, Zimbabwe|252x252px]] Euclase crystals

Datolite is a calcium boron hydroxide nesosilicate, CaBSiO4(OH). It was first observed by Jens Esmark in 1806, and named by him from δατεῖσθαι, "to divide," and λίθος, "stone," in allusion to the granular structure of the massive mineral.

thumb|Scanning electron microscope|SEM image of Ringwoodite (RGW) discovered in the Suizhou L6 [[chondrite meteorite. See image for details. ]]

thumb|Spectacle bracelet in dumortierite and gold by Cora Sheibani Dumortierite is a fibrous variably colored aluminium boro-silicate mineral, Al7BO3(SiO4)3O3. It crystallizes in the orthorhombic system typically forming fibrous aggregates of slender prismatic crystals. The crystals are vitreous and vary in color from brown, blue, and green to more rare violet and pink. Substitution of iron and other tri-valent elements for aluminium results in the color variations. It has a Mohs hardness of 7 and a specific gravity of 3.3 to 3.4. Crystals show pleochroism from red to blue to violet. Dumortier

Jadarite is a white, earthy monoclinic silicate mineral, sodium lithium boron silicate hydroxide with the chemical formula LiNaSiB3O7(OH). == Discovery and classification ==

Mullite or porcelainite is a rare silicate mineral formed during contact metamorphism of clay minerals. It can form two stoichiometric forms: 3Al2O32SiO2 or 2Al2O3 SiO2. Unusually, mullite has no charge-balancing cations present. As a result, there are three different aluminium sites: two distorted tetrahedral and one octahedral.

Chloritoid is a silicate mineral of metamorphic origin. It is an iron magnesium manganese alumino-silicate hydroxide with formula . It occurs as greenish grey to black platy micaceous crystals and foliated masses. Its Mohs hardness is 6.5, unusually high for a platy mineral, and it has a specific gravity of 3.52 to 3.57. It typically occurs in phyllites, schists and marbles.

Uranophane (Ca(UO2)2(SiO3OH)2·5H2O), also known as uranotile, is a rare calcium uranium silicate hydrate mineral that forms from the oxidation of other uranium-bearing minerals. It has a yellow color and is radioactive.

Monticellite and kirschsteinite (commonly also spelled kirschteinite) are gray silicate minerals of the olivine group with compositions CaMgSiO4 and CaFeSiO4, respectively. Most monticellites have the pure magnesium end-member composition but rare ferroan monticellites and magnesio-kirschsteinite are found with between 30 and 75 mol.% of the iron end member. Pure kirschsteinite is only found in synthetic systems. Monticellite is named after Teodoro Monticelli, an Italian mineralogist (1759–1845). Kirschsteinite is named after Egon Kirschstein, a German geologist.

Coffinite is a uranium-bearing silicate mineral with formula: U(SiO4)1−x(OH)4x.

Abswurmbachite is a copper manganese silicate mineral ((Cu,Mn2+)Mn3+6O8SiO4). It was first described in 1991 and named after Irmgard Abs-Wurmbach (born 1938), a German mineralogist. It crystallizes in the tetragonal system. Its Mohs scale rating is 6.5 and a specific gravity of 4.96. It has a metallic luster and its color is jet black, with light brown streaks.

Tephroite is the manganese endmember of the olivine group of nesosilicate minerals with the formula Mn2SiO4. A solid solution series exists between tephroite and its analogues, the group endmembers fayalite and forsterite. Divalent iron or magnesium may readily replace manganese in the olivine crystal structure.

Afwillite is a calcium hydroxide nesosilicate mineral with formula Ca3(SiO3OH)2·2H2O. It occurs as glassy, colorless to white prismatic monoclinic crystals. Its Mohs scale hardness is between 3 and 4. It occurs as an alteration mineral in contact metamorphism of limestone. It occurs in association with apophyllite, natrolite, thaumasite, merwinite, spurrite, gehlenite, ettringite, portlandite, hillebrandite, foshagite, brucite and calcite.

Chernobylite is a solid solution technogenic compound consisting of a crystalline zirconium silicate and an amount of uranium as high as 10%.

Tranquillityite is a silicate mineral with formula (Fe2+)8Ti3Zr2 Si3O24. It is mostly composed of iron, oxygen, silicon, zirconium and titanium with smaller fractions of yttrium and calcium. It is named after the Mare Tranquillitatis (Sea of Tranquility), the place on the Moon where the rock samples were found during the 1969 Apollo 11 mission. It was the last mineral brought from the Moon which was thought to be unique, with no counterpart on Earth, until it was discovered in Australia in 2011.

thumb|260px|Specimen from Santiago de Compostela, Spain

Cuprosklodowskite is a secondary uranium mineral formed by alteration of earlier uranium minerals. Its empirical formula is Cu(UO2)2(HSiO4)2·6(H2O). Cuprosklodowskite is a nesosilicate mineral, It is grass green to dark green in color, and its crystal habit is typically acicular, flat bladed crystals. It is a strongly radioactive mineral.

Spurrite is a white, yellow or light blue mineral with monoclinic crystals. Its chemical formula is Ca5(SiO4)2CO3.

Glaucochroite is a calcium manganese nesosilicate mineral with formula . It occurs in metamorphosed limestones.

Larnite is a calcium silicate mineral with the formula . It is the calcium member of the olivine group of minerals.

Grandidierite is a rare mineral that was first discovered in 1902 in southern Madagascar. The mineral was named in honor of French explorer Alfred Grandidier (1836–1912) who studied the natural history of Madagascar. thumb|left|A large, faceted grandidierite, a 429.87 carat stone owned by a Filipino collector Benedicto G. Membrere V. GIL Report certificate number STN201811139168.

Cerite is a complex silicate mineral group containing cerium, formula . The cerium and lanthanum content varies with the Ce rich species (cerite-(Ce)) and the La rich species (cerite-(La)). Analysis of a sample from the Mountain Pass carbonatite gave 35.05% and 30.04% .

Eucryptite is a lithium-bearing aluminium silicate mineral with formula LiAlSiO4. It crystallizes in the trigonal - rhombohedral crystal system. It typically occurs as granular to massive in form and may pseudomorphically replace spodumene. It has a brittle to conchoidal fracture and indistinct cleavage. It is transparent to translucent and varies from colorless to white to brown. It has a Mohs hardness of 6.5 and a specific gravity of 2.67. Optically it is uniaxial positive with refractive index values of nω = 1.570 – 1.573 and nε = 1.583 – 1.587.

Bultfonteinite, originally dutoitspanite, is a pink, light-brown or colorless mineral with chemical formula Ca2SiO2(OH,F)4. It was discovered in 1903 or 1904 in the Bultfontein mine in South Africa, for which the mineral is named, and described in 1932.

Hafnon is a hafnium nesosilicate mineral with the idealized chemical formula . It is the mineral form of hafnium silicate and one of the few known minerals with essential hafnium.

Huttonite is a thorium nesosilicate mineral with the chemical formula and which crystallizes in the monoclinic system. It is dimorphous with tetragonal thorite, and isostructual with monazite. An uncommon mineral, huttonite forms transparent or translucent cream–colored crystals. It was first identified in samples of beach sands from the West Coast region of New Zealand by the mineralogist Colin Osborne Hutton (1910–1971). Owing to its rarity, huttonite is not an industrially useful mineral.

Ottrelite is a form of chloritoid. Its empirical formula is .

Majorite is a mineral found in the mantle of the Earth. Its chemical formula is Mg3(MgSi)(SiO4)3. It is a type of garnet, distinguished from other garnets in having silicon in octahedral as well as tetrahedral coordination. Majorite was first described in 1970 from the Coorara Meteorite of Western Australia and has been reported from various other meteorites in which majorite is thought to result from an extraterrestrial high pressure shock event. Mantle-derived xenoliths containing majorite have been reported from potassic ultramafic magmas on Malaita Island on the Ontong Java Plateau in the

Bakerite is the common name given to hydrated calcium boro-silicate hydroxide, a borosilicate mineral (chemical formula Ca4B4(BO4)(SiO4)3(OH)3·(H2O)) that occurs in volcanic rocks in the Baker, California area. Discredited mineral: IMA2016-A.

Soddyite is a mineral of uranium. It has yellow crystals and usually mixed with curite in oxidized uranium ores. It is named after the British radiochemist and physicist Frederick Soddy (1877–1956). Soddyite has been a valid species since 1922, following its discovery in the locality of the Shinkolobwe uranium mine in the Haut-Katanga Province of the Democratic Republic of the Congo (DRC).

Weeksite is a naturally occurring uranium silicate mineral with the chemical formula: K2(UO2)2Si6O15•4(H2O), potassium uranyl silicate. Weeksite has a Mohs hardness of 1–2. It was named for USGS mineralogist Alice Mary Dowse Weeks (1909–1988).

Esperite is a rare complex calcium lead zinc silicate (PbCa3Zn4(SiO4)4) related to beryllonite and trimerite that used to be called calcium larsenite.

Homilite is a borosilicate mineral belonging to the gadolinite group of minerals with formula .

Stillwellite-(Ce) is a rare-earth boro-silicate mineral with chemical formula .

Sonolite is a mineral with formula Mn9(SiO4)4(OH,F)2. The mineral was discovered in 1960 in the Sono mine in Kyoto Prefecture, Japan. In 1963, it was identified as a new mineral and named after the Sono mine.

Clinohedrite is a rare silicate mineral. Its chemical composition is a hydrous calcium-zinc silicate; CaZn(SiO4)·H2O. It crystallizes in the monoclinic system and typically occurs as veinlets and fracture coatings. It is commonly colorless, white to pale amethyst in color. It has perfect cleavage and the crystalline habit has a brilliant luster. It has a Mohs hardness of 5.5 and a specific gravity of 3.28–3.33.

Hodgkinsonite is a rare zinc manganese silicate mineral Zn2MnSiO4(OH)2. It crystallizes in the monoclinic system and typically forms radiating to acicular prismatic crystals with variable color from pink, yellow-red to deep red. Hodgkinsonite was discovered in 1913 by H. H. Hodgkinson, for whom it is named in Franklin, New Jersey, and it is only found in that area.

Haiweeite is a mineral of uranium and has the chemical formula: Ca[(UO2)2Si5O12(OH)2]·3(H2O). It is a secondary mineral of uranium, a product of oxidation. It has a greenish yellow color. It has a Mohs hardness of about 3.5 and is fluorescent under UV light.

Leucophoenicite is a mineral with formula Mn7(SiO4)3(OH)2. Generally brown to red or pink in color, the mineral gets its name from the Greek words meaning "pale purple-red". Leucophoenicite was discovered in New Jersey, US and identified as a new mineral in 1899.

Jerrygibbsite is a rare silicate mineral with the chemical formula . Jerrygibbsite was originally discovered by Pete J. Dunn in 1984, who named it after mineralogist Gerald V. Gibbs (born 1929). It has only been reported from the type locality of Franklin Furnace, New Jersey, United States, and in Namibia's Otjozondjupa region. Jerrygibbsite is member of the leucophoenite family of the humite group. It is always found with these two minerals. It is a dimorph of sonolite.

Fluorellestadite is a rare nesosilicate of calcium, with sulfate and fluorine, with the chemical formula Ca10(SiO4)3(SO4)3F2. It is a member of the apatite group, and forms a series with hydroxylellestadite.

Malayaite is a calcium tin silicate mineral with formula CaSnOSiO4. It is a member of the titanite group.

Reidite is a rare polymorph of ZrSiO4 created when zircon experiences high pressure and temperature. Reidite is denser than zircon and has the same crystal structure as scheelite. All natural occurrences of reidite are associated with meteorite impact events.

thumb | right | Knebelite specimen Knebelite is a manganese variety of the fayalite-tephroite series with formula . It forms dark green orthorhombic crystals. It is reported from a variety of locations in Sweden as well as South Africa, Russia, British Columbia, New Hampshire, and Rhode Island.