Tetragonal minerals

Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is ZrSiO4. An empirical formula showing some of the range of substitution in zircon is (Zr1–y, REEy)(SiO4)1–x(OH)4x–y. Zircon precipitates from silicate melts and has relatively high concentrations of high field strength incompatible elements. For example, hafnium is almost always present in quantities ranging from 1 to 4%. The crystal structure of zircon is tetragonal crystal system. The natural color of zirc

Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green-tinged black.

Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite.

Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem. Cassiterite was the chief tin ore throughout ancient history and remains the most important source of tin today.

Pyrolusite is a mineral consisting essentially of manganese dioxide (MnO2) and is important as an ore of manganese. It is a black, amorphous appearing mineral, often with a granular, fibrous, or columnar structure, sometimes forming reniform crusts. It has a metallic luster, a black or bluish-black streak, and readily soils the fingers. The specific gravity is about 4.8. Its name is from the Greek for fire and to wash, in reference to its use as a way to remove tints from glass. thumb|Acicular radiating pyrolusite

Wulfenite is a lead molybdate mineral with the formula PbMoO4. It often occurs as thin tabular crystals with a bright orange-red to yellow-orange color, sometimes brown, although the color can be highly variable. In its yellow form it is sometimes called "yellow lead ore".

Scheelite is a calcium tungstate mineral with the chemical formula CaWO4. It is an important ore of tungsten (wolfram). Scheelite is originally named after Swedish chemist Carl Wilhelm Scheele (1742–1786). Well-formed crystals are sought by collectors and are occasionally fashioned into gemstones when suitably free of flaws. Scheelite has been synthesized using the Czochralski process; the material produced may be used to imitate diamond, as a scintillator, or as a solid-state lasing medium. It was also used in radium paint in the same fashion as was zinc sulphide, and Thomas Edison invented a

Vesuvianite, also known as idocrase, is a green, brown, yellow, or blue silicate mineral. Vesuvianite occurs as tetragonal crystals in skarn deposits and limestones that have been subjected to contact metamorphism. It was first discovered within included blocks or adjacent to lavas on Mount Vesuvius, hence its name. Attractive-looking crystals are sometimes cut as gemstones. Localities which have yielded fine crystallized specimens include Mount Vesuvius and the Ala Valley near Turin, Piedmont.

Anatase is a metastable mineral form of titanium dioxide (TiO2) with a tetragonal crystal structure. Although colorless or white when pure, anatase in nature is usually a black solid due to impurities. Three other polymorphs (or mineral forms) of titanium dioxide are known to occur naturally: brookite, akaogiite, and rutile, with rutile being the most common and most stable of the bunch. Anatase is formed at relatively low temperatures and found in minor concentrations in igneous and metamorphic rocks. Glass coated with a thin film of TiO2 shows antifogging and self-cleaning properties under u

Braunite is a silicate mineral containing both di- and tri-valent manganese with the chemical formula: Mn2+Mn3+6[O8|SiO4]. Common impurities include iron, calcium, boron, barium, titanium, aluminium, and magnesium.

Leucite (from the Greek word leukos meaning white) is a rock-forming mineral of the feldspathoid group, silica-undersaturated and composed of potassium and aluminium tectosilicate KAlSi2O6. Crystals have the form of cubic icositetrahedra but, as first observed by Sir David Brewster in 1821, they are not optically isotropic, and are therefore pseudo-cubic. Goniometric measurements made by Gerhard vom Rath in 1873 led him to refer the crystals to the tetragonal system. Optical investigations have since proved the crystals to be still more complex in character, and to consist of several orthorhom

Thorite, (Th,U)SiO4, is a rare nesosilicate of thorium that crystallizes in the tetragonal system and is isomorphous with zircon and hafnon. It is the most common mineral of thorium and is nearly always strongly radioactive. Thorite was discovered in 1828 on the island of Løvøya, Norway, by the vicar and mineralogist, Hans Morten Thrane Esmark. First specimens of Thorite were sent to his father, Jens Esmark, who was a professor of mineralogy and geology. It was named in 1829 to reflect its thorium content.

Torbernite, also known as chalcolite, is a relatively common mineral with the chemical formula Cu[(UO2)(PO4)]2·12H2O. It is a radioactive, hydrated green copper uranyl phosphate, found in granites and other uranium-bearing deposits as a secondary mineral. The chemical formula of torbernite is similar to that of autunite in which a Cu2+ cation replaces a Ca2+ cation. Torbernite tends to dehydrate to metatorbernite with the sum formula Cu[(UO2)(PO4)]2·8H2O.

Cristobalite ( ) is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, SiO2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the quartz group, which also include coesite, tridymite and stishovite. It is named after Cerro San Cristóbal in Pachuca Municipality, Hidalgo, Mexico.

The name apophyllite refers to a specific group of phyllosilicates, a class of minerals. Originally, the group name referred to a specific mineral, but was redefined in 1978 to stand for a class of minerals of similar chemical makeup that comprise a solid solution series, and includes the members fluorapophyllite-(K), fluorapophyllite-(Na), hydroxyapophyllite-(K). The name apophyllite is derived from the Greek (), meaning 'it flakes off', a reference to this class's tendency to flake apart when heated, due to water loss. Exfoliation of apophyllite is also possible by treating it with acids or

Hausmannite is a complex oxide, or a mixed oxide, of manganese containing both di- and tri-valent manganese. Its chemical formula can be represented as , or more simply noted as , or , as commonly done for magnetite (), the corresponding iron oxide. It belongs to the spinel group and forms tetragonal crystals. Hausmannite is a brown to black metallic mineral with Mohs hardness of 5.5 and a specific gravity of 4.8.

Stannite is a mineral, a sulfide of copper, iron, and tin, in the category of thiostannates.

Xenotime is a rare-earth phosphate mineral, the major component of which is yttrium orthophosphate (YPO4). The phosphate ions are described by a tetrahedral shape and coordinate to the center Y3+ metal ion in a way that closely resembles the structure of zircon (ZrSiO4). It forms a solid solution series with chernovite-(Y) (YAsO4) and therefore may contain trace impurities of arsenic, as well as silicon dioxide and calcium. Other iso-structural ions that undergo exchanges with PO4 are VO4 and NbO4 ions, contributing to the list of possible co-occurring elements that may be in need of separatio

Abernathyite is a mineral with formula K(UO2)(AsO4)·3H2O. The mineral is named after Jesse Evrett Abernathy (1913–1963) who first noted it in 1953 in the U.S. State of Utah. It was described as a new mineral species in 1956. Abernathyite is yellow and occurs as small crystals.

The scapolites (, "rod", and , "stone") are a group of rock-forming silicate minerals composed of aluminium, calcium, and sodium silicate with chlorine, carbonate and sulfate. The two endmembers are meionite () and marialite (). Silvialite is also a recognized member of the group.

Matlockite is a rare lead halide mineral, named after the town of Matlock in Derbyshire, England, where it was first discovered in a nearby mine. Matlockite (chemical formula: PbFCl) gives its name to the matlockite group which consists of rare minerals of a similar structure.

Tugtupite is a beryllium aluminium tectosilicate. It also contains sodium and chlorine and has the formula Na4AlBeSi4O12Cl. Tugtupite is a member of the silica-deficient feldspathoid mineral group. It occurs in high alkali intrusive igneous rocks.

Litharge (from Greek , 'stone' + 'silver' ) is one of the natural mineral forms of lead(II) oxide, PbO. Litharge is a secondary mineral which forms from the oxidation of galena ores. It forms as coatings and encrustations with internal tetragonal crystal structure. It is dimorphous with the yellow orthorhombic form massicot. It forms soft (Mohs hardness of 2), red, greasy-appearing crusts with a very high specific gravity of 9.14–9.35. PbO may be prepared by heating lead metal in air at approximately 600 °C (lead melts at only 300 °C). At this temperature it is also the end product o

Mellite, also called honeystone, is an unusual mineral being also an organic chemical. It is chemically identified as an aluminium salt of mellitic acid, and specifically as aluminium benzenehexacarboxylate hexadecahydrate, with the chemical formula Al2C6(COO)6·16H2O.

Powellite is a calcium molybdate mineral with formula CaMoO4. Powellite crystallizes with tetragonal – dipyramidal crystal structure as transparent adamantine blue, greenish-brown, yellow-to-grey typically anhedral forms. It exhibits distinct cleavage, and has a brittle-to-conchoidal fracture. It has a Mohs hardness of 3.5 to 4 and a specific gravity of 4.25. It forms a solid solution series with scheelite (calcium tungstate, CaWO4). It has refractive index values of nω=1.974 and nε=1.984.

thumb|300px|right|A view down onto the sheets of the A2B(T2O7) melilite structure. The A sites are yellow spheres, the B sites are pale orange tetrahedra, and the T sites are blue tetrahedra. Oxygen atoms (not shown) are on the corners of the tetrahedra.

Coffinite is a uranium-bearing silicate mineral with formula: U(SiO4)1−x(OH)4x.

Stolzite is a mineral, a lead tungstate; with the formula PbWO4. It is similar to, and often associated with, wulfenite which is the same chemical formula except that the tungsten is replaced by molybdenum. Stolzite crystallizes in the tetragonal crystal system and is dimorphous with the monoclinic form raspite. thumb|left|Stolzite crystal from the Darwin District, Inyo County, California (size: 2.0 × 1.7 × 1.6 cm) Lead tungstate crystals have the optical transparency of glass combined with much higher density (8.28 g/cm3 vs ~2.2 g/cm3 for fused silica). They are used as scintillator

Schreibersite is generally a rare iron nickel phosphide mineral, , though common in iron-nickel meteorites. It has been found on Disko Island in Greenland and Illinois.

thumb|Pressure-temperature diagram for various forms of silicon dioxide, including stishovite (at top left)

Abswurmbachite is a copper manganese silicate mineral ((Cu,Mn2+)Mn3+6O8SiO4). It was first described in 1991 and named after Irmgard Abs-Wurmbach (born 1938), a German mineralogist. It crystallizes in the tetragonal system. Its Mohs scale rating is 6.5 and a specific gravity of 4.96. It has a metallic luster and its color is jet black, with light brown streaks.

Phosgenite is a rare mineral consisting of lead carbonate chloride, (PbCl)2CO3. The tetragonal crystals are prismatic or tabular in habit: they are usually colorless and transparent, and have a brilliant adamantine lustre. Sometimes the crystals have a curious helical twist about the tetrad or principal axis. The hardness is 3 and the specific gravity 6.3. The mineral is rather sectile, and consequently was earlier known as corneous lead ().

Ekanite is an uncommon silicate mineral with chemical formula or . It is a member of the steacyite group. It is among the few gemstones that are naturally radioactive. Most ekanite is mined in Sri Lanka, although deposits also occur in Russia and North America. Clear and well-colored stones are rare as the radioactivity tends to degrade the crystal matrix over time in a process known as metamictization.

Marialite is a silicate mineral with a chemical formula of if a pure endmember or with increasing meionite content. Marialite is the sodium endmember of the scapolite group and a solid solution exists between marialite and meionite, the calcium endmember. It is a rare mineral usually used as a collector's stone.

Fergusonite is a mineral comprising a complex oxide of various rare-earth elements. The general chemical formula of fergusonite is (Y,REE)NbO4, where REE = rare-earth elements in solid solution with Y. Yttrium is usually dominant (the mineral in this case being referred to as fergusonite-(Y)), but sometimes Ce or Nd may be the major rare-earth component (in fergusonite-(Ce) and fergusonite-(Nd), respectively). The other rare-earth elements are present in smaller amounts, and tantalum sometimes substitutes for some of the niobium. There are fergusonite-beta-(Nd), fergusonite-beta-(Y), fergusoni

naturally occurring mineral form of lead tetroxide

Meionite is a tectosilicate belonging to the scapolite group with the formula Ca4Al6Si6O24CO3. Some samples may also contain a sulfate group. It was first discovered in 1801 on Mt Somma, Vesuvius, Italy. It was named by Rene Just Haüy after μειωυ, the Greek word for less, in reference to the less acute pyramidal form as compared to vesuvianite.

Braggite is a sulfide mineral of platinum, palladium and nickel with chemical formula: (Pt, Pd, Ni)S. It is a dense (specific gravity of 10), steel grey, opaque mineral which crystallizes in the tetragonal crystal system. It is the central member in the platinum group end-members cooperite and vysotskite.

Carletonite is a rare phyllosilicate mineral with formula KNa4Ca4(CO3)4Si8O18(F,OH)·(H2O). Its tetragonal crystals are a translucent blue, white, colorless or pink with a vitreous to dull lustre. It has a density of 2.45 and a hardness of 4–4.5.

Gehlenite, (Ca2Al[AlSiO7]), is a sorosilicate, Al-rich endmember of the melilite complete solid solution series with akermanite. The type locality is in the Monzoni Mountains, Fassa Valley in Trentino in Italy, and is named after the Adolf Ferdinand Gehlen (1775–1815) by A.J. Fuchs in 1815.

Kësterite is a sulfide mineral with a chemical formula of . In its lattice structure, zinc and iron atoms share the same lattice sites. Kesterite is the zinc-rich variety whereas the zinc-poor form is called ferrokesterite or stannite. Owing to their similarity, kesterite is sometimes called isostannite. The synthetic form of kesterite is abbreviated as CZTS (from copper-zinc-tin sulfide). The name kesterite is sometimes extended to include this synthetic material and also CZTSe, which contains selenium instead of sulfur. Along with perovskite, recent advances have made kesterite promising mat

Plattnerite is an oxide mineral and is the beta crystalline form of lead dioxide (β-PbO2), scrutinyite being the other, alpha form. It was first reported in 1845 and named after German mineralogist Karl Friedrich Plattner. Plattnerite forms bundles of dark needle-like crystals on various minerals; the crystals are hard and brittle and have tetragonal symmetry.

sulfide mineral

Gonnardite is a comparatively rare, fibrous zeolite, natrolite subgroup. Older papers claim that a complete solid solution exists between tetranatrolite and gonnardite, but tetranatrolite was discredited as a separate species in 1999. A series, based on the disorder of the silicon-aluminum in the framework, appears to exist between Na-rich gonnardite and natrolite, Na2(Si3Al2)O10·2H2O.

Uranocircite or Uranocircite-II is a uranium mineral with the chemical formula: Ba(UO2)2(PO4)2·10H2O. Uranocircite-I was discredited (the IMA-CMNMC published 'The New IMA List of Minerals', September 2012). It is a phosphate mineral which contains barium and is a green to yellow colour. It has a Mohs hardness of about 2.

Jalpaite is a rare copper silver sulfide mineral with formula Ag3CuS2.

Umangite is a copper selenide mineral, Cu3Se2, discovered in 1891. It occurs only in small grains or fine granular aggregates with other copper minerals of the sulfide group. It has a hardness of 3. It is blue-black to red-violet in color with a black streak. It has a metallic luster.

Briartite is an opaque iron-grey metallic sulfide mineral, with traces of Ga and Sn, found as inclusions in other germanium-gallium-bearing sulfides.

Metatorbernite (or meta-torbernite) is a radioactive phosphate mineral, and is a dehydration pseudomorph of torbernite. Chemically, it is a copper uranyl phosphate and usually occurs in the form of green platy deposits. It can form by direct deposition from a supersaturated solution, which produces true crystalline metatorbernite, with a dark green colour, translucent diaphaneity, and vitreous lustre. However, more commonly, it is formed by the dehydration of torbernite, which causes internal stress and breakage within the crystal lattice, resulting in crystals composed of microscopic powder h

Diaboleite is a blue-colored mineral with formula Pb2CuCl2(OH)4. It was discovered in England in 1923 and named diaboleite, from the Greek word διά and boleite, meaning "distinct from boleite". The mineral has since been found in a number of countries.

Hafnon is a hafnium nesosilicate mineral with the idealized chemical formula . It is the mineral form of hafnium silicate and one of the few known minerals with essential hafnium.

Åkermanite (Ca2Mg[Si2O7]) is a melilite mineral of the sorosilicate group, containing calcium, magnesium, silicon, and oxygen. It is a product of contact metamorphism of siliceous limestones and dolomites, and rocks of sanidinite facies. Sanidinite facies represent the highest conditions of temperature of contact metamorphism and are characterized by the absence of hydrous minerals. It has a density of 2.944 g/cm3. Åkermanite ranks a 5 or 6 on the Mohs scale of mineral hardness, and can be found gray, green, brown, or colorless. It has a white streak and a vitreous or resinous luster. It has a

Sellaite is a magnesium fluoride mineral with the formula MgF2. It crystallizes in the tetragonal crystal system, typically as clear to white vitreous prisms. It may be fibrous and occur as radiating aggregates. It has a Mohs hardness of 5 to 6 and a specific gravity of 2.97 to 3.15. Refractive index values are nω = 1.378 and nε = 1.390.

Wiluite is a dark green, brownish, or black blocky silicate mineral with the chemical formula . It has a Mohs hardness of 6 and a specific gravity of 3.36. It has a vitreous lustre, poor cleavage and an irregular brittle fracture. It crystallizes in the tetragonal system and occurs as well-formed crystals with good external form. It is isostructural with the vesuvianite group and is associated with wollastonite and olive-green grossulars (viluites) in a serpentinized skarn.

Bismoclite is a bismuth oxohalide mineral with formula BiOCl. It is the naturally occurring form of bismuth oxychloride. The name was derived from its chemical constituents. It is a secondary bismuth mineral first thought to be composed of bismuthyl ions (BiO+) and chloride anions, however, the existence of the diatomic bismuthyl ion is doubtful.

Zeunerite is a green copper uranium arsenate mineral with formula Cu(UO2)2(AsO4)2·(10-16)H2O. It is a member of the autunite group. The associated mineral metazeunerite is a dehydration product of zeunerite.

Renierite is a rare copper zinc germanium bearing sulfide mineral with the chemical formula . It occurs at the Kipushi Mine, Democratic Republic of the Congo; and Namibia, among other places.

Mackinawite ( ) is an iron sulfide mineral, which can contain nickel substituting for iron(II), with as chemical formula (where x = 0 to 0.11). As indicated by its chemical composition, Fe(1+×), Fe is present with an excess of × over S, and it is thus an iron-rich, or a sulfur-deficient, iron monosulfide mineral. The mineral crystallizes in the tetragonal crystal system and has been described as a distorted, close packed, cubic array of S atoms with some of the gaps filled with Fe. Mackinawite occurs as opaque bronze to grey-white tabular crystals and anhedral masses. It has a Mohs hardness of

Paramelaconite is a rare, black-colored copper(I,II) oxide mineral with formula CuCuO3 (or Cu4O3). It was discovered in the Copper Queen Mine in Bisbee, Arizona, about 1890. It was described in 1892 and more fully in 1941. Its name is derived from the Greek word for "near" and the similar mineral melaconite, now known as tenorite.

Maucherite is a grey to reddish silver white nickel arsenide mineral. It crystallizes in the tetragonal crystal system. It occurs in hydrothermal veins alongside other nickel arsenide and sulfide minerals. It is metallic and opaque with a hardness of 5 and a specific gravity of 7.83. It is also known as placodine and Temiskamite. The unit cell is of symmetry group P41212 or P43212.