Skip to content
1,4,2-Dithiazole

Structure via PubChem · Public domain (PubChem)

EntityQ4545689· pop 8· linked from 2 articles

1,4,2-Dithiazole

Sign in to save

1,4,2-Dithiazole is a heterocyclic compound consisting of an unsaturated five-membered ring containing two carbon atoms, one nitrogen atom, and two sulfur atoms. 1,4,2-Dithiazole compounds may be formed by the reaction of nitrile sulfide (formed by the thermolysis of oxathiazolone) with various reactive species; for instance thiocarbonyls via a 1,3-dipolar cycloaddition reaction. These compounds may be protonated by strong acids to give synthetically useful aromatic cations.

Chemical data

Formula
C2H3NS2
Molecular weight
105.19 g/mol
IUPAC name
1,4,2-dithiazole
SMILES
C1SC=NS1
InChIKey
MNNJLAZJQBWSST-UHFFFAOYSA-N
XLogP
1.1
Polar surface area
63 Ų
H-bond donors
0
H-bond acceptors
3
Formal charge
0

via PubChem

Wikidata facts

Mass
104.970691
Show 2 more facts
canonical SMILES
C1SC=NS1
chemical formula
C₂H₃NS₂
Sources (1)

via Wikidata · CC0

~1 min read

Encyclopedic overview

1 sections
Contents
  • References

1,4,2-Dithiazole is a heterocyclic compound consisting of an unsaturated five-membered ring containing two carbon atoms, one nitrogen atom, and two sulfur atoms. 1,4,2-Dithiazole compounds may be formed by the reaction of nitrile sulfide (formed by the thermolysis of oxathiazolone) with various reactive species; for instance thiocarbonyls via a 1,3-dipolar cycloaddition reaction. These compounds may be protonated by strong acids to give synthetically useful aromatic cations.

==References==

Excerpted from Wikipedia’s “1,4,2-Dithiazole” article, available under the CC BY-SA 4.0 licence.

Available in 8 languages

via Wikidata sitelinks · CC0