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2-benzimidazolethiol

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EntityQ16004147· pop 5· linked from 4 articles

2-benzimidazolethiol

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Also known as mercaptobenzimidazole, 2-mercaptobenzimidazole, 1,3-dihydrobenzimidazole-2-thione

Mercaptobenzimidazole is the organosulfur compound with the formula C6H4(NH)2C=S. It is the mercaptan of benzimidazole. It is a white solid that has been investigated as a corrosion inhibitor. The name is a misnomer because the compound is a thiourea, characterized with a short C=S bond length of 169 pm. A similar situation applies to 2-mercaptoimidazole, which is also a thiourea properly called 2-imidazolidinethione and mercaptobenzothiazole, which is also a thioamide.

Chemical data

Formula
C7H6N2S
Molecular weight
150.2 g/mol
IUPAC name
1,3-dihydrobenzimidazole-2-thione
SMILES
C1=CC=C2C(=C1)NC(=S)N2
InChIKey
YHMYGUUIMTVXNW-UHFFFAOYSA-N
XLogP
1.7
Polar surface area
56.2 Ų
H-bond donors
2
H-bond acceptors
1
Formal charge
0

via PubChem

Drug data · ChEMBL

Molecule type
Small molecule

via ChEMBL · EBI

Wikidata facts

Mass
150.025
Show 4 more facts
chemical formula
C₇H₆N₂S
canonical SMILES
C1=CC=C2C(=C1)NC(=S)N2
melting point
303.0
Commons category
Mercaptobenzimidazole
Sources (2)

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Encyclopedic overview

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Contents
  • References

Mercaptobenzimidazole is the organosulfur compound with the formula C6H4(NH)2C=S. It is the mercaptan of benzimidazole. It is a white solid that has been investigated as a corrosion inhibitor. The name is a misnomer because the compound is a thiourea, characterized with a short C=S bond length of 169 pm. A similar situation applies to 2-mercaptoimidazole, which is also a thiourea properly called 2-imidazolidinethione and mercaptobenzothiazole, which is also a thioamide.

It is prepared from o-phenylenediamine.

Excerpted from Wikipedia’s “2-benzimidazolethiol” article, available under the CC BY-SA 4.0 licence.

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