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acylsilane

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Also known as Acylsilanes

thumb|right|The general structure of an acylsilane Acylsilanes are a group of chemical compounds sharing a common functional group with the general structure RC(O)-SiR3.

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Acylsilanes

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  • Synthesis
  • Reactions
  • Further reading
  • References

thumb|right|The general structure of an acylsilane Acylsilanes are a group of chemical compounds sharing a common functional group with the general structure RC(O)-SiR3.

== Synthesis == Acylsilanes can be synthesized by treating acyl anion equivalents with silyl halides (typically trimethylsilyl chloride, tmsCl). Silylation of 2-lithio-1,3-dithiane, followed by hydrolysis of the dithioacetal group with mercury(II) chloride. Analogous methods has also been used to produce acylgermanes. left|thumb|567x567px|Brook acylsilane synthesis scheme.

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