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ageliferin

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ageliferin

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Ageliferin is a chemical compound produced by some sponges. It was first isolated from Caribbean and then Okinawan marine sponges in the genus Agelas. It often co-exists with the related compound sceptrin and other similar compounds. It has antibacterial properties and can cause biofilms to dissolve. Total syntheses have been independently accomplished by the research groups of Phil S. Baran at the Scripps Research Institute, Chuo Chen at UT Southwestern Medical Center, Patrick Harran at UCLA, and Daisuke Urabe at Toyama Prefectural University.

Chemical data

Formula
C22H24Br2N10O2
Molecular weight
620.3 g/mol
IUPAC name
N-[[(5S,6R,7R)-2-amino-7-(2-amino-1H-imidazol-5-yl)-6-[[(4-bromo-1H-pyrrole-2-carbonyl)amino]methyl]-4,5,6,7-tetrahydro-3H-benzimidazol-5-yl]methyl]-4-bromo-1H-pyrrole-2-carboxamide
SMILES
C1[C@@H]([C@H]([C@@H](C2=C1NC(=N2)N)C3=CN=C(N3)N)CNC(=O)C4=CC(=CN4)Br)CNC(=O)C5=CC(=CN5)Br
InChIKey
DMMLTRAQSJWUHT-OGTWGDGJSA-N
XLogP
1.4
Polar surface area
199 Ų
H-bond donors
8
H-bond acceptors
6
Formal charge
0

via PubChem

Drug data · ChEMBL

Molecule type
Small molecule

via ChEMBL · EBI

Wikidata facts

Has part
oxygen
Mass
618.045044208
Show 4 more facts
canonical SMILES
O=C(NCC1CC=2NC(=N)NC2C(C3=CNC(=N)N3)C1CNC(=O)C4=CC(Br)=CN4)C5=CC(Br)=CN5
chemical formula
C₂₂H₂₄Br₂N₁₀O₂
isomeric SMILES
C1[C@@H]([C@H]([C@@H](C2=C1NC(=N2)N)C3=CN=C(N3)N)CNC(=O)C4=CC(=CN4)Br)CNC(=O)C5=CC(=CN5)Br
found in taxon
Agelas nakamurai
Sources (3)

via Wikidata · CC0

~1 min read

Encyclopedic overview

2 sections
Contents
  • See also
  • References

{{Chembox |Verifiedfields = changed |Watchedfields = changed |verifiedrevid = 477243588 |ImageFile = Ageliferin.png |ImageSize = 200px |PIN = N,N′-{[(4R,5R,6S)-2-Amino-4-(2-amino-1H-imidazol-5-yl)-4,5,6,7-tetrahydro-1H-1,3-benzimidazole-5,6-diyl]bis(methylene)}bis(4-bromo-1H-pyrrole-2-carboxamide) |OtherNames = Ageliferine |Section1= |Section2= }}

Ageliferin is a chemical compound produced by some sponges. It was first isolated from Caribbean and then Okinawan marine sponges in the genus Agelas. It often co-exists with the related compound sceptrin and other similar compounds. It has antibacterial properties and can cause biofilms to dissolve. Total syntheses have been independently accomplished by the research groups of Phil S. Baran at the Scripps Research Institute, Chuo Chen at UT Southwestern Medical Center, Patrick Harran at UCLA, and Daisuke Urabe at Toyama Prefectural University.

Excerpted from Wikipedia’s “ageliferin” article, available under the CC BY-SA 4.0 licence.

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