English
Structure via PubChem · Public domain (PubChem)
bismole
Sign in to saveBismole is a theoretical heterocyclic organic compound, a five-membered ring with the formula C4H4BiH. It is classified as a metallole. It can be viewed as a structural analog of pyrrole, with bismuth replacing the nitrogen atom of pyrrole. The unsubstituted compound has not been isolated due to the high energy of the Bi-H bond. Substituted derivatives, which have been synthesized, are called bismoles.
Chemical data
- Formula
- C4H5Bi
- Molecular weight
- 262.06 g/mol
- IUPAC name
- 1H-bismole
- SMILES
- C1=C[BiH]C=C1
- InChIKey
- SUILZFJIVIXVOA-UHFFFAOYSA-N
- Polar surface area
- 0 Ų
- H-bond donors
- 0
- H-bond acceptors
- 0
- Formal charge
- 0
via PubChem
Wikidata facts
- Subclass of
- chemical compound
- Mass
- 262.019524
Show 3 more facts
- canonical SMILES
- C1=C[BiH]C=C1
- chemical formula
- C₄H₅Bi
- Commons category
- Bismole
Sources (2)
via Wikidata · CC0
~1 min read
Encyclopedic overview
3 sectionsContents
- Reactions
- See also
- References
Bismole is a theoretical heterocyclic organic compound, a five-membered ring with the formula C4H4BiH. It is classified as a metallole. It can be viewed as a structural analog of pyrrole, with bismuth replacing the nitrogen atom of pyrrole. The unsubstituted compound has not been isolated due to the high energy of the Bi-H bond. Substituted derivatives, which have been synthesized, are called bismoles.
==Reactions== 2,5-Bis(trimethylsilyl)-3,4-dimethyl-1-phenyl-1H-bismole, for example, can be formed by the reaction of (1Z,3Z)-1,4-bis(trimethylsilyl)-1,4-diiodobuta-2,3-dimethyl-1,3-diene and diiodophenylbismuthine. Bismoles can be used to form ferrocene-like sandwich compounds.
Excerpted from Wikipedia’s “bismole” article, available under the CC BY-SA 4.0 licence.