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bromochlorodifluoromethane

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bromochlorodifluoromethane

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Also known as difluorobromochloromethane, monobromomonochlorodifluoromethane, difluorochlorobromomethane, chlorodifluoromonobromomethane, Freon 12B1, fluorocarbon 1211, Halon 1211, Halon-1211

Bromochlorodifluoromethane (BCF), also referred to by the code numbers Halon 1211 and Freon 12B1, is a haloalkane with the chemical formula CF2ClBr. It is used for fire suppression, especially for expensive equipment or items that could be damaged by the residue from other types of extinguishers. It is stored as a liquid under pressure and vaporizes when discharged to suppress fires. The use of halons, including Halon 1211, has decreased over time due to their adverse impact on the ozone layer. Alternatives have been developed to mitigate environmental concerns while still providing effective

Chemical data

Formula
CBrClF2
Molecular weight
165.36 g/mol
IUPAC name
bromo-chloro-difluoromethane
SMILES
C(F)(F)(Cl)Br
InChIKey
MEXUFEQDCXZEON-UHFFFAOYSA-N
XLogP
2.4
Polar surface area
0 Ų
H-bond donors
0
H-bond acceptors
2
Formal charge
0

via PubChem

Wikidata facts

Subclass of
halon
Mass
163.884
Show 8 more facts
ozone depletion potential
7.9
chemical formula
CBrClF₂
canonical SMILES
C(F)(F)(Cl)Br
Commons category
Bromochlorodifluoromethane
global warming potential
2070
ionization energy
11.83
melting point
-159.5
boiling point
-3.72
Sources (4)

via Wikidata · CC0

~4 min read

Encyclopedic overview

7 sections
Contents
  • Use as a fire extinguishing agent
  • Synthesis
  • Regulation
  • Gallery
  • See also
  • References
  • External links

Bromochlorodifluoromethane (BCF), also referred to by the code numbers Halon 1211 and Freon 12B1, is a haloalkane with the chemical formula CF2ClBr. It is used for fire suppression, especially for expensive equipment or items that could be damaged by the residue from other types of extinguishers. It is stored as a liquid under pressure and vaporizes when discharged to suppress fires. The use of halons, including Halon 1211, has decreased over time due to their adverse impact on the ozone layer. Alternatives have been developed to mitigate environmental concerns while still providing effective fire suppression capabilities. ==Use as a fire extinguishing agent== Brominated haloalkanes were first used during World War II in fire extinguishers for aircraft and tanks. BCF was introduced as an effective gaseous fire suppression agent in the mid-1960s for use around highly valuable materials in places such as museums, mainframe rooms, and telecommunication switching centers. BCFs were also widely used in the maritime industries in the engine rooms of ships and also in the transport industry in vehicles. Its efficiency as a fire extinguishing agent has also led it to be the predominant choice of fire extinguishing agent on commercial aircraft and is typically found in cylindrical hand-held canisters. Its advantages as a fire extinguishing agent are that it has lower toxicity than chemicals such as carbon tetrachloride and that since it is a covalently bonded compound, it does not form conductive ions, therefore being usable on electrical equipment.

BCF is an excellent fire extinguishing agent, as it is a streaming agent with low toxicity, a low pressure, liquefied gas, and effective on all common types of fires, A, B, and C. It is mainly used in portable and wheeled extinguishers, and small spot protection units for aviation and marine engine applications, and was never widely used in fixed systems like Halon 1301 was.

Excerpted from Wikipedia’s “bromochlorodifluoromethane” article, available under the CC BY-SA 4.0 licence.