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cyclododecanone

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Cyclododecanone is an organic compound with the formula (CH2)11CO. It is a cyclic ketone that exists as a white solid at room temperature. Like its smaller analogs but unlike the larger ones, it has a camphor-like odor. ==History and synthesis== It was first obtained by Ružička et al. in 1926 by ketonic decarboxylation. A higher-yield method by acyloin condensation was devised by Prelog et al. in 1947.

Wikidata facts

Mass
182.167
Show 4 more facts
chemical formula
C₁₂H₂₂O
canonical SMILES
C1CCCCCC(=O)CCCCC1
melting point
61.0
Commons category
Cyclododecanone
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Contents
  • History and synthesis
  • Uses
  • References

Cyclododecanone is an organic compound with the formula (CH2)11CO. It is a cyclic ketone that exists as a white solid at room temperature. Like its smaller analogs but unlike the larger ones, it has a camphor-like odor. ==History and synthesis== It was first obtained by Ružička et al. in 1926 by ketonic decarboxylation. A higher-yield method by acyloin condensation was devised by Prelog et al. in 1947.

It is now industrially produced by the oxidation of cyclododecane via cyclododecanol. ==Uses== Cyclododecanone is oxidized on an industrial scale to give the corresponding dicarboxylic acid 1,12-dodecanedioic acid and laurolactam, which are precursors to certain specialized nylons. It is also precursor to cyclohexadecanone, which is used in some fragrances.

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