fulvenes
Sign in to savethumb|right|upright|Chemical structure of fulvene Fulvenes are the class of hydrocarbon obtained by formally cross-conjugating one ring and methylidene through a common exocyclic double bond.
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Encyclopedic overview
4 sectionsContents
- Preparation
- Properties
- Ligand in organometallic chemistry
- References
thumb|right|upright|Chemical structure of fulvene Fulvenes are the class of hydrocarbon obtained by formally cross-conjugating one ring and methylidene through a common exocyclic double bond.
In addition to compounds with substituent group on the fulvene skeleton, structural analogs in this class include heteroatom replacements and variations of ring-size. Thus, methylenecyclopropene can be called triafulvene and cyclopropenone is an oxafulvene. Analogs in which certain ring carbons are replaced by other elements, sometimes entailing changes of the double-bonding pattern of the heterocyclic core as in dithiafulvene, lead to changes in the electronic properties of the ring.
Excerpted from Wikipedia’s “fulvenes” article, available under the CC BY-SA 4.0 licence.