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thumb|right|upright|Chemical structure of fulvene Fulvenes are the class of hydrocarbon obtained by formally cross-conjugating one ring and methylidene through a common exocyclic double bond.

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  • Preparation
  • Properties
  • Ligand in organometallic chemistry
  • References

thumb|right|upright|Chemical structure of fulvene Fulvenes are the class of hydrocarbon obtained by formally cross-conjugating one ring and methylidene through a common exocyclic double bond.

In addition to compounds with substituent group on the fulvene skeleton, structural analogs in this class include heteroatom replacements and variations of ring-size. Thus, methylenecyclopropene can be called triafulvene and cyclopropenone is an oxafulvene. Analogs in which certain ring carbons are replaced by other elements, sometimes entailing changes of the double-bonding pattern of the heterocyclic core as in dithiafulvene, lead to changes in the electronic properties of the ring.

Excerpted from Wikipedia’s “fulvenes” article, available under the CC BY-SA 4.0 licence.

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