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Jacobsen's catalyst

Structure via PubChem · Public domain (PubChem)

EntityQ6119792· pop 8· linked from 10 articles

Jacobsen's catalyst

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chemical compound

Chemical data

Formula
C36H52ClMnN2O2
Molecular weight
635.2 g/mol
IUPAC name
2,4-ditert-butyl-6-[[(1R,2R)-2-[(3,5-ditert-butyl-2-oxidophenyl)methylideneamino]cyclohexyl]iminomethyl]phenolate;manganese(3+);chloride
SMILES
CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)[O-])C=N[C@@H]2CCCC[C@H]2N=CC3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)[O-].[Cl-].[Mn+3]
InChIKey
LJVAWOSDJSQANR-SEILFYAJSA-K
Polar surface area
70.8 Ų
H-bond donors
0
H-bond acceptors
5
Formal charge
0

via PubChem

Wikidata facts

Mass
634.309776684
Show 4 more facts
canonical SMILES
CC(C)(C)C1=CC(=C(C(=C1)C=NC2CCCCC2N=CC3=CC(=CC(=C3[O-])C(C)(C)C)C(C)(C)C)[O-])C(C)(C)C.[Cl-].[Mn+3]
Commons category
Jacobsen's catalyst
isomeric SMILES
CC(C)(C)c1cc2/C=N/[C@H]4CCCC[C@@H]4/N=C/c3cc(cc(c3O[Mn](Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
chemical formula
C₃₆H₅₂ClMnN₂O₂
Sources (2)

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