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myrophine

Structure via PubChem · Public domain (PubChem)

EntityQ6948508· pop 7· linked from 16 articles

Myrophine (Myristylbenzylmorphine) is an opiate analogue that was developed in 1952. It is a derivative of morphine.

Chemical data

Formula
C38H51NO4
Molecular weight
585.8 g/mol
IUPAC name
[(4R,4aR,7S,7aR,12bS)-3-methyl-9-phenylmethoxy-2,4,4a,7,7a,13-hexahydro-1H-4,12-methanobenzofuro[3,2-e]isoquinolin-7-yl] tetradecanoate
SMILES
CCCCCCCCCCCCCC(=O)O[C@H]1C=C[C@H]2[C@H]3CC4=C5[C@]2([C@H]1OC5=C(C=C4)OCC6=CC=CC=C6)CCN3C
InChIKey
GODGZZGKTZQSAL-VXFFQEMOSA-N
XLogP
9.5
Polar surface area
48 Ų
H-bond donors
0
H-bond acceptors
5
Formal charge
0

via PubChem

Wikidata facts

Mass
585.381809
Show 4 more facts
chemical formula
C₃₈H₅₁NO₄
canonical SMILES
CCCCCCCCCCCCCC(=O)OC1C=CC2C3CC4=C5C2(C1OC5=C(C=C4)OCC6=CC=CC=C6)CCN3C
isomeric SMILES
CCCCCCCCCCCCCC(=O)O[C@H]1C=C[C@H]2[C@H]3CC4=C5[C@]2([C@H]1OC5=C(C=C4)OCC6=CC=CC=C6)CCN3C
Commons category
Myrophine
Sources (2)

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Encyclopedic overview

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Contents
  • References

Myrophine (Myristylbenzylmorphine) is an opiate analogue that was developed in 1952. It is a derivative of morphine.

Myrophine is substituted with a 3-benzyl group and a 6-myristyl chain. It is metabolised to form benzylmorphine and then further to morphine, and so is a long-acting prodrug for morphine, but with a slow onset of effects. It is weaker than morphine as an analgesic but longer-lasting in effects, and was thought to have more local anesthetic effect than morphine, though with a somewhat greater tendency to cause reactions like itching and rash. In addiction studies conducted in human subjects in the 1950s, myrophine did not substitute for morphine in withdrawal, did not produce notable morphine-like effects, and did not produce addiction or dependence regardless of dose or how it was administered. Consequently, it was thought to be useful in treating pain in addicts who were being detoxified from other opioid drugs.

Excerpted from Wikipedia’s “myrophine” article, available under the CC BY-SA 4.0 licence.

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