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triethoxysilane

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triethoxysilane

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Triethoxysilane is an organosilicon compound with the formula HSi(OC2H5)3. It is a colourless liquid used in precious metal-catalysed hydrosilylation reactions. The resulting triethoxysilyl groups are often valued for attachment to silica surfaces. Compared to most compounds with Si-H bonds, triethoxysilane exhibits relatively low reactivity. Like most silyl ethers, triethoxysilane is susceptible to hydrolysis. As reducing agent, triethoxysilane can for example be used in reduction of amides, reduction of carbonyl compounds in the presence of cobalt(II) chloride as catalyst, Cu-catalyzed reduc

Chemical data

Formula
C6H16O3Si
Molecular weight
164.27 g/mol
IUPAC name
triethoxysilane
SMILES
CCO[SiH](OCC)OCC
InChIKey
QQQSFSZALRVCSZ-UHFFFAOYSA-N
Polar surface area
27.7 Ų
H-bond donors
0
H-bond acceptors
3
Formal charge
0

via PubChem

Wikidata facts

Mass
164.087
Show 4 more facts
chemical formula
C₆H₁₆O₃Si
canonical SMILES
CCO[SiH](OCC)OCC
melting point
-170.0
Commons category
Triethoxysilane
Sources (4)

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Encyclopedic overview

2 sections
Contents
  • Applications
  • References

Triethoxysilane is an organosilicon compound with the formula HSi(OC2H5)3. It is a colourless liquid used in precious metal-catalysed hydrosilylation reactions. The resulting triethoxysilyl groups are often valued for attachment to silica surfaces. Compared to most compounds with Si-H bonds, triethoxysilane exhibits relatively low reactivity. Like most silyl ethers, triethoxysilane is susceptible to hydrolysis. As reducing agent, triethoxysilane can for example be used in reduction of amides, reduction of carbonyl compounds in the presence of cobalt(II) chloride as catalyst, Cu-catalyzed reductive hydroxymethylation of styrenes, and Rh-catalyzed hydrodediazoniation.

== Applications == Compounds based on triethoxysilane might be used in fluoride varnish.

Excerpted from Wikipedia’s “triethoxysilane” article, available under the CC BY-SA 4.0 licence.

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