trimethylsilanol
Sign in to saveAlso known as TMS
Trimethylsilanol (TMS) is an organosilicon compound with the formula . The Si centre bears three methyl groups and one hydroxyl group. It is a colourless volatile liquid.
Wikidata facts
- Mass
- 90.05
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- Commons category
- Trimethylsilanol
- chemical formula
- C₃H₁₀OSi
- canonical SMILES
- C[Si](C)(C)O
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Article
7 sectionsContents
- Occurrence
- Production
- Reactions
- Structure
- Additional properties
- Bioactivity
- References
Trimethylsilanol (TMS) is an organosilicon compound with the formula . The Si centre bears three methyl groups and one hydroxyl group. It is a colourless volatile liquid.
==Occurrence== TMS is a contaminant in the atmospheres of spacecraft, where it arises from the degradation of silicone-based materials. Specifically, it is the volatile product from the hydrolysis of polydimethylsiloxane, which are generally terminated with trimethylsilyl groups: {{chem2|(CH3)3SiO[Si(CH3)2O]_{n}R + H2O → (CH3)3SiOH + HO[Si(CH3)2O]_{n}R}}