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trimethylsilanol

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Also known as TMS

Trimethylsilanol (TMS) is an organosilicon compound with the formula . The Si centre bears three methyl groups and one hydroxyl group. It is a colourless volatile liquid.

Wikidata facts

Mass
90.05
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Commons category
Trimethylsilanol
chemical formula
C₃H₁₀OSi
canonical SMILES
C[Si](C)(C)O
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~3 min read

Article

7 sections
Contents
  • Occurrence
  • Production
  • Reactions
  • Structure
  • Additional properties
  • Bioactivity
  • References

Trimethylsilanol (TMS) is an organosilicon compound with the formula . The Si centre bears three methyl groups and one hydroxyl group. It is a colourless volatile liquid.

==Occurrence== TMS is a contaminant in the atmospheres of spacecraft, where it arises from the degradation of silicone-based materials. Specifically, it is the volatile product from the hydrolysis of polydimethylsiloxane, which are generally terminated with trimethylsilyl groups: {{chem2|(CH3)3SiO[Si(CH3)2O]_{n}R + H2O → (CH3)3SiOH + HO[Si(CH3)2O]_{n}R}}

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