Category
page 1Refrigerants
water
Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and nearly colorless chemical substance. It is the main constituent of Earth's streams, lakes, and oceans and the fluids of all known living organisms, in which it acts as a solvent. Water, being a polar molecule, undergoes strong intermolecular hydrogen bonding which is a large contributor to its physical and chemical properties. It is vital for all known forms of life, despite not providing food energy or being an organic micronutrient. Due to its presence in all organisms, its chemical stabi

hydrogen
Hydrogen is a chemical element; it has the symbolH and atomic number1. It is the lightest and most abundant chemical element in the universe, constituting about 75% of all normal matter. Under standard conditions, hydrogen is a gas of diatomic molecules with the formula, called dihydrogen, or sometimes hydrogen gas, molecular hydrogen, or simply hydrogen. Dihydrogen is colorless, odorless, non-toxic, and highly combustible. Stars, including the Sun, mainly consist of hydrogen in a plasma state, while on Earth, hydrogen is found as the gas (dihydrogen) and in molecules, such as in water and org
neon
Neon is a chemical element; it has the symbol Ne and the atomic number 10. It is the second noble gas in the periodic table. Neon is a colorless, odorless, inert monatomic gas under standard conditions, with approximately two-thirds the density of air.
carbon dioxide
chemical compound
ammonia
sulfur dioxide
chemical compound
butane
Butane () is an alkane with the formula C4H10. Butane exists as two isomers, n-butane, and iso-butane, . Both isomers are highly flammable, colorless, easily liquefied gases that quickly vaporize at room temperature and pressure. Butanes are a trace component of natural gases, which contain higher concentrations of other hydrocarbons such as propane, ethane, and especially methane. Liquefied petroleum gas is a mixture of propane and some butanes.

propane
thumb|A 20 lb () steel propane cylinder. This cylinder is fitted with an overfill prevention device (OPD) valve, as evidenced by the trilobular handwheel.
Propane () is a three-carbon chain alkane with the molecular formula . It is a gas at standard temperature and pressure, but becomes liquid when compressed for transportation and storage. A by-product of natural gas processing and petroleum refining, it is often a constituent of liquefied petroleum gas (LPG), which is commonly used as a fuel in domestic and industrial applications and in low-emissions public transportation; other constituent
chlorofluorocarbon
Chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) are fully or partly halogenated hydrocarbons that contain carbon (C), hydrogen (H), chlorine (Cl), and fluorine (F). They are produced as volatile derivatives of methane, ethane, and propane.
dry ice
solid carbon dioxide
carbon tetrachloride
chemical compound
haloalkane
thumb|upright|Tetrafluoroethane (a haloalkane) is a colorless liquid that boils well below room temperature (as seen here) and can be extracted from common [[canned air canisters by simply inverting them during use.]]

dichloromethane
Dichloromethane (DCM, methylene chloride, or methylene bichloride) is an organochlorine compound with the formula . This colorless, volatile liquid with a chloroform-like, sweet odor is widely used as a solvent. Although it is not miscible with water, it is slightly polar and miscible with many organic solvents.

brine
Brine (or briny water) is a high-concentration solution of salt (typically sodium chloride or calcium chloride) in water. In diverse contexts, brine may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawater, on the lower end of that of solutions used for brining foods) up to about 26% (a typical saturated solution, depending on temperature). Brine forms naturally due to evaporation of ground saline water but it is also generated in the mining of sodium chloride. Brine is used for food processing and cooking (pickling and brining), for de-icing of roads and ot

methyl chloride
Chloromethane, also called methyl chloride, Refrigerant-40, R-40 or HCC 40, is an organic compound with the chemical formula . One of the haloalkanes, it is a colorless, sweet-smelling, flammable gas. Methyl chloride is a crucial reagent in industrial chemistry, although it is rarely present in consumer products, and was formerly utilized as a refrigerant. Most chloromethane is biogenic.
refrigerant
Refrigerants are working fluids that carry heat from a cold environment to a warm environment while circulating between them. For example, the refrigerant in an air conditioner carries heat from a cool indoor environment to a hotter outdoor environment. Similarly, the refrigerant in a kitchen refrigerator carries heat from the inside the refrigerator out to the surrounding room. A wide range of fluids are used as refrigerants, with the specific choice depending on the temperature range needed and constraints related to the system involved.
sulfur hexafluoride
chemical compound, non-toxic, climate-damaging gas
isobutane
Isobutane, also known as '''i-butane, 2-methylpropane or methylpropane''', is a chemical compound with molecular formula HC(CH3)3. An isomer of butane, it is a colorless, odorless gas. Isobutane is the simplest alkane with a tertiary carbon atom, and is used as a precursor molecule in the petrochemical industry, such as in the synthesis of isooctane.
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freon
thumb|A can of 1,1,1,2-Tetrafluoroethane (Freon 134a) used for recharging vehicle air conditioning
Freon ( ) is a registered trademark of Chemours and generic descriptor for a number of halocarbon products. They are stable, nonflammable, low toxicity gases or liquids which have generally been used as refrigerants and as aerosol propellants. They include chlorofluorocarbons (CFCs) and hydrofluorocarbons (HFCs), both of which cause ozone depletion (although the latter much less so) and contribute to global warming. "Freon" is the brand name for the refrigerants R-12, R-13B1, R-22, R-410A, R-502,
tetrafluoromethane
chemical compound

norflurane
1,1,1,2-Tetrafluoroethane (also known as norflurane (INN), R-134a, Klea 134a, Freon 134a, Forane 134a, Genetron 134a, Green Gas, Florasol 134a, Suva 134a, HFA-134a, or HFC-134a) is a hydrofluorocarbon (HFC) and haloalkane refrigerant with thermodynamic properties similar to R-12 (dichlorodifluoromethane) but with insignificant ozone depletion potential and a lower 100-year global warming potential (1,430, compared to R-12's GWP of 10,900). It has the formula CFCHF and a boiling point of −26.3 °C (−15.34 °F) at atmospheric pressure. R-134a cylinders are colored light blue. A phaseout
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chlorodifluoromethane
Chlorodifluoromethane or difluoromonochloromethane is a hydrochlorofluorocarbon (HCFC). This colorless gas is better known as HCFC-22, or R-22, or . It was commonly used as a propellant and refrigerant. These applications were phased out under the Montreal Protocol in developed countries in 2020 due to the compound's ozone depletion potential (ODP) and high global warming potential (GWP), and in developing countries this process will be completed by 2030. R-22 is a versatile intermediate in industrial organofluorine chemistry, e.g. as a precursor to tetrafluoroethylene.
== Production and curr
dichlorodifluoromethane
Dichlorodifluoromethane (R-12) is a colorless gas popularly known by the genericized brand name Freon (as Freon-12). It is a chlorofluorocarbon halomethane (CFC) used as a refrigerant and aerosol spray propellant. In compliance with the Montreal Protocol, its manufacture was banned in developed countries (non-article 5 countries) in 1996, and in developing countries (Article 5 countries) in 2010 out of concerns about its damaging effect on the ozone layer. Its only allowed usage is as a fire retardant in submarines and aircraft. It is soluble in many organic solvents. R-12 cylinders are colore
trichloromonofluoromethane
Trichlorofluoromethane, also called freon-11, CFC-11, or R-11, is a chlorofluorocarbon (CFC). It is a colorless, faintly ethereal, and sweetish-smelling liquid that boils around room temperature. CFC-11 is a Class 1 ozone-depleting substance which damages Earth's protective stratospheric ozone layer. R-11 is not flammable at ambient temperature and pressure but it can become very combustible if heated and ignited by a strong ignition source.
fluoromethane
Fluoromethane, also known as methyl fluoride, Freon 41, Halocarbon-41 and HFC-41, is a non-toxic, liquefiable, and flammable gas at standard temperature and pressure. It is made of carbon, hydrogen, and fluorine. The name stems from the fact that it is methane (CH4) with a fluorine atom substituted for one of the hydrogen atoms. It is used in semiconductor manufacturing processes as an etching gas in plasma etch reactors.

fluoroform
Fluoroform, or trifluoromethane, is the chemical compound with the formula . It is a hydrofluorocarbon as well as being a part of the haloforms, a class of compounds with the formula (X = halogen) with C3v symmetry. Fluoroform is used in diverse applications in organic synthesis. It is not an ozone depleter but is a greenhouse gas.
chlorotrifluoromethane
Chlorotrifluoromethane, R-13, CFC-13, or Freon 13, is a non-flammable, non-corrosive, nontoxic chlorofluorocarbon (CFC) and also a mixed halomethane. It is a man-made substance used primarily as a refrigerant. When released into the environment, CFC-13 has a high ozone depletion potential, and long atmospheric lifetime. Only a few other greenhouse gases surpass CFC-13 in global warming potential (GWP). The IPCC AR5 reported that CFC-13's atmospheric lifetime was 640 years.
dibromomethane
Dibromomethane or methylene bromide, or methylene dibromide is a halomethane with the formula CH2Br2. It is slightly soluble in water but very soluble in organic solvents. It is a colorless liquid.
difluoromethane
Difluoromethane, also called HFC-32 or R-32, is an organofluorine compound with the formula CH2F2. It is a colorless gas that is used as a refrigerant. As a hydrofluorocarbon, R-32 is being phased out in the EU.
== Synthesis ==
Difluoromethane is produced by the reaction of dichloromethane and hydrogen fluoride (HF) using SbF5 as a catalyst.

trihalomethane
In chemistry, trihalomethanes (THMs) are chemical compounds in which three of the four hydrogen atoms of methane () are replaced by halogen atoms. Trihalomethanes with all the same halogen atoms are called haloforms. Many trihalomethanes find uses in industry as solvents or refrigerants. Some THMs are also environmental pollutants, and a few are considered carcinogenic.
chlorofluoromethane
Chlorofluoromethane or Freon 31 is the hydrochlorofluorocarbon (HCFC) with the formula CH2ClF. It is a colorless, odorless, flammable gas. It is a class II ozone depleting substance and in accordance with the Montreal protocol, its production and import were banned on 1 January 2015.

1,1,2,2-tetrachlorethane
1,1,2,2-Tetrachloroethane (TeCA), also known as acetylene tetrachloride and by the brand names Bonoform, Cellon and Westron, is an organochloride. It is a dense, colorless, non-flammable liquid with a sweet odor, used as an industrial solvent and as a separation agent. TeCA is toxic to humans via inhalation, ingestion and skin absorption. After exposure, nausea, dizziness or liver damage may occur.
dichlorofluoromethane
Dichlorofluoromethane or Freon 21 or R 21 is a halomethane or hydrochlorofluorocarbon with the formula CHCl2F. It is a colorless and odorless gas. It is produced by fluorination of chloroform using a catalyst such as antimony trifluoride:
CHCl3 + HF → CHCl2F + HCl

dichlorotetrafluoroethane
1,2-Dichlorotetrafluoroethane, or R-114, also known as cryofluorane (INN), is a chlorofluorocarbon (CFC) with the molecular formula ClFCCFCl. Its primary use has been as a refrigerant. It is a non-flammable gas with a sweetish, chloroform-like odor with the critical point occurring at 145.6 °C and 3.26 MPa. When pressurized or cooled, it is a colorless liquid. It is listed on the Intergovernmental Panel on Climate Change's list of ozone depleting chemicals, and is classified as a Montreal Protocol Class I, group 1 ozone depleting substance.
==Uses==
When used as a refrigerant, R-114
vinyl fluoride
chemical compound

R-410A
R-410A is a refrigerant fluid used in air conditioning and heat pump applications. It is a zeotropic but near-azeotropic mixture of difluoromethane (CH2F2, called R-32) and pentafluoroethane (CHF2CF3, called R-125). R-410A is sold under the trademarked names AZ-20, EcoFluor R410, Forane 410A, Genetron R410A, Puron, and Suva 410A. Due to its high global warming potential, R410A is being phased out in several countries.

1,1,1-trifluoroethane
1,1,1-Trifluoroethane, or R-143a or simply trifluoroethane, is a hydrofluorocarbon (HFC) compound that is a colorless gas. It should not be confused with the much more commonly used HFC gas R-134a, nor confused with the isomeric compound 1,1,2-trifluoroethane. 1,1,1-Trifluoroethane has a critical temperature of 73 °C.
bromodifluoromethane
Bromodifluoromethane or Halon 1201 or FC-22B1 is a gaseous trihalomethane or a hydrobromofluorocarbon.

1,1-difluoroethane
1,1-Difluoroethane, or DFE, is an organofluorine compound with the chemical formula CHF. This colorless gas is used as a refrigerant, where it is often listed as R-152a (refrigerant-152a) or HFC-152a (hydrofluorocarbon-152a). It is also used as a propellant for aerosol sprays and in gas duster products. As an alternative to chlorofluorocarbons, it has a global warming potential of 120-140, lower than other hydrofluorocarbons, and a shorter atmospheric lifetime (1.4 years).
chlorotrifluoroethene
Chlorotrifluoroethylene (CTFE) is a chlorofluorocarbon with chemical formula CFCl=CF2. It is commonly used as a refrigerant in cryogenic applications. CTFE has a carbon-carbon double bond and so can be polymerized to form polychlorotrifluoroethylene or copolymerized to produce the plastic ECTFE. PCTFE has the trade name Neoflon PCTFE from Daikin Industries in Japan, and it used to be produced under the trade name Kel-F from 3M Corporation in Minnesota.

1,1-dichloro-1-fluoroethane
1,1-Dichloro-1-fluoroethane is a haloalkane with the formula . It is one of the three isomers of dichlorofluoroethane. It belongs to the hydrochlorofluorocarbon (HCFC) family of man-made compounds that contribute significantly to both ozone depletion and global warming when released into the environment.
2,3,3,3-tetrafluoropropene
2,3,3,3-Tetrafluoropropene, HFO-1234yf, is a hydrofluoroolefin (HFO) with molecular formula CH2=CFCF3. Its primary application is as a refrigerant with low global warming potential (GWP).
chloropentafluoroethane
Chloropentafluoroethane is a chlorofluorocarbon (CFC) once used as a refrigerant and also known as R-115 and CFC-115. Its production and consumption has been banned since 1 January 1996 under the Montreal Protocol because of its high ozone depletion potential and very long lifetime when released into the environment. CFC-115 is also a potent greenhouse gas.

1-chloro-1,1-difluoroethane
1-Chloro-1,1-difluoroethane (HCFC-142b) is a haloalkane with the chemical formula CH3CClF2. It belongs to the hydrochlorofluorocarbon (HCFC) family of man-made compounds that contribute significantly to both ozone depletion and global warming when released into the environment. It is primarily used as a refrigerant where it is also known as R-142b and by trade names including Freon-142b.

hexafluoroethane
Hexafluoroethane is an organofluorine compound with the chemical formula . It is a non-flammable colorless odorless gas negligibly soluble in water and slightly soluble in methanol. Its structure is . It is an extremely potent and long-lived greenhouse gas. It is the perfluorocarbon counterpart to the hydrocarbon ethane.
apaflurane
1,1,1,2,3,3,3-Heptafluoropropane, also called heptafluoropropane, HFC-227ea (ISO name), HFC-227 or FM-200, as well as apaflurane (INN), is a colourless, odourless gaseous halocarbon commonly used as a gaseous fire suppression agent.
2,2-dichloro-1,1,1-trifluoroethane
2,2-Dichloro-1,1,1-trifluoroethane or HCFC-123 is considered as an alternative to CFC-11 in low pressure refrigeration and HVAC systems, and should not be used in foam blowing processes or solvent applications. It is also the primary component of the Halotron I fire-extinguishing mixture.
1,1,1,2-tetrafluorochloroethane
1-Chloro-1,2,2,2-tetrafluoroethane, C2HClF4, is a hydrochlorofluorocarbon used as a component in refrigerants offered as replacements for chlorofluorocarbons. HCFC-124 is also used in gaseous fire suppression systems as a replacement for bromochlorocarbons.
octafluorocyclobutane
Octafluorocyclobutane, or perfluorocyclobutane, C4F8, is an organofluorine compound which enjoys several niche applications. Octafluorocyclobutane is a colourless gas and shipped as a liquefied gas. It is the perfluorinated analogue of cyclobutane whereby all C–H bonds are replaced with C–F bonds.
halomethane
alt=Molecule of methane. |thumb|A methane [[molecule in 3D space filling model.]]
Halomethane compounds are derivatives of methane () with one or more of the hydrogen atoms replaced with halogen atoms (F, Cl, Br, or I). Halomethanes are both naturally occurring, especially in marine environments, and human-made, most notably as refrigerants, solvents, propellants, and fumigants. Many, including the chlorofluorocarbons, have attracted wide attention because they become active when exposed to ultraviolet light found at high altitudes and destroy the Earth's protective ozone layer.
octafluoropropane
Octafluoropropane (C3F8) is the perfluorocarbon counterpart to the hydrocarbon propane. This non-flammable and non-toxic synthetic substance has applications in semiconductor production and medicine. It is also an extremely potent greenhouse gas.
1,1-dichloro-2,2-difluoroethylene
A dichlorodifluoroethylene (systematically named dichlorodifluoroethene) is one of three compounds with the chemical formula . Dichlorodifluoroethylenes are colourless gases, and are some of the simplest chlorodifluoroalkenes.
1,1,1,3,3,3-hexafluoropropane
1,1,1,3,3,3-Hexafluoropropane is an organic chemical, an organofluoride. It is a colorless gas, usually available in the form of a liquid gas. It is used as a fire suppression agent, a foaming agent, a highly effective refrigerant, a heat transfer medium, a dielectric gas, a sterilant carrier, a polymerization medium, a carrier fluid, a displacement drying agent, a thermodynamic power cycle working fluid, etc. It is used as a cold gas rocket propellant by the Mars Cube One spacecraft.
2-chloro-1,1,1-trifluoroethane
2-Chloro-1,1,1-trifluoroethane, also known as 1,1,1-trifluoro-2-chloroethane or Freon 133a, is an alkyl halide belonging to the category of hydrochlorofluorocarbons, having chemical formula F3C-CH2-Cl. Under standard conditions, it appears as a colorless gas, partially soluble in water. It is used as a refrigerant, as a solvent and as a reagent in organic synthesis.
hydrofluoroolefin
class=skin-invert-image|thumb|right|150px|Chemical structure of 1,3,3,3-Tetrafluoropropene|1,3,3,3-tetrafluoropropene (HFO-1234ze)
Hydrofluoroolefins (HFOs) are unsaturated organic compounds composed of hydrogen, fluorine and carbon. These organofluorine compounds are of interest as refrigerants. Unlike traditional hydrofluorocarbons (HFCs) and chlorofluorocarbons (CFCs), which are saturated, HFOs are olefins, otherwise known as alkenes.
list of refrigerants
Wikimedia list article
R-407C
thumb | 220x124px | right | R-407C container
R-407C is a mixture of hydrofluorocarbons used as a refrigerant. It is a zeotropic blend of difluoromethane (R-32), pentafluoroethane (R-125), and 1,1,1,2-tetrafluoroethane (R-134a). Difluoromethane provides heat capacity, pentafluoroethane decreases flammability, and tetrafluoroethane reduces pressure. R-407C has a glide of approximately 5°C compared with R-410a which has less than 0.17K. R-407C cylinders are colored burnt orange.
1,1,1-trichloro-2,2,2-trifluoroethane
1,1,1-Trichloro-2,2,2-trifluoroethane, also called Asymmetrical trichlorotrifluoroethane or CFC-113a, is a chlorofluorocarbon (CFC) with the formula .
Trifluoroethane
Trifluoroethane may refer to either of two isomeric fluorocarbons which differ by the location of attachment of the fluorine atoms:
1,1,2-Trifluoroethane (R-143)
1,1,1-Trifluoroethane (R-143a)
1,1,1,3,3-pentafluoropropane
1,1,1,3,3-Pentafluoropropane (HFC-245fa) is a hydrofluorocarbon, a colorless gas which is used primarily for closed-cell spray foam insulation. HFC-245fa is also known as pentafluoropropane and by its chemical name 1,1,1,3,3-pentafluoropropane.