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acenaphthene

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acenaphthene

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Also known as peri-ethylenenaphthalene

Acenaphthene is a polycyclic aromatic hydrocarbon (PAH) consisting of naphthalene with an ethylene bridge connecting positions 1 and 8. It is a colourless solid. Coal tar consists of about 0.3% of this compound.

Chemical data

Formula
C12H10
Molecular weight
154.21 g/mol
IUPAC name
1,2-dihydroacenaphthylene
SMILES
C1CC2=CC=CC3=C2C1=CC=C3
InChIKey
CWRYPZZKDGJXCA-UHFFFAOYSA-N
XLogP
3.9
Polar surface area
0 Ų
H-bond donors
0
H-bond acceptors
0
Formal charge
0

via PubChem

Wikidata facts

Mass
154.078
Show 7 more facts
Commons category
Acenaphthene
chemical formula
C₁₂H₁₀
electric dipole moment
0.85
ionization energy
7.68
boiling point
279
melting point
94
canonical SMILES
C1CC2=CC=CC3=C2C1=CC=C3
Sources (3)

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Article

3 sections
Contents
  • Production and reactions
  • Uses
  • References

Acenaphthene is a polycyclic aromatic hydrocarbon (PAH) consisting of naphthalene with an ethylene bridge connecting positions 1 and 8. It is a colourless solid. Coal tar consists of about 0.3% of this compound.

==Production and reactions== Acenaphthene was prepared for the first time in 1866 by Marcellin Berthelot by reacting hot naphthalene vapours with acetylene, and a year later he reproduced a similar reaction with ethylene as well as discovered acenaphthene in coal tar. Later Berthelot and Bardy synthesized the compound by cyclization of α-ethylnaphthalene. Industrially, it is still obtained from coal tar together with its derivative acenaphthylene (and many other compounds).

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