ladderane
Sign in to savethumb|Simple ladderane structure thumb|A licorice model of the chemical structure of the 3-ladderane molecule
~10 min read
Encyclopedic overview
12 sectionsContents
- Nomenclature
- Chain length
- Stereochemistry
- Synthesis
- Dimerization of cyclobutadiene
- Synthesis of a [4]-ladderdiene
- Synthesis of long-chain ladderanes
- Dimerization of polyene precursors
- Biological background
- Synthesis of ladderane lipids
- See also
- References
thumb|Simple ladderane structure thumb|A licorice model of the chemical structure of the 3-ladderane molecule
In chemistry, a ladderane is an organic molecule containing two or more fused cyclobutane rings. The name arises from the resemblance of a series of fused cyclobutane rings to a ladder. Numerous synthetic approaches have been developed for the synthesis of ladderane compounds of various lengths. The mechanisms often involve [[Woodward-Hoffmann rules|[2 + 2] photocycloadditions]], a useful reaction for creating strained 4-membered rings. Naturally occurring ladderanes have been identified as major components of the anammoxosome membrane of the anammox bacteria, phylum Planctomycetota.
Excerpted from Wikipedia’s “ladderane” article, available under the CC BY-SA 4.0 licence.