File:Hydrazin.svg · Wikimedia Commons · See Wikimedia Commons
hydrazine
Sign in to saveAlso known as diazane, tetrahydridodinitrogen, H2NNH2, N2H4, nitrogen hydride, diamine, hydrazin, inorganic hydrazine
OverviewAI-generated
Hydrazine is a chemical compound with the formula N₂H₄, also written as H₄N₂. It has a molecular mass of 32.05 and a density of 1.01. The substance melts at 36 and boils at 236. Its vapor pressure is 10, and it has an electric dipole moment of 1.75. The pKa of hydrazine is 8.10, while its ionization energy is 8.93.
Safety data indicates that hydrazine has a flash point of 99. The lower flammable limit is 2.9, and the upper flammable limit is 98. The immediately dangerous to life or health concentration is 65.5. Exposure limits include a time-weighted average of 1.3 and a ceiling of 0.04. The compound has two hydrogen bond donors and two hydrogen bond acceptors, with a topological polar surface area of 52.
Synthesized by Vinony from 32 facts across 4 sources: Wikidata, PubChem, PubMed, Vinony graph. Generated from structured data (not the Wikipedia text) and checked against those facts — may still contain errors.
Chemical data
- Formula
- H4N2
- Molecular weight
- 32.046 g/mol
- IUPAC name
- hydrazine
- SMILES
- NN
- InChIKey
- OAKJQQAXSVQMHS-UHFFFAOYSA-N
- XLogP
- -1.5
- Polar surface area
- 52 Ų
- H-bond donors
- 2
- H-bond acceptors
- 2
- Formal charge
- 0
via PubChem
Research
61,119 papers- Bacterial Hydrazine Biosynthetic Pathways Featuring Cupin/Methionyl tRNA Synthetase-like Enzymes.ReviewChembiochem : a European journal of chemical biology · 2024Matsuda K, Wakimoto TDOI: 10.1002/cbic.202300874
- Hydrazine.ReviewIARC monographs on the evaluation of carcinogenic risks to humans · 1999
- The Hydrazine Moiety in the Synthesis of Modified Nucleosides and Nucleotides.ReviewChemMedChem · 2024Guillou A, Peyrottes S, Vasseur JJ et al.DOI: 10.1002/cmdc.202400234
- Hydrazine Exposé: The Next-Generation Fluorescent Probe.ACS sensors · 2019Jung Y, Ju IG, Choe YH et al.DOI: 10.1021/acssensors.8b01429
- Hydrazine reagents as derivatizing agents in environmental analysis--a critical review.ReviewFresenius' journal of analytical chemistry · 2000Vogel M, Büldt A, Karst UDOI: 10.1007/s002160051572
- Natural hydrazine-containing compounds: Biosynthesis, isolation, biological activities and synthesis.ReviewBioorganic & medicinal chemistry · 2014Le Goff G, Ouazzani JDOI: 10.1016/j.bmc.2014.10.011
- Risk assessment of trace hydrazine in a 2020 bottled water-associated nonviral hepatitis outbreak.ReviewCritical reviews in toxicology · 2025Deckard BM, McCauley KM, Stevens ME et al.DOI: 10.1080/10408444.2025.2600331
- The Toxicity, Pathophysiology, and Treatment of Acute Hydrazine Propellant Exposure: A Systematic Review.Military medicine · 2021Nguyen HN, Chenoweth JA, Bebarta VS et al.DOI: 10.1093/milmed/usaa429
via PubMed
~25 min read
Encyclopedic overview
26 sectionsContents
- Etymology and history
- Applications
- Gas producers and propellants
- Precursor to pesticides and pharmaceuticals
- Small-scale, niche, and research
- Rocket fuel
- Occupational hazards
- Health effects
- Occupational exposure limits
- Handling and medical surveillance
- Molecular structure
- Synthesis and production
- Oxidation of ammonia via oxaziridines from peroxide
- Chlorine-based oxidations
- Reactions
- Acid-base behavior
- Redox reactions
- Hydrazinium salts
- Organic chemistry
- Hydrazone formation
- Biochemistry
- In popular culture
- See also
- References
- Further reading
- External links
Hydrazine is an inorganic compound with the chemical formula . It is a simple pnictogen hydride, and is a colourless flammable liquid with an ammonia-like odour. Hydrazine is highly hazardous unless handled in solution as, for example, hydrazine hydrate ().
Hydrazine is mainly used as a foaming agent in preparing polymer foams, but applications also include its uses as a precursor to pharmaceuticals and agrochemicals, as well as a long-term storable propellant for in-space spacecraft propulsion. Additionally, hydrazine is used in various rocket fuels and to prepare the gas precursors used in airbags. Hydrazine is used within both nuclear and conventional electrical power plant steam cycles as an oxygen scavenger to control concentrations of dissolved oxygen in an effort to reduce corrosion. , approximately 120,000 tons of hydrazine hydrate (corresponding to a 64% solution of hydrazine in water by weight) were manufactured worldwide per year.
Excerpted from Wikipedia’s “hydrazine” article, available under the CC BY-SA 4.0 licence.
Gallery (27)
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