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orbital hybridization

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orbital hybridization

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Also known as orbital hybridisation, hybrid orbital

mixing (superposition) of atomic orbitals in chemistry

~16 min read

Encyclopedic overview

In chemistry, orbital hybridisation (or hybridization) is the concept of mixing atomic orbitals to form new hybrid orbitals (with different energies, shapes, etc., than the component atomic orbitals) suitable for the pairing of electrons to form chemical bonds in valence bond theory. For example, in a carbon atom which forms four single bonds, the valence-shell s orbital combines with three valence-shell p orbitals to form four equivalent sp mixtures in a tetrahedral arrangement around the carbon to bond to four different atoms. Hybrid orbitals are useful in the explanation of molecular geometry and atomic bonding properties and are symmetrically disposed in space. Usually hybrid orbitals are formed by mixing atomic orbitals of comparable energies.

History and uses

Excerpted from Wikipedia’s “orbital hybridization” article, available under the CC BY-SA 4.0 licence.

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