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phenylphosphine

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phenylphosphine

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Also known as Fenylfosfin, PF, phosphaniline

Phenylphosphine is an organophosphorus compound with the chemical formula C6H5PH2. It is the phosphorus analog of aniline. Like other primary phosphines, phenylphosphine has an intense penetrating odor and is highly oxidizable. It is mainly used as a precursor to other organophosphorus compounds. It can function as a ligand in coordination chemistry.

Chemical data

Formula
C6H7P
Molecular weight
110.09 g/mol
IUPAC name
phenylphosphane

via PubChem

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Encyclopedic overview

3 sections
Contents
  • Synthesis
  • Reactions
  • References

Phenylphosphine is an organophosphorus compound with the chemical formula C6H5PH2. It is the phosphorus analog of aniline. Like other primary phosphines, phenylphosphine has an intense penetrating odor and is highly oxidizable. It is mainly used as a precursor to other organophosphorus compounds. It can function as a ligand in coordination chemistry.

==Synthesis== Phenylphosphine can be produced by reducing dichlorophenylphosphine with lithium aluminum hydride in ether: LiAlH4 + 2C6H5PCl2 → 2C6H5PH2 + Li+ + Al3+ + 4Cl− This reaction is performed under a nitrogen atmosphere to prevent side reactions involving oxygen.

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