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phenylphosphine
Sign in to saveAlso known as Fenylfosfin, PF, phosphaniline
Phenylphosphine is an organophosphorus compound with the chemical formula C6H5PH2. It is the phosphorus analog of aniline. Like other primary phosphines, phenylphosphine has an intense penetrating odor and is highly oxidizable. It is mainly used as a precursor to other organophosphorus compounds. It can function as a ligand in coordination chemistry.
Chemical data
- Formula
- C6H7P
- Molecular weight
- 110.09 g/mol
- IUPAC name
- phenylphosphane
via PubChem
Wikidata facts
- Subclass of
- chemical compound
- Has part
- hydrogen
- Mass
- 110.029
Show 8 more facts
- chemical formula
- C₆H₇P
- canonical SMILES
- C1=CC=C(C=C1)P
- NIOSH Pocket Guide ID
- 0501
- density
- 1.001
- boiling point
- 320
- ceiling exposure limit
- 0.25
- Commons category
- Phenylphosphine
- has characteristic
- flammable liquid
via Wikidata · CC0
~2 min read
Encyclopedic overview
3 sectionsContents
- Synthesis
- Reactions
- References
Phenylphosphine is an organophosphorus compound with the chemical formula C6H5PH2. It is the phosphorus analog of aniline. Like other primary phosphines, phenylphosphine has an intense penetrating odor and is highly oxidizable. It is mainly used as a precursor to other organophosphorus compounds. It can function as a ligand in coordination chemistry.
==Synthesis== Phenylphosphine can be produced by reducing dichlorophenylphosphine with lithium aluminum hydride in ether: LiAlH4 + 2C6H5PCl2 → 2C6H5PH2 + Li+ + Al3+ + 4Cl− This reaction is performed under a nitrogen atmosphere to prevent side reactions involving oxygen.
Excerpted from Wikipedia’s “phenylphosphine” article, available under the CC BY-SA 4.0 licence.