plutonocene
Sign in to savePlutonocene, Pu(C8H8)2, is an organoplutonium compound composed of a plutonium atom sandwiched between two cyclooctatetraenide (COT2-) rings. It is a dark red, very air-sensitive solid that is sparingly soluble in toluene and chlorocarbons. Plutonocene is a member of the actinocene family of metallocenes incorporating actinide elements in the +4 oxidation state.
~3 min read
Article
4 sectionsContents
- Structure and bonding
- Synthesis
- Other properties
- References
Plutonocene, Pu(C8H8)2, is an organoplutonium compound composed of a plutonium atom sandwiched between two cyclooctatetraenide (COT2-) rings. It is a dark red, very air-sensitive solid that is sparingly soluble in toluene and chlorocarbons. Plutonocene is a member of the actinocene family of metallocenes incorporating actinide elements in the +4 oxidation state.
Compared to other actinocenes such as uranocene, plutonocene has been studied to a lesser degree since the 1980s due to the notable radiation hazard posed by the compound. Instead, it has mostly been the subject of theoretical studies relating to the bonding in the molecule.