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tetraphosphorus hexaoxide

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tetraphosphorus hexaoxide

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Also known as Phosphorus(III) oxide, tetraphosphorus hexoxide, (P2O3)2, P4O6, 2,4,6,8,9,10-hexaoxa-1,3,5,7-tetraphosphatricyclo[3.3.1.1(3,7)]decane, phosphorus oxide

chemical compound

Chemical data

Formula
O6P4
Molecular weight
219.89 g/mol
IUPAC name
2,4,6,8,9,10-hexaoxa-1,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane
SMILES
O1P2OP3OP1OP(O2)O3
InChIKey
VSAISIQCTGDGPU-UHFFFAOYSA-N
XLogP
-0.2
Polar surface area
55.4 Ų
H-bond donors
0
H-bond acceptors
6
Formal charge
0

via PubChem

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Encyclopedic overview

Phosphorus trioxide is the chemical compound with the molecular formula P4O6. Although the molecular formula suggests the name tetraphosphorus hexoxide, the name phosphorus trioxide preceded the knowledge of the compound's molecular structure, and its usage continues today. This colorless solid is structurally related to adamantane. It is formally the anhydride of phosphorous acid, H3PO3, but cannot be obtained by the dehydration of the acid. A white solid that melts at room temperature, it is waxy, crystalline and highly toxic, with garlic odor.

Preparation

Excerpted from Wikipedia’s “tetraphosphorus hexaoxide” article, available under the CC BY-SA 4.0 licence.