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thiourea

Structure via PubChem · Public domain (PubChem)

EntityQ528995· pop 35· linked from 250 articles

Also known as thiocarbonic acid diamide, 2-thiourea, thiocarbamide, carbonothioic diamide, aminothioamide, aminothiocarboxamide

Thiourea () is an organosulfur compound with the formula and the structure . It is structurally similar to urea (), with the oxygen atom replaced by sulfur atom (as implied by the thio- prefix). The properties of urea and thiourea differ significantly. Thiourea is a reagent in organic synthesis. Thioureas are a broad class of compounds with the formula

Chemical data

Formula
CH4N2S
Molecular weight
76.12 g/mol
IUPAC name
thiourea
SMILES
C(=S)(N)N
InChIKey
UMGDCJDMYOKAJW-UHFFFAOYSA-N
XLogP
-0.8
Polar surface area
84.1 Ų
H-bond donors
2
H-bond acceptors
1
Formal charge
0

via PubChem

Wikidata facts

Mass
76.01
Show 5 more facts
Commons category
Thiourea
canonical SMILES
C(=S)(N)N
chemical formula
CH₄N₂S
melting point
177.0
MCN code
2930.90.21
Sources (5)

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Article

18 sections
Contents
  • Structure and bonding
  • Production
  • Applications
  • Thiox precursor
  • Pharmaceuticals
  • Other uses
  • Reactions
  • Oxidation
  • Reductant
  • Precursor to thiols
  • Precursor to metal sulfides
  • Precursor to heterocycles
  • With metals
  • Safety
  • See also
  • References
  • Further reading
  • External links

Thiourea () is an organosulfur compound with the formula and the structure . It is structurally similar to urea (), with the oxygen atom replaced by sulfur atom (as implied by the thio- prefix). The properties of urea and thiourea differ significantly. Thiourea is a reagent in organic synthesis. Thioureas are a broad class of compounds with the formula

==Structure and bonding== Thiourea is a planar molecule. The C=S bond distance is 1.71 Å. The C-N distances average 1.33 Å. The weakening of the C-S bond by C-N pi-bonding is indicated by the short C=S bond in thiobenzophenone, which is 1.63 Å.

Gallery (11)

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