α-Chaconine is a steroidal glycoalkaloid that occurs in plants of the family Solanaceae. It is a natural toxicant produced in green potatoes and gives the potato a bitter taste. Tubers produce this glycoalkaloid in response to stress, providing the plant with insecticidal and fungicidal properties. It belongs to the chemical family of saponins. Since it causes physiological effects on individual organism, chaconine is considered to be a defensive allelochemical. Solanine, a related substance also found in potatoes, has similar properties.
{{Chembox | Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 437977784 | ImageFile = Chaconine.svg | ImageSize = | ImageFile2 = File:Chaconine1.png | ImageCaption2 = 3D model of chaconine using MolView | IUPACName = Solanid-5-en-3β-yl α--rhamnopyranosyl-(1→2)-[α--rhamnopyranosyl-(1→4)]-β--glucopyranoside | SystematicName = (2S,2′S,3R,3′R,4R,4′R,5R,5′R,6S,6′S)-2,2′-{[(2R,3S,4S,5R,6R)-4-Hydroxy-2-(hydroxymethyl)-6-{[(2S,4aR,4bS,6aS,6bR,7S,7aR,10S,12aS,13aS,13bS)-4a,6a,7,10-tetramethyl-1,3,4,4a,4b,5,6,6a,6b,7,7a,8,9,10,11,12a,13,13a,13b,14-icosahydro-2H-naphtho[2′,1′:4,5]indeno[1,2-b]indolizin-2-yl]oxy}oxane-3,5-diyl]bis(oxy)}bis(6-methyloxane-3,4,5-triol) | OtherNames = α-Chaconine, Chaconine | Section1 = | Section2 = | Section3 = }} α-Chaconine is a steroidal glycoalkaloid that occurs in plants of the family Solanaceae. It is a natural toxicant produced in green potatoes and gives the potato a bitter taste. Tubers produce this glycoalkaloid in response to stress, providing the plant with insecticidal and fungicidal properties. It belongs to the chemical family of saponins. Since it causes physiological effects on individual organism, chaconine is considered to be a defensive allelochemical. Solanine, a related substance also found in potatoes, has similar properties.
== Symptoms and treatment == Symptoms resemble those seen following solanine ingestion including abdominal pain, diarrhea, and headache.
Discovered by embedding cosine similarity (sentence-transformers MiniLM, 384-dim).