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chemoselectivity
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chemoselectivity

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Chemoselectivity is the preferential reaction of a chemical reagent with one of two or more different functional groups.

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Subclass of
selectivity
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~4 min read

Encyclopedic overview

6 sections
Contents
  • Electrophilicity
  • Carbonyl functional groups
  • Metal-assisted selectivity
  • Reducing and oxidizing reagents
  • See also
  • References

Chemoselectivity is the preferential reaction of a chemical reagent with one of two or more different functional groups.

In a chemoselective system, a reagent in the presence of an aldehyde and an ester would mostly target the aldehyde, even if it has the option to react with the ester. Chemoselectivity is an area of interest in chemistry because scientists want to recreate complex biological compounds, such as natural products, and make specific modifications to them.

Excerpted from Wikipedia’s “chemoselectivity” article, available under the CC BY-SA 4.0 licence.

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