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dithionate(2-)

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dithionate(2-)

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Also known as [O3SSO3](2-), [S2O6](2-)

The dithionate (or metabisulfate) anion, , is a sulfur oxoanion derived from dithionic acid, H2S2O6. Its chemical formula is sometimes written in a semistructural format, as [O3SSO3]2−. It is the first member of the polythionates.

Chemical data

Formula
O6S2-2
Molecular weight
160.13 g/mol
SMILES
[O-]S(=O)(=O)S(=O)(=O)[O-]
InChIKey
RMGVZKRVHHSUIM-UHFFFAOYSA-L
XLogP
-2
Polar surface area
131 Ų
H-bond donors
0
H-bond acceptors
6
Formal charge
-2

via PubChem

Wikidata facts

Mass
159.914
Show 3 more facts
canonical SMILES
[O-]S(=O)(=O)S(=O)(=O)[O-]
Commons category
Dithionate ion
chemical formula
O₆S₂²⁻
Sources (2)

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Encyclopedic overview

3 sections
Contents
  • Compounds
  • References
  • External links

The dithionate (or metabisulfate) anion, , is a sulfur oxoanion derived from dithionic acid, H2S2O6. Its chemical formula is sometimes written in a semistructural format, as [O3SSO3]2−. It is the first member of the polythionates.

The sulfur atoms of the dithionate ion are in the +5 oxidation state due to the presence of the S–S bond. Generally, dithionates form stable compounds that are not readily oxidised or reduced. Strong oxidants oxidise them to sulfates and strong reducing agents reduce them to sulfites and dithionites. Aqueous solutions of dithionates are quite stable and can be boiled without decomposition.

Excerpted from Wikipedia’s “dithionate(2-)” article, available under the CC BY-SA 4.0 licence.