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mustard gas

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mustard gas

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Also known as HD, Lost, bis(2-chloroethyl)sulfane, sulfur mustard, 1,1'-thiobis(2-chloroethane), bis(2-chloroethyl) sulfide, bis(2-chloroethyl) sulphide, 1-chloro-2-[(2-chloroethyl)thio]ethane

chemical compound

OverviewAI-generated

Mustard gas, also referred to as sulfur mustard, is a chemical compound with the formula C₄H₈Cl₂S. Its IUPAC name is 1-chloro-2-(2-chloroethylsulfanyl)ethane. The substance was discovered in 1822. It has a density of 1.37 and a mass of 157.972. The melting point is 14.45, while the boiling point is 227.8. The flash point is 105, and the decomposition point is 180.

Physical properties include a vapor pressure of 0.11 and a refractive index of 1.5313. The median lethal dose (LD50) is 100. According to PubChem data, the weight is 159.08, the xlogp is 2.1, and the tpsa is 25.3. The molecule has zero hydrogen bond donors and one hydrogen bond acceptor, with a charge of 0.

Synthesized by Vinony from 26 facts across 4 sources: Wikidata, PubChem, PubMed, Vinony graph. Generated from structured data (not the Wikipedia text) and checked against those facts — may still contain errors.

Chemical data

Formula
C4H8Cl2S
Molecular weight
159.08 g/mol
IUPAC name
1-chloro-2-(2-chloroethylsulfanyl)ethane
SMILES
C(CCl)SCCCl
InChIKey
QKSKPIVNLNLAAV-UHFFFAOYSA-N
XLogP
2.1
Polar surface area
25.3 Ų
H-bond donors
0
H-bond acceptors
1
Formal charge
0

via PubChem

Drug data · ChEMBL

Molecule type
Small molecule

via ChEMBL · EBI

Research

2,732 papers

via PubMed

Wikidata facts

Subclass of
thioether
Has part
chlorine
Mass
157.972
Show 14 more facts
Commons category
Sulfur mustard
chemical formula
C₄H₈Cl₂S
different from
nitrogen mustard
flash point
105
canonical SMILES
C(CCl)SCCCl
density
1.2741
melting point
14.45
refractive index
1.5313
decomposition point
180
vapor pressure
0.11
boiling point
227.8
median lethal dose (LD50)
100
time of discovery or invention
1822-00-00
Sources (10)

via Wikidata · CC0

~35 min read

Encyclopedic overview

Mustard gas or sulfur mustard are names commonly used for the organosulfur chemical compound bis(2-chloroethyl) sulfide, which has the chemical structure S(CH2CH2Cl)2, as well as other species. In the wider sense, compounds with the substituents −SCH2CH2X or −N(CH2CH2X)2 are known as sulfur mustards or nitrogen mustards, respectively, where X = Cl or Br. Such compounds are potent alkylating agents, making mustard gas acutely and severely toxic. Mustard gas is a carcinogen. There is no preventive agent against mustard gas, with protection depending entirely on skin and airways protection, and no antidote exists for mustard poisoning.

Also known as mustard agents, this family of compounds comprises infamous cytotoxins and blister agents with a long history of use as chemical weapons. The name mustard gas is technically incorrect; the substances, when dispersed, are often not gases but a fine mist of liquid droplets that can be readily absorbed through the skin and by inhalation. The skin can be affected by contact with either the liquid or vapor. The rate of penetration into skin is proportional to dose, temperature and humidity.

Excerpted from Wikipedia’s “mustard gas” article, available under the CC BY-SA 4.0 licence.

Gallery (13)