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thioformaldehyde

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EntityQ18692307· pop 9· linked from 202 articles

thioformaldehyde

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Also known as methanethial, methanethione

Thioformaldehyde is the organosulfur compound with the formula CH2S. It is the simplest thioaldehyde. This compound is not observed in the condensed state (solid or liquid) because it oligomerizes to 1,3,5-trithiane, which is a stable colorless compound with the same empirical formula.

Chemical data

Formula
CH2S
Molecular weight
46.09 g/mol
IUPAC name
methanethione
SMILES
C=S
InChIKey
DBTDEFJAFBUGPP-UHFFFAOYSA-N
XLogP
1.8
Polar surface area
32.1 Ų
H-bond donors
0
H-bond acceptors
1
Formal charge
0

via PubChem

Wikidata facts

Mass
45.987721
Show 2 more facts
canonical SMILES
C=S
chemical formula
CH₂S
Sources (2)

via Wikidata · CC0

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Encyclopedic overview

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Contents
  • References

Thioformaldehyde is the organosulfur compound with the formula CH2S. It is the simplest thioaldehyde. This compound is not observed in the condensed state (solid or liquid) because it oligomerizes to 1,3,5-trithiane, which is a stable colorless compound with the same empirical formula.

Despite the instability of these concentrated forms, thioformaldehyde as a dilute gas has been extensively studied. For these purposes, it is produced by thermal decomposition of dimethyl disulfide. The molecule has been observed in the interstellar medium and has attracted much attention for its fundamental nature. The tendency of thioformaldehyde to form chains and rings is a manifestation of the double bond rule.

Excerpted from Wikipedia’s “thioformaldehyde” article, available under the CC BY-SA 4.0 licence.

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