Calcium minerals

Ilvaite is a sorosilicate of iron and calcium with formula: . Both manganese and magnesium substitute in the structure. Ilvaite crystallizes in the monoclinic system in black prismatic crystals and columnar masses. It is black to brownish black to gray and opaque. It has a Mohs hardness of 5.5 to 6 and a specific gravity of 3.8 to 4.1. Ilvaite is structurally related to lawsonite.

Colemanite (Ca2B6O11·5H2O) or (CaB3O4(OH)3·H2O) is a borate mineral found in evaporite deposits of alkaline lacustrine environments. Colemanite is a secondary mineral that forms by alteration of borax and ulexite.

Polyhalite is an evaporite mineral, a hydrated sulfate of potassium, calcium and magnesium with formula: . Polyhalite crystallizes in the triclinic system, although crystals are very rare. The normal habit is massive to fibrous. It is typically colorless, white to gray, although it may be brick red due to iron oxide inclusions. It has a Mohs hardness of 3.5 and a specific gravity of 2.8. It is used as a valuable fertilizer.

Lawsonite is a hydrous calcium aluminium sorosilicate mineral with formula CaAl2Si2O7(OH)2·H2O. Lawsonite crystallizes in the orthorhombic system in prismatic, often tabular crystals. Crystal twinning is common. It forms transparent to translucent colorless, white, pink, and bluish to pinkish grey glassy to greasy crystals. Refractive indices are nα= 1.665, nβ= 1.672 – 1.676, and nγ= 1.684 – 1.686. It is typically almost colorless in thin section, but some lawsonite is pleochroic from colorless to pale yellow to pale blue, depending on orientation. The mineral has a Mohs hardness of 7.5 and a

Glauberite is a monoclinic sodium calcium sulfate mineral with the formula Na2Ca(SO4)2.

The rare mineral adelite, is a calcium, magnesium, arsenate with chemical formula CaMgAsO4OH. It forms a solid solution series with the vanadium-bearing mineral gottlobite. Various transition metals substitute for magnesium and lead replaces calcium leading to a variety of similar minerals in the adelite–duftite group.

Powellite is a calcium molybdate mineral with formula CaMoO4. Powellite crystallizes with tetragonal – dipyramidal crystal structure as transparent adamantine blue, greenish-brown, yellow-to-grey typically anhedral forms. It exhibits distinct cleavage, and has a brittle-to-conchoidal fracture. It has a Mohs hardness of 3.5 to 4 and a specific gravity of 4.25. It forms a solid solution series with scheelite (calcium tungstate, CaWO4). It has refractive index values of nω=1.974 and nε=1.984.

Cancrinite is a complex carbonate and silicate of sodium, calcium and aluminium with the formula Na6Ca2[(CO3)2|Al6Si6O24]·2H2O. It is classed as a member of the feldspathoid group of minerals; the alkali feldspars that are poor in silica. Yellow, orange, pink, white or even blue, it has a vitreous or pearly luster; a hardness of 5–6 and an uneven conchoidal fracture. It is unusual among the silicate minerals in that it will effervesce with hydrochloric acid due to the associated carbonate ions.

Scolecite is a tectosilicate mineral belonging to the zeolite group; it is a hydrated calcium silicate, CaAl2Si3O10·3H2O. Only minor amounts of sodium and traces of potassium substitute for calcium. There is an absence of barium, strontium, iron and magnesium. Scolecite is isostructural (having the same structure) with the sodium-calcium zeolite mesolite and the sodium zeolite natrolite, but it does not form a continuous chemical series with either of them. It was described in 1813, and named from the Greek word, σκώληξ (sko-lecks) = "worm" because of its reaction to the blowpipe flame.

Saponite is a trioctahedral mineral of the smectite group. Its chemical formula is . It is soluble in sulfuric acid. It was first described in 1840 by Svanberg. Varieties of saponite are griffithite, bowlingite and sobotkite.

thumb|Garnet demantoid - Antetezambato, Ambanja District, Diana (Northern) Region, Antsiranana Province, Madagaskar. Demantoid is the green gemstone variety of the mineral andradite, a member of the garnet group of minerals. Andradite is a calcium- and iron-rich garnet. The chemical formula is Ca3Fe2(SiO4)3 with chromium substitution as the cause of the demantoid green color. Ferric iron is the cause of the yellow in the stone.

thumb|300px|right|A view down onto the sheets of the A2B(T2O7) melilite structure. The A sites are yellow spheres, the B sites are pale orange tetrahedra, and the T sites are blue tetrahedra. Oxygen atoms (not shown) are on the corners of the tetrahedra.

Cavansite, named for its chemical composition of calcium vanadium silicate, is a deep blue hydrous calcium vanadium phyllosilicate mineral, occurring as a secondary mineral in basaltic and andesitic rocks along with a variety of zeolite minerals. Its blue coloring comes from vanadium, a metal ion. Discovered in 1967 in Malheur County, Oregon, cavansite is a relatively rare mineral. It is polymorphic with the even rarer mineral, pentagonite. It is most frequently found in Pune, India, and in the Deccan Traps, a large igneous province.

Omphacite is a member of the clinopyroxene group of silicate minerals with formula: (Ca, Na)(Mg, Fe2+, Al)Si2O6. It is a variably deep to pale green or nearly colorless variety of clinopyroxene. It normally appears in eclogite, which is the high-pressure metamorphic rock of basalt. Omphacite is the solid solution of Fe-bearing diopside and jadeite. It crystallizes in the monoclinic system with prismatic, typically twinned forms, though usually anhedral. Its space group can be P2/n or C2/c depending on the thermal history. It exhibits the typical near 90° pyroxene cleavage. It is brittle with s

Tsavorite or tsavolite is a variety of the garnet group species grossular, a calcium-aluminium garnet with the formula Ca3Al2Si3O12. Trace amounts of vanadium or chromium provide the green color.

Piemontite is a sorosilicate mineral in the monoclinic crystal system with the chemical formula . It is a member of the epidote group.

Uranophane (Ca(UO2)2(SiO3OH)2·5H2O), also known as uranotile, is a rare calcium uranium silicate hydrate mineral that forms from the oxidation of other uranium-bearing minerals. It has a yellow color and is radioactive.

Okenite (CaSi2O5·2H2O) is a silicate mineral that is usually associated with zeolites. It most commonly is found as small white "cotton ball" formations within basalt geodes. These formations are clusters of straight, radiating, fibrous crystals that are both bendable and fragile. It also belongs to the family of the calcium silicate hydrates (C-S-H) commonly found in hardened cement paste. In cement chemist notation (CCN) it is noted as CaO·2SiO2·2H2O and abbreviated as CS2H2.

Clinozoisite is a complex calcium aluminium sorosilicate mineral with formula: Ca2Al3(Si2O7)(SiO4)O(OH). It forms a continuous solid solution series with epidote by substitution of iron(III) in the aluminium (m3 site) and is also called aluminium epidote.

Mesolite is a tectosilicate mineral with formula . It is a member of the zeolite group and the natrolite subgroup, also resembling natrolite in appearance.

Agrellite () is a rare triclinic inosilicate mineral with four-periodic single chains of silica tetrahedra.

thumb|Betafite, Gunnison, Colorado

Devilline is a sulfate mineral with the chemical formula CaCu4(SO4)2(OH)6·3H2O. The name originates from the French chemist's name, Henri Etienne Sainte-Claire Deville (1818–1881).

Afwillite is a calcium hydroxide nesosilicate mineral with formula Ca3(SiO3OH)2·2H2O. It occurs as glassy, colorless to white prismatic monoclinic crystals. Its Mohs scale hardness is between 3 and 4. It occurs as an alteration mineral in contact metamorphism of limestone. It occurs in association with apophyllite, natrolite, thaumasite, merwinite, spurrite, gehlenite, ettringite, portlandite, hillebrandite, foshagite, brucite and calcite.

Creedite is a calcium aluminium sulfate fluoro hydroxide mineral with formula: Ca3Al2SO4(F,OH)10·2(H2O). Creedite forms colorless to white to purple monoclinic prismatic crystals. It often occurs as acicular radiating sprays of fine prisms. It is translucent to transparent with indices of refraction of nα = 1.461 nβ = 1.478 nγ = 1.485. It has a Mohs hardness of 3.5 to 4 and a specific gravity of 2.7.

Babingtonite is a calcium iron manganese inosilicate mineral with the formula . It is unusual in that iron(III) completely replaces the aluminium so typical of silicate minerals. It is a very dark green to black translucent (in thin crystals or splinters) mineral crystallizing in the triclinic system with typically radial short prismatic clusters and druzy coatings. It occurs with zeolite minerals in cavities in volcanic rocks. Babingtonite contains both iron(II) and iron(III) and shows weak magnetism. It has a Mohs hardness of 5.5 to 6 and a specific gravity of 3.3.

Xonotlite, or eakleite, is a mineral of general formula named by the German mineralogist Karl Friedrich August Rammelsberg in 1866. The name originates from its discovery locality, Tetela de Xonotla, Puebla, Mexico. Although it was discovered in 1866, it was first described in 1959. It is approved by the IMA, but it is a grandfathered species, meaning the name supposedly represents a valid species til this day.

Tyrolite is a hydrous calcium copper arsenate carbonate mineral with the formula CaCu5(AsO4)2CO3(OH)4⋅6H2O. Tyrolite forms glassy, blue to green orthorhombic radial crystals and botryoidal masses. It has a Mohs hardness of 1.5–2.0 and a specific gravity of 3.1–3.2. It is translucent with refractive indices of nα = 1.694, nβ = 1.726, and nγ = 1.730.

Clinoptilolite is a natural zeolite composed of a microporous arrangement of silica and alumina tetrahedra. It has the complex formula . It forms as white, green to reddish tabular monoclinic tectosilicate crystals with a Mohs hardness of 3.5 to 4 and a specific gravity of 2.1 to 2.2. It commonly occurs as a devitrification product of volcanic glass shards in tuff and as vesicle fillings in basalts, andesites and rhyolites. It was described in 1969 from an occurrence in the Barstow Formation, San Bernardino County, California. Sodium levels in clinoptilolite are generally higher than potassium

Phillipsite is a mineral series of the zeolite group; a hydrated potassium, calcium and aluminium silicate, approximating to . The members of the series are phillipsite-K, phillipsite-Na and phillipsite-Ca. The crystals are monoclinic, but only complex cruciform twins are known, these being exactly like twins of harmotome which also forms a series with phillipsite-Ca. Crystals of phillipsite are, however, usually smaller and more transparent and glassy than those of harmotome. Spherical groups with a radially fibrous structure and bristled with crystals on the surface are not uncommon. The Moh

Tranquillityite is a silicate mineral with formula (Fe2+)8Ti3Zr2 Si3O24. It is mostly composed of iron, oxygen, silicon, zirconium and titanium with smaller fractions of yttrium and calcium. It is named after the Mare Tranquillitatis (Sea of Tranquility), the place on the Moon where the rock samples were found during the 1969 Apollo 11 mission. It was the last mineral brought from the Moon which was thought to be unique, with no counterpart on Earth, until it was discovered in Australia in 2011.

Anapaite is a calcium–iron phosphate mineral with formula: Ca2Fe2+(PO4)2·4H2O. It is a mineral that typically occurs in cavities in fossil bearing sedimentary rocks. It is also found in phosphate bearing iron ores and rarely in pegmatites. It is commonly found with goethite, siderite and vivianite.

thumb|Putnisite (animation) Putnisite is a mineral composed of strontium, calcium, chromium, sulfur, carbon, oxygen and hydrogen. It was discovered on the Polar Bear Peninsula in Shire of Dundas, Western Australia in 2007 during mining activity. Following identification and recognition by the IMA in 2012 the mineral was named after mineralogists Andrew and Christine Putnis. The formal description was published in 2014.

Ekanite is an uncommon silicate mineral with chemical formula or . It is a member of the steacyite group. It is among the few gemstones that are naturally radioactive. Most ekanite is mined in Sri Lanka, although deposits also occur in Russia and North America. Clear and well-colored stones are rare as the radioactivity tends to degrade the crystal matrix over time in a process known as metamictization.

thumb|Scanning electron microscope (SEM) photograph of smectite clay – magnification 23,500 – [[U.S. Geological Survey – Tuckup Canyon]] thumb|Typical cracks pattern of a smectite-rich bentonite after its desiccation and shrinkage

Portlandite is a hydroxide-bearing mineral typically included in the oxide mineral class. It is the naturally occurring form of calcium hydroxide (Ca(OH)2) and the calcium analogue of brucite (Mg(OH)2).

Harmotome is a mineral, one of the rarer zeolites; a hydrated barium silicate with formula: . It forms vitreous white well defined monoclinic crystals, often associated with calcite and other zeolites. It has a Mohs hardness of 4 to 5 and a specific gravity of 2.44 to 2.5.

Kutnohorite is a rare calcium manganese carbonate mineral with the formula in the dolomite group of minerals. It forms a solid solution with the other group members dolomite and ankerite. The mineral was originally spelt "kutnahorite" but "kutnohorite" is the current IMA-approved spelling.

Gaylussite is a carbonate mineral, a hydrated sodium calcium carbonate, formula Na2Ca(CO3)2·5H2O. It occurs as translucent, vitreous white to grey to yellow monoclinic prismatic crystals. It is an unstable mineral which dehydrates in dry air and decomposes in water.

Mordenite is a zeolite mineral with the chemical formula . and it is one of the six most abundant zeolites and is used commercially.

Tobermorite is a calcium silicate hydrate mineral with chemical formula: Ca5Si6O16(OH)2·4H2O or Ca5Si6(O,OH)18·5H2O.

Pigeonite is a mineral in the clinopyroxene subgroup of the pyroxene group. It has a general formula of . The calcium cation fraction can vary from 5% to 25%, with iron and magnesium making up the rest of the cations.

Vaterite is a mineral, a polymorph of calcium carbonate (CaCO3). It was named after the German mineralogist Heinrich Vater. It is also known as mu-calcium carbonate (μ-CaCO3). Vaterite belongs to the hexagonal crystal system, whereas calcite is trigonal and aragonite is orthorhombic.

Brushite is a phosphate mineral with the chemical formula . Crystals of the pure compound belong to the monoclinic space group C2/c and are colorless. It is the phosphate analogue of the arsenate pharmacolite.

Richterite is a sodium calcium magnesium silicate mineral belonging to the amphibole group. If iron replaces the magnesium within the structure of the mineral, it is called ferrorichterite; if fluorine replaces the hydroxyl, it is called fluororichterite. Richterite crystals are long and prismatic, or prismatic to fibrous aggregate, or rock-bound crystals. Colors of richterite range from brown, grayish-brown, yellow, brownish- to rose-red, or pale to dark green. Richterite occurs in thermally metamorphosed limestones in contact metamorphic zones. It also occurs as a hydrothermal product in maf

Aerinite () is a bluish-purple inosilicate mineral. It crystallizes in the monoclinic system and occurs as fibrous or compact masses and coatings. It has a dark, vitreous luster, a specific gravity of 2.48 and a Mohs hardness of 3.

Serandite is a mineral with formula Na(Mn2+,Ca)2Si3O8(OH). The mineral was discovered in Guinea in 1931 and named for J. M. Sérand. Serandite is generally red, brown, black or colorless. The correct name lacks an accent.

Meionite is a tectosilicate belonging to the scapolite group with the formula Ca4Al6Si6O24CO3. Some samples may also contain a sulfate group. It was first discovered in 1801 on Mt Somma, Vesuvius, Italy. It was named by Rene Just Haüy after μειωυ, the Greek word for less, in reference to the less acute pyramidal form as compared to vesuvianite.

Bentorite is a mineral with the chemical formula . It is colored violet to light violet. Its crystals are hexagonal to dihexagonal dipyramidal. It is transparent and has vitreous luster. It has perfect cleavage. It is not radioactive. Bentorite is rated 2 on the Mohs scale.

Gyrolite, NaCa16(Si23Al)O60(OH)8·14H2O, is a rare silicate mineral (basic sodium calcium silicate hydrate: N-C-S-H, in cement chemist notation) belonging to the class of phyllosilicates. Gyrolite is also often associated with zeolites. It is most commonly found as spherical or radial formations in hydrothermally altered basalt and basaltic tuffs. These formations can be glassy, dull or fibrous in appearance.

Thaumasite is a calcium silicate mineral, containing Si atoms in unusual octahedral configuration, with chemical formula Ca3Si(OH)6(CO3)(SO4)·12H2O, also sometimes more simply written as CaSiO3·CaCO3·CaSO4·15H2O.

Leucophanite is an inosilicate mineral with the chemical formula . It may contain cerium substituting in the calcium position.

Huntite is a carbonate mineral with the chemical formula Mg3Ca(CO3)4. Huntite crystallizes in the trigonal system and typically occurs as platy crystals and powdery masses. For most of recorded history its main use was as a white pigment. Today the most common industrial use of huntite is as a natural mixture with hydromagnesite as a flame retardant or fire retardant additive for polymers.

Gmelinite is a series of rare zeolite minerals. The most common member is gmelinite-Na; others are gmelinite-Ca and gmelinite-K. It is closely related to the very similar mineral chabazite. Gmelinite was named as a single species in 1825 after Christian Gottlob Gmelin (1792–1860) professor of chemistry and mineralogist from Tübingen, Germany, and in 1997 it was raised to the status of a series.Gmelinite-Na has been synthesised from Na-bearing aluminosilicate gels. The naturally occurring mineral forms striking crystals, shallow, six sided double pyramids, which can be colorless, white, pale ye

Kinoite ( or ) is a light blue copper silicate mineral. It is somewhat scarce. It has a monoclinic crystal system, vitreous luster, and is transparent to translucent. It can be found in the Santa Rita Mountains, the Christmas Mine at Christmas, Arizona and a few other copper mines. Kinoite is popular with mineral collectors. Kinoite was named upon its discovery in 1970 after the pioneer Jesuit missionary Padre Eusebio Kino who worked in Arizona, Sonora and Baja California.

Whewellite is a mineral, hydrated calcium oxalate, formula Ca C2O4·H2O. Because of its organic content it is thought to have an indirect biological origin; this hypothesis is supported by its presence in coal and sedimentary nodules. However, it has also been found in hydrothermal deposits where a biological source appears improbable. For this reason, it may be classed as a true mineral.

Bassanite is a sulfate mineral composed of calcium sulfate hemihydrate, with the chemical formula or . It has half a water molecule per CaSO4 unit.

Gehlenite, (Ca2Al[AlSiO7]), is a sorosilicate, Al-rich endmember of the melilite complete solid solution series with akermanite. The type locality is in the Monzoni Mountains, Fassa Valley in Trentino in Italy, and is named after the Adolf Ferdinand Gehlen (1775–1815) by A.J. Fuchs in 1815.

Edenite or edenitic hornblende is a double chain silicate mineral of the amphibole group with the general chemical composition NaCa2Mg5(Si7Al)O22(OH)2. Edenite is named for the locality of Edenville, Orange County, New York, where it was first described.