right|frameless|550x550px A carbometallation is any reaction where a carbon-metal bond reacts with a carbon-carbon π-bond to produce a new carbon-carbon σ-bond and a carbon-metal σ-bond. The resulting carbon-metal bond can undergo further carbometallation reactions (oligomerization or polymerization see Ziegler-Natta polymerization) or it can be reacted with a variety of electrophiles including halogenating reagents, carbonyls, oxygen, and inorganic salts to produce different organometallic reagents. Carbometallations can be performed on alkynes and alkenes to form products with high geometric
碳金屬化反應(英語:carbometalation)是任何過程中發生以下事件的反應:一個碳-金屬鍵與一個碳-碳π鍵反應,並產生一個新的碳-碳σ鍵與一個碳-金屬σ鍵。 生成的碳金屬鍵可以進行進一步的碳金屬化反應(低聚或聚合,請參見齐格勒-纳塔催化剂聚合),也可以使其與各種亲电体試劑反應,包括鹵化試劑、羰基化合物、氧和無機鹽,從而生成不同的有機金屬試劑。碳金屬化反應可以在炔烴和烯烴上被進行,以分別形成具有高幾何純度或對映選擇性的產物。
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Discovered by embedding cosine similarity (sentence-transformers MiniLM, 384-dim).